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A Techno-Economic Study of Commercial Electrochemical CO2 Reduction into Diesel Fuel and Formic Acid

  • Mustafa, Azeem;Lougou, Bachirou Guene;Shuai, Yong;Razzaq, Samia;Wang, Zhijiang;Shagdar, Enkhbayar;Zhao, Jiupeng
    • Journal of Electrochemical Science and Technology
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    • v.13 no.1
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    • pp.148-158
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    • 2022
  • The electrochemical CO2 reduction (ECR) to produce value-added fuels and chemicals using clean energy sources (like solar and wind) is a promising technology to neutralize the carbon cycle and reproduce the fuels. Presently, the ECR has been the most attractive route to produce carbon-building blocks that have growing global production and high market demand. The electrochemical CO2 reduction could be extensively implemented if it produces valuable products at those costs which are financially competitive with the present market prices. Herein, the electrochemical conversion of CO2 obtained from flue gases of a power plant to produce diesel and formic acid using a consistent techno-economic approach is presented. The first scenario analyzed the production of diesel fuel which was formed through Fischer-Tropsch processing of CO (obtained through electroreduction of CO2) and hydrogen, while in the second scenario, direct electrochemical CO2 reduction to formic acid was considered. As per the base case assumptions extracted from the previous outstanding research studies, both processes weren't competitive with the existing fuel prices, indicating that high electrochemical (EC) cell capital cost was the main limiting component. The diesel fuel production was predicted as the best route for the cost-effective production of fuels under conceivable optimistic case assumptions, and the formic acid was found to be costly in terms of stored energy contents and has a facile production mechanism at those costs which are financially competitive with its bulk market price. In both processes, the liquid product cost was greatly affected by the parameters affecting the EC cell capital expenses, such as cost concerning the electrode area, faradaic efficiency, and current density.

SNIPE Mission for Space Weather Research (우주날씨 관측을 위한 큐브위성 도요샛 임무)

  • Lee, Jaejin;Soh, Jongdae;Park, Jaehung;Yang, Tae-Yong;Song, Ho Sub;Hwang, Junga;Kwak, Young-Sil;Park, Won-Kee
    • Journal of Space Technology and Applications
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    • v.2 no.2
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    • pp.104-120
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    • 2022
  • The Small Scale magNetospheric and Ionospheric Plasma Experiment (SNIPE)'s scientific goal is to observe spatial and temporal variations of the micro-scale plasma structures on the topside ionosphere. The four 6U CubeSats (~10 kg) will be launched into a polar orbit at ~500 km. The distances of each satellite will be controlled from 10 km to more than ~1,000 km by the formation flying algorithm. The SNIPE mission is equipped with identical scientific instruments, Solid-State Telescopes(SST), Magnetometers(Mag), and Langmuir Probes(LP). All the payloads have a high temporal resolution (sampling rates of about 10 Hz). Iridium communication modules provide an opportunity to upload emergency commands to change operational modes when geomagnetic storms occur. SNIPE's observations of the dimensions, occurrence rates, amplitudes, and spatiotemporal evolution of polar cap patches, field-aligned currents (FAC), radiation belt microbursts, and equatorial and mid-latitude plasma blobs and bubbles will determine their significance to the solar wind-magnetosphere-ionosphere interaction and quantify their impact on space weather. The formation flying CubeSat constellation, the SNIPE mission, will be launched by Soyuz-2 at Baikonur Cosmodrome in 2023.

