• 한국진공학회:학술대회논문집
• /
• 한국진공학회 2013년도 제45회 하계 정기학술대회 초록집
• /
• pp.251.2-251.2
• /
• 2013

Natural photosynthesis utilizes two proteins, photosystem I and photosystem II, to efficiently oxidize water and reduce NADP+ to NADPH. Artificial photosynthesis which mimics this process achieve water splitting through a two-step Z-schematic water splitting process using man-made synthetic materials for hydrogen fuel production. In this study, Z-scheme system was achieved from the hybrid materials which composed of hydrogen production part as photosystem I protein and water oxidizing part as semiconductor BiVO4. Utilizing photosystem I as the hydrogen evolving part overcomes the problems of existing hydrogen evolving p-type semiconductors such as water instability, expensive cost, few available choices and poor red light (>600 nm) absorbance. Some problems of photosystem II, oxygen evolving part of natural photosynthesis, such as demanding isolation process and D1 photo-damage can also be solved by utilizing BiVO4 as the oxygen evolving part. Preceding research has not suggested any protein-inorganic-hybrid Z-scheme composed of both materials from natural photosynthesis and artificial photosynthesis. In this study, to realize this Z-schematic electron transfer, diffusion step of electron carrier, which usually degrades natural photosynthesis efficiency, was eliminated. Instead, BiVO4 and Pt-photosystem I were all linked together by the mediator gold. Synthesized all-solid-state hybrid materials show enhanced hydrogen evolution ability directly from water when illuminated with visible light.

• International Journal of Air-Conditioning and Refrigeration
• /
• 제10권3호
• /
• pp.117-128
• /
• 2002

This paper describes the smoke filling process of a fire field model based on a self-deve-loped SMEP (Smoke Movement Estimating Program) code to the simulation of fire induced flows in the two types of atrium space containing a ceiling heat flux. The SMEP using PISO algorithm solves conservation equations for mass, momentum, energy and species, together with those for the modified k-$\varepsilon$ turbulence model with buoyancy production term. Also it solves the radiation equation using the discrete ordinates method. Compressibility is assumed and the perfect gas law is used. Comparison of the calculated upper-layer average tempera-ture and smoke layer clear height with the zone models has shown reasonable agreement. The zone models used are the CFAST and the NBTC one-room. For atrium fires with ceiling glass the ceiling heat flux by solar heat causes a high smoke temperature near the ceiling. However, it has no effect on the smoke movement such as the smoke layer clear heights that are important in fire safety. In conclusion, the smoke layer clear heights that are important in evacuation activity except the early of a fire were not as sensitive as the smoke layer tem-perature to the nature of ceiling heat flux condition. Thus, a fire sensor in atrium with ceiling glass has to consider these phenomena.

• 한국신재생에너지학회:학술대회논문집
• /
• 한국신재생에너지학회 2011년도 춘계학술대회 초록집
• /
• pp.111.2-111.2
• /
• 2011

야금학적 방법을 통한 태양전지용 실리콘 제조를 위하여 아크로(Arc furnace)에서 제조된 용융 상태의 금속급 실리콘을 슬래그와 직접 반응시켜 불순물을 제거하는 공정에 관한 연구를 수행하였다. 이를 위해 아크로와 고주파 유도용해로(High-frequency induction furnace)를 이용하여 금속급 실리콘을 제조와 정련 특성 실험을 수행하였다. 본 연구에서 금속급 실리콘을 제조하기 위한 장비로 150kW급-DC 아크로와 300kW급-AC 아크로를 사용하였다. 원재료로 규석, 코크스(Cokes), 숯, 그리고 우드칩(Wood chip)을 실험 비율에 맞춰 아크로 내부에 장입하고, 이를 용융환원 방법을 통해 반응을 시켰다. 이때 생산된 금속급 실리콘의 순도는 약 99.2~99.8% 이었으며, 원재료의 순도, 장입 비율 및 아크로 운전 특성에 따라 편차가 있다. 아크로에서 생산된 금속급 실리콘의 경우 인(phosphorus), 붕소(boron)를 다량 함유하고 있고, 이를 제거하기 위하여 50kW급 고주파 유도용해로 장비를 사용하여 슬래그 정련 실험을 수행하였다. 슬래그 정련시 사용한 성분은 SiO2, CaO 그리고 CaF2 이며, 금속급 실리콘과 슬래그의 질량비 및 반응 시간에 따른 실리콘 불순물 특성을 평가하였다. 실험결과 인과 붕소는 각각 1 ppm 이하, 5 ppm 이하 였으며, 칼슘을 제외한 대부분의 금속 불순물의 경우 0.1~0.2% 임을 확인하였다.