Frequency Stability Enhancement of Power System using BESS (BESS를 활용한 전력계통 주파수 안정도 향상)

  • Yoo, Seong-Soo;Kwak, Eun-Sup;Moon, Chae-Joo
    • The Journal of the Korea institute of electronic communication sciences
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    • v.17 no.4
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    • pp.595-606
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    • 2022
  • Korea has the characteristics of traditional power system such as large-scale power generation and large-scale power transmission systems, including 20 GW large-scale power generation complexes in several regions with unit generator capacity exceeding 1.4 GW, 2-3 ultra-high-voltage transmission lines that transport power from large-scale power generation complexes, and 6 ultra-high-voltage transmission lines that transport power from non-metropolitan areas to the metropolitan area. Due to the characteristics of the power system, the penetration level for renewable energy is low, but due to frequency stability issue, some generators are reducing the output of generators. In the future, the issue of maintaining the stability of the power system is expected to emerge as the most important issue in accordance with the policy of expanding renewable energy. When non-inertial inverter-based renewable energy, such as solar and wind power, surges rapidly, the means to improve the power system stability in an independent system is to install a natural inertial resource synchronous condenser (SC) and a virtual inertial resource BESS in the system. In this study, we analyzed the effect of renewable energy on power system stability and the BESS effect to maintain the minimum frequency through a power system simulation. It was confirmed that the BESS effect according to the power generation constraint capacity reached a maximum of 122.81 %.

A Multi-Criteria Spatial Decision Support System for Smart Hydrogen Energy Plant Location Planning in the Gangwon-Do Region, South Korea (강원도 지역 스마트 수소에너지 플랜트 입지계획을 위한 다기준 공간의사결정 지원 시스템 연구)

  • Yum, Sang-Guk;Adhikari, Manik Das
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.43 no.3
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    • pp.381-395
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    • 2023
  • This paper presents a GIS-based site suitability analysis for a smart hydrogen energy plant in the Gangwon-Do region, South Korea. A GIS-based multi-criteria decision analysis (MCDA) was implemented in this study to identify the most suitable sites for the development of smart hydrogen energy plants. The study utilizes various spatial data layers, including hydrogen generation potential and climatic conditions, environmental and topographic conditions, and natural catastrophic conditions, to evaluate the suitability of potential sites for the hydrogen energy plant. The spatial data layers were then used to rank and prioritize the sites based on suitability. The findings revealed that 4.26% of the study area, or 712.14 km2, was suitable for constructing smart hydrogen energy plants. Some regions of Cheorwon-gun, Chuncheon-si, Wonju-si, Yanggu-gun, Gangneung-si, Hoengseong-gun, and near the coastal region along the east coast were found to be suitable for solar and wind energy utilization. The proposed MCDA provides a valuable tool for decision-makers and stakeholders to make informed decisions on the location of smart hydrogen energy plants and supports the transition to a sustainable and low-carbon energy system. Decision-makers can use the results of this study to select suitable sites for constructing smart hydrogen energy plants.

An Observation Study of the Relationship of between the Urban and Architectural Form and Microclimate (도시·건축형태와 미기후의 관계에 대한 관찰 연구)

  • Lee, Gunwon;Jeong, Yunnam
    • Asia-pacific Journal of Multimedia Services Convergent with Art, Humanities, and Sociology
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    • v.8 no.11
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    • pp.109-119
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    • 2018
  • This study investigates the effect of urban and architectural forms on the microclimate in urban areas. It applies urban and architectural elements such as urban form and tissue and building form and characteristics as the main influences on the microclimate within urban area. Among the 23 Automated Weather Stations (AWS) installed within Seoul city by the Korea Meteorological Administration, 6 sites were selected for the analysis, based on their different urban and architectural characteristics, and actual measurements were conducted in August 2017 using individual AWS equipment. Also, the measurements of microclimate and urban and architectural elements within a 500m radius of the AWS measurement points were collected and analyzed. The result of the analysis shows that the microclimate elements, such as wind speed, solar radiation, and temperature, were affected by the direction of the streets, the width, depth, and height of the buildings, the topographic elevation and direction and the traffic volume. This study is expected to contribute to mitigating urban heat island effect and setting the foundation for sustainable cities through development of urban management methods and techniques including the relationship between built environment elements and microclimate.