• Journal of Microbiology and Biotechnology
• /
• 제19권12호
• /
• pp.1665-1671
• /
• 2009

Anaerobic digestion sludge was cultivated in an electrochemical bioreactor (ECB) to enrich the hydrogenotrophic methanogens. A modified graphite felt cathode with neutral red (NR-cathode) was charged with electrochemical reducing power generated from a solar cell. The methane and carbon dioxide collected in a Teflon bag from the ECB were more than 80 ml/l of reactant/day and less than 20 ml/l of reactant/day, respectively, whereas the methane and carbon dioxide collected from a conventional bioreactor (CB) was around 40 ml/l of reactant/day, respectively. Moreover, the maximal volume ratios of methane to carbon dioxide (M/C ratio) collected in the Teflon bag from the ECB and CB were 7 and 1, respectively. The most predominant methanogens isolated from the CB on the $20^{th}$, $80^{th}$, and $150^{th}$ days of incubation were hydrogenotrophs. The methanogenic diversity analyzed by temperature gradient gel electrophoresis (TGGE) of the 16S rDNA variable region was higher in the ECB than in the CB. The DNA extracted from the TGGE bands was more than 95% homologous with hydrogenotrophic methanogens in the ECB, but was an aceticlastic methanogen in the CB. In conclusion, the ECB was demonstrated as a useful system for enriching hydrogenotrophic methanogens and increasing the M/C ratio of the gas product.

• 한국재료학회:학술대회논문집
• /
• 한국재료학회 2010년도 춘계학술발표대회
• /
• pp.11.2-11.2
• /
• 2010

Photovoltaic devices are promising candidates as affordable and large-area renewable energy sources, which can replace the fossil-fuel-based resources. Especially, thin film solar cells have attracted increasing research attention, since they have a great advantage of low production cost. From the physical point of view, the photovoltaic devices can provide us interesting questions, how to enhance the light absorption and the carrier collection efficiency. A lot of approaches would be possible to address these issues. We have focused on two major topics relevant to photovoltaic device physics; (1) light management using surface plasmons and (2) junction characterizations aiming at proper interface engineering. Regarding the first topic, we have investigated the influences of Ag under-layer morphology on optical properties of ZnO thin films. The experimental results suggested that coupling between the surface plasmon polaritons at the ZnO/Ag interface and excitons in ZnO should play important roles in reflectivity of the ZnO/Ag thin films, which are widely used back reflector structures in thin film solar cells. For the second topic, we have carried out scanning probe microscopy studies of Schottky junctions consisting of photovoltaic materials. Such a research is very helpful to understand the correlation between the defects (e.g., grain boundaries) and local electrical properties. We will introduce some of the recent experimental results and discuss the physical significance.

• 한국신재생에너지학회:학술대회논문집
• /
• 한국신재생에너지학회 2011년도 추계학술대회 초록집
• /
• pp.54.2-54.2
• /
• 2011

야금학적 정련 공정 중 슬래그 처리, 일방향 응고, 플라즈마-전자기유도용해 공정을 적용한 태양전지용 실리콘 제조 기술에 관한 연구를 수행하였다. 원소재인 금속급 실리콘을 제조하기 위해원재료로 규석, 코크스(Cokes), 숯, 그리고 우드칩(Wood chip)을 사용하였으며, 150kW급 DC 아크로(Arc furnace)를 이용하여 순도 99.8% 금속급 실리콘을 제조하였다. 제조된 용융 상태의 금속급 실리콘은 슬래그와 반응시켜 불순물을 제거하였다. SiO2-CaO-CaF2 계의 슬래그를 이용하였으며, 금속급 실리콘과 슬래그의 질량비 및 반응 시간에 따른 실리콘 불순물 특성을 평가하였다. 이후 고액 계면이 제어 가능한 일방향 응고 장치를 이용하여 금속불순물을 제거하였다. 고액상태의 온도 조건 및 응고 시간에 따른 불순물 농도 변화를 평가하였으며, 순도 6N급의 실리콘을 제조하였다. 마지막 공정으로 스팀 플라즈마 토치와 냉도가니가 적용된 전자기 유도 용해장치를 이용하여 붕소와 인을 제거하였다. 플라즈마 토치 가스로는 아르곤, 스팀, 수소를 이용하였다. 붕소와 인의 제거율은 각각 94%와 96%를 달성하였으며, 최종 순도 6N급의 실리콘을 제조하였다.