Analysis of the Spatial Distribution of Pan Evaporation Trends (Pan 증발량 추세분포 분석)

  • Rim, Chang-Soo
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.30 no.3B
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    • pp.243-255
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    • 2010
  • The spatial distribution of pan evaporation and pan evaporation trends have been studied. In this study, pan evaporation data from 1973 to 1990 for 56 climatological stations were analyzed. In addition to annual average daily pan evaporation, monthly average daily pan evaporation in April, July, October and January were analyzed, considering seasonal effect. The study results indicate that in case of annual average daily pan evaporation, 38 stations out of 56 stations show decreasing trend. In case of average daily pan evaporation in January, 33 stations show decreasing trend. In April, 38 stations show increasing trend. In July, 47 stations show decreasing trend. In October, 35 stations show increasing trend. Therefore, on the whole, pan evaporation tended to decrease in January, July, and annual basis. On the other hand, pan evaporation tended to increase in April and October. Furthermore, pan evaporation trend in each individual region shows also different trend even though the region is located nearby, indicating that there are geographical and topographical effects on pan evaporation trend. Pan evaporation data and climatic data from 1973 to 2006 for 11 climatological stations were used for trend analysis. Climatic variables such as temperature, relative humidity and wind speed show same or opposite trend direction compared with pan evaporation in annual or monthly basis. Annual and monthly solar radiation trends show the same direction compared with pan evaporation; however, annual and monthly precipitation trends show the opposite direction compared with pan evaporation.

Production of Digital Climate Maps with 1km resolution over Korean Peninsula using Statistical Downscaling Model (통계적 상세화 모형을 활용한 한반도 1km 농업용 전자기후도 제작)

  • Jina Hur;Jae-Pil Cho;Kyo-Moon Shim;Sera Jo;Yong-Seok Kim;Min-Gu Kang;Chan-Sung Oh;Seung-Beom Seo;Eung-Sup Kim
    • Korean Journal of Agricultural and Forest Meteorology
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    • v.25 no.4
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    • pp.404-414
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    • 2023
  • In this study, digital climate maps with high-resolution (1km, daily) for the period of 1981 to 2020 were produced for the use as reference data within the procedures for statistical downscaling of climate change scenarios. Grid data for the six climate variables including maximum temperature, minimum temperature, precipitation, wind speed, relative humidity, solar radiation was created over Korean Peninsula using statistical downscaling model, so-called IGISRM (Improved GIS-based Regression Model), using global reanalysis data and in-situ observation. The digital climate data reflects topographical effects well in terms of representing general behaviors of observation. In terms of Correlation Coefficient, Slope of scatter plot, and Normalized Root Mean Square Error, temperature-related variables showed satisfactory performance while the other variables showed relatively lower reproducibility performance. These digital climate maps based on observation will be used to downscale future climate change scenario data as well as to get the information of gridded agricultural weather data over the whole Korean Peninsula including North Korea.

Demand Shifting or Ancillary Service?: Optimal Allocation of Storage Resource to Maximize the Efficiency of Power Supply (Demand Shifting or Ancillary Service?: 효율적 재생발전 수용을 위한 에너지저장장치 최적 자원 분배 연구)

  • Wooyoung Jeon
    • Environmental and Resource Economics Review
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    • v.33 no.2
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    • pp.113-133
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    • 2024
  • Variable renewable energy (VRE) such as solar and wind power is the main sources of achieving carbon net zero, but it undermines the stability of power supply due to high variability and uncertainty. Energy storage system (ESS) can not only reduce the curtailment of VRE by load shifting but also contribute to stable power system operation by providing ancillary services. This study analyzes how the allocation of ESS resources between load shifting and ancillary service can contribute to maximizing the efficiency of power supply in a situation where the problems caused by VRE are becoming more and more serious. A stochastic power system optimization model that can realistically simulate the variability and uncertainty of VRE was applied. The analysis time point was set to 2023 and 2036, and the optimal resource allocation strategy and benefits of ESS by varying VRE penetration levels were analyzed. The analysis results can be largely summarized into the following three. First, ESS provides excellent functions for both load shifting and ancillary service, and it was confirmed that the higher the reserve price, the more limited the load shifting and focused on providing reserve. Second, the curtailment of VRE can be a effective substitute for the required reserve, and the higher the reserve price level, the higher the curtailment of VRE and the lower the required amount of reserve. Third, if a reasonable reserve offer price reflecting the opportunity cost is applied, ESS can secure economic feasibility in the near future, and the higher the proportion of VRE, the greater the economic feasibility of ESS. This study suggests that cost-effective low-carbon transition in the power system is possible when the price signal is correctly designed so that power supply resources can be efficiently utilized.

Analysis of Gas Emissions and Power Generation for Co-firing Ratios of NG, NH3, and H2 Based on NGCC (NGCC 기반 천연가스, 암모니아, 수소 혼소 발전 비율에 따른 CO2와 NOx 배출량 및 전력 생산량 분석)

  • Inhye Kim;Jeongjae Oh;Taesung Kim;Minsuk Im;Sunghyun Cho
    • Korean Chemical Engineering Research
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    • v.62 no.3
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    • pp.225-232
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    • 2024
  • The reduction of CO2 emissions in the energy production sector, which accounts for 86.8% of total greenhouse gas emissions, is important to achieve carbon-neutrality. At present, 60% of total power generation in South Korea is coal and natural gas. Replacing fossil fuel with renewable energy such as wind and solar has disadvantages of unstable energy supply and high costs. Therefore, this study was conducted through the co-firing of natural gas, ammonia and hydrogen utilizing the natural gas combined cycle process. The results demonstrated reduction in CO2 emissions and 34%~238% of the power production compared to using only natural gas. Case studies on mass fractions of natural gas, ammonia and hydrogen indicated that power production and NOx emissions were inversely proportional to the ammonia ratio and directly proportional to the hydrogen ratio. This study provides guidelines for the use of various fuel mixtures and economic analysis in co-firing power generation.

Effects of Environmental Conditions on Vegetation Indices from Multispectral Images: A Review

  • Md Asrakul Haque;Md Nasim Reza;Mohammod Ali;Md Rejaul Karim;Shahriar Ahmed;Kyung-Do Lee;Young Ho Khang;Sun-Ok Chung
    • Korean Journal of Remote Sensing
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    • v.40 no.4
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    • pp.319-341
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    • 2024
  • The utilization of multispectral imaging systems (MIS) in remote sensing has become crucial for large-scale agricultural operations, particularly for diagnosing plant health, monitoring crop growth, and estimating plant phenotypic traits through vegetation indices (VIs). However, environmental factors can significantly affect the accuracy of multispectral reflectance data, leading to potential errors in VIs and crop status assessments. This paper reviewed the complex interactions between environmental conditions and multispectral sensors emphasizing the importance of accounting for these factors to enhance the reliability of reflectance data in agricultural applications.An overview of the fundamentals of multispectral sensors and the operational principles behind vegetation index (VI) computation was reviewed. The review highlights the impact of environmental conditions, particularly solar zenith angle (SZA), on reflectance data quality. Higher SZA values increase cloud optical thickness and droplet concentration by 40-70%, affecting reflectance in the red (-0.01 to 0.02) and near-infrared (NIR) bands (-0.03 to 0.06), crucial for VI accuracy. An SZA of 45° is optimal for data collection, while atmospheric conditions, such as water vapor and aerosols, greatly influence reflectance data, affecting forest biomass estimates and agricultural assessments. During the COVID-19 lockdown,reduced atmospheric interference improved the accuracy of satellite image reflectance consistency. The NIR/Red edge ratio and water index emerged as the most stable indices, providing consistent measurements across different lighting conditions. Additionally, a simulated environment demonstrated that MIS surface reflectance can vary 10-20% with changes in aerosol optical thickness, 15-30% with water vapor levels, and up to 25% in NIR reflectance due to high wind speeds. Seasonal factors like temperature and humidity can cause up to a 15% change, highlighting the complexity of environmental impacts on remote sensing data. This review indicated the importance of precisely managing environmental factors to maintain the integrity of VIs calculations. Explaining the relationship between environmental variables and multispectral sensors offers valuable insights for optimizing the accuracy and reliability of remote sensing data in various agricultural applications.