• 한국신재생에너지학회:학술대회논문집
• /
• 한국신재생에너지학회 2010년도 춘계학술대회 초록집
• /
• pp.237.1-237.1
• /
• 2010

Recent developments such as concern over global warming, depletion of fossil fuels and increase in energy demands by the increasing world population has eventually lead to mass production of electricity using renewable sources. Ocean contains energy in form of thermal energy and mechanical energy: thermal energy from solar radiation and mechanical energy from the waves and tides. The current paper looks at generating power using waves. The primary objective of the present study is to maximize the primary energy conversion (first stage conversion) of the base model by making some design changes. The model entire consisted of a numerical wave tank and the turbine section. The turbine section had three components; front guide nozzle, augmentation channel and the rear chamber. The augmentation channel further consisted of a front nozzle, rear nozzle and an internal fluid region representing the turbine housing. Different front guide nozzle configuration and rear chamber design were studied. As mentioned, a numerical wave tank was utilized to generate waves of desired properties and later the turbine section was integrated. The waves in the numerical wave tank were generated by a piston type wave maker which was located at the wave tank inlet. The inlet which was modeled as a plate wall which moved sinusoidally with the general function, $x=asin{\omega}t$. In addition to primary energy conversion, observation of flow characteristics, pressure and the velocity in the augmentation channel, rear chamber as well as the front guide nozzle are presented in the paper. The analysis was performed using the commercial code of the ANSYS-CFX. The base model recorded water power of 29.9 W. After making the changes, the best model obtained water power of 37.1 W which represents an increase of approximately 24% in water power and primary energy conversion.

• 한국태양에너지학회:학술대회논문집
• /
• 한국태양에너지학회 2009년도 춘계학술발표대회 논문집
• /
• pp.184-189
• /
• 2009

In order to improve the operation of energy systems, it is necessary for the urban communities to have reliable optimization routines, both computerized and manual, implemented in their organizations. However, before a production plan for the energy system units can be constructed, a prediction of the energy systems first needs to be determined. So, several methodologies have been proposed for energy demand prediction, but due to uncertainties in urban community, many of them will fail in practice. The main topic of this paper has been the development of a method for energy demand prediction at urban community. Energy demand prediction is important input parameters to plan for the energy planing. This paper presents a energy demand prediction method which estimates heat and electricity for various building categories. The method has been based on artificial neural networks(ANN). The advantage of ANN with respect to the other method is their ability of modeling a multivariable problem given by the complex relationships between the variables. Also, the ANN can extract the relationships among these variables by means of learning with training data. In this paper, the ANN have been applied in oder to correlate weather conditions, calendar data, schedules, etc. Space heating, cooling, hot water and HVAC electricity can be predicted using this method. This method can produce 10% of errors hourly load profile from individual building to urban community.

• Journal of Electrochemical Science and Technology
• /
• 제13권1호
• /
• pp.148-158
• /
• 2022

The electrochemical CO₂ reduction (ECR) to produce value-added fuels and chemicals using clean energy sources (like solar and wind) is a promising technology to neutralize the carbon cycle and reproduce the fuels. Presently, the ECR has been the most attractive route to produce carbon-building blocks that have growing global production and high market demand. The electrochemical CO₂ reduction could be extensively implemented if it produces valuable products at those costs which are financially competitive with the present market prices. Herein, the electrochemical conversion of CO₂ obtained from flue gases of a power plant to produce diesel and formic acid using a consistent techno-economic approach is presented. The first scenario analyzed the production of diesel fuel which was formed through Fischer-Tropsch processing of CO (obtained through electroreduction of CO₂) and hydrogen, while in the second scenario, direct electrochemical CO₂ reduction to formic acid was considered. As per the base case assumptions extracted from the previous outstanding research studies, both processes weren't competitive with the existing fuel prices, indicating that high electrochemical (EC) cell capital cost was the main limiting component. The diesel fuel production was predicted as the best route for the cost-effective production of fuels under conceivable optimistic case assumptions, and the formic acid was found to be costly in terms of stored energy contents and has a facile production mechanism at those costs which are financially competitive with its bulk market price. In both processes, the liquid product cost was greatly affected by the parameters affecting the EC cell capital expenses, such as cost concerning the electrode area, faradaic efficiency, and current density.

• 한국태양에너지학회:학술대회논문집
• /
• 한국태양에너지학회 2008년도 춘계학술발표대회 논문집
• /
• pp.275-280
• /
• 2008

Photovoltaic(PV) permit the on-site production of electricity without concern for fuel supply or environmental adverse effects. The electrical power is produced without noise and little depletion of resources. So BIPV(Building-Integrated Photovoltaic) system have been increased around the world. Hereby the relative installation costs of the system will be relatively low compared to traditional installations of PV in high-rise buildings. This paper examined possibility of BIPV system of cold facade type and analyzed of performance of BIPV system of cold facade type. The system is influenced by conditions such as irradiation, module temperature, shade and architectural component etc. If this BIPV system of 1.1kW is possible the natural ventilation in the summer case, the temperature of PV module decrease and then the efficiency of PV system increase generally. By the results, the annual averaged PR of BIPV system of cold facade type is about 73.1%.