• Korean Journal of Soil Science and Fertilizer
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• v.47 no.6
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• pp.443-450
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• 2014

To determine Pb species in soils following the immobilization process, sequential extraction has been used despite the possibility of overestimating Pb species from unintended reactions during chemical extraction. Meanwhile, the application of extended X-ray absorption fine structure (EXAFS) has been shown to provide a more precise result than chemical extraction. In this study, the immobilization of Pb in contaminated soils treated with liming materials such as oyster shell (OS) or eggshell (ES) was evaluated with thermodynamic modelling and EXAFS analysis. Thermodynamic modelling by visual MINTEQ predicted the precipitation of $Pb(OH)_2$ in OS and ES treated soils. In particular, the values of saturation index (SI) for $Pb(OH)_2$ in OS (SI=0.286) and ES (SI=0.453) treated soils were greater than in the control soil (SI=0.281). Linear combination fitting (LCF) analysis confirmed the presence of $C_{12}H_{10}O_{14}Pb_3$ (lead citrate, 44.7%) by citric acid from plant root, Pb-gibbsite (Pb adsorbed gibbsite, 26.4%), and Pb-kaolinite (Pb adsorbed kaolinite, 20.3%) in the control soil. On the other hand, $Pb(OH)_2$ (16.8%), Pb-gibbsite (39.3%), and Pb-kaolinite (25.6%) were observed in the OS treated soil and $Pb(OH)_2$ (55.2%) and Pb-gibbsite (33.8%) were also confirmed in the ES treated soil. Our results indicate that the treatment with OS and ES immobilizes Pb by adsorption of Pb onto the soil minerals as a result of the increase in soil negative charge and the formation of stable $Pb(OH)_2$ under high pH condition of soils.

• Journal of Korean Society for Atmospheric Environment
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• v.4 no.1
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• pp.33-44
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• 1988

For the purpose of examining the effects of simulated acid rain on the chemical properties of the experimental soil in Pinus densiflora seedlings and Forsythia koreana rooted cuttings, the experimental design of randomized block arrangement with three replications was implemented in the experimental field of Yesan National Agricultural Junior College. One-year-old Pinus densiflora seedlings and Forsythia koreana cuttings were planted in the pots filled the mixed soils (nursery soil: forest soil of siliceous sandy loam = 1 : V/V)in the early spring of 1985. The regime of artificil acid rain, in terms of spray frequency per monthly and spray amount at single treatment per plot, was simulated on the basis of climatological data averaged from 30 years records. Simulated acid rain (pH 2.0, pH4.0, and pH 5.5 as control) containing sulfuric and nitric acid in the ratio of 3:2 (chemical equivalant basis) diluted ground water, were treated on the experimental plants under condition of cutting off the natural precipitation with vinyl tunnel, during the growing season (May 1 to August 31) in 1985. THe results obtained in this study were as follows; 1. Soil acidity was dropped, and exchangeable aluminum contents in the soil was dramatically increased in both species, with decreasing pH levels of acid rain. 2. Exchangeable potassium, clacium, magnesium contents, and base saturation degree of the soil were highly drcreased in two species as the pH levels of acid rain decreased. 3. In two species, sulfate concentrations in the soil were decreased of pH 4.0 treatment, and remarkably increased at pH 2.0 treatment of acid rain in comparison with control. 4. Total nitrogen and available phosphate contents of the soil were not affected by acid rain treatment in the both species, and Fe contents at pH 2.0 treatment were highest among three acid rain treatments.

• Land and Housing Review
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• v.1 no.1
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• pp.59-65
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• 2010

The paper presents a comparison between a semi-implicit time integration linear finite element implementation and fully-implicit nonlinear Newton-Raphson finite element implementation of a triphasic small strain mixture formulation of an elastic partially saturated porous medium. The pore air phase pressure pa is assumed atmospheric, i.e., $p_a$ = 0, although the formulation and implementation are general to handle increase in pore air pressure as a result of loading, if needed. The solid skeleton phase is assumed linear isotropic elastic and partially saturated 'consolidation' in the presence of surface infiltration and traction is simulated. The verification of the implementation against an analytical solution for partially saturated pore water flow (no deformation) and comparison between the two implementations is presented and the important of the porosity-dependent nature of the partially saturated permeability is assessed on comparison with a commercial code for the partially saturated flow with deformation. As a result, the response of partially saturated permeability subjected to the porosity influences on the saturation of a soil, and the different behaviors of the partially saturated soil between staggered and monolithic coupled programs is worth of attention because the negative pore water pressure in the partially saturated soil depends on the difference.

• Journal of Soil and Groundwater Environment
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• v.24 no.1
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• pp.10-16
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• 2019

Alkalinity is an essential parameter for understanding geochemical processes and calculating partial pressure of $CO_2$, dissolved inorganic carbon, and mineral saturation indices. The Gran Titration Method (GTM) is one of the most accurate methods for measuring the alkalinity in water samples. However, this method has not been widely employed in measuring groundwater alkalinity in Korea, probably due to inadequate and insufficient understanding of the method. In this regard, this article was prepared to introduce GTM and related know-hows learned from the authors' experiences in measuring alkalinity. This paper also introduces a MS Excel-based alkalinity calculator as a handy tool for GTM.

• Korean Journal of Soil Science and Fertilizer
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• v.39 no.3
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• pp.144-150
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• 2006

Chemical characteristics and their interrelationships of 156 soils included by 74 sandy loam and 82 loam soils collected from plastic film house in Chungbuk area were investigated from 1998 to 2001. Seventeen chemical properties including pH, organic matter (OM), electrical conductivity (EC), inorganic nitrogen, available phosphorus, exchangeable cations, CEC, etc., were analyzed by correlation, standardized partial regression coefficient, and principal factor analysis. Standardized partial regression coefficients of chemical properties were estimated to determine the degree of contribution of EC and OM contents in soils. Principal factor analysis was applied to classify the studied chemical properties into different groups having similar chemical properties. The pH of experimental soils ranged from 4.24 to 7.14 and 4.95 to 7.35 for loam and sandy loam soils, respectively. The EC of soils varied from 0.93 to $15.65dS\;m^{-1}$ for loam and $0.91{\sim}22.30dS\;m^{-1}$ for sandy loam soils, respectively with significant differences among them. The EC measured by 1:5 $H_2O$ dilution method and saturation method were significantly related with 8.163 and 8.599 as the slopes of regression equation for loam and sandy loam soils, respectively. These slopes more than 8.0 in this regression equation was higher than the slope of 5.0 that is estimated from dilution coefficient suggesting that EC measured by 1:5 dilution method might be erratic. The standardized partial regression coefficient of different chemical properties for the estimation of EC was in the order of $NO_3{^-}$ > $Cl^-$ > OM > exchangeable Mg for loam soils and $NO_3{^-}$ > exchangeable Mg > $Cl^-$ for sandy loam soils. Contribution order of the chemical properties based on standardized partial regression coefficient differed 1:5 dilution method and saturation method, indicating that different chemical compounds might be present in the extract solutions of these two methods. Consequently the measurement of EC by saturation method was thought be still better for estimation of chemical property because accuracy of EC measurement by 1:5 dilution method can't be improved by any specific coefficient for adjustment of EC. Regardless of differences in soil textures and extraction methods, correlation coefficients between EC and the other chemical properties were routinely in the order of $NO_3{^-}$ > $Cl^-$ > degree of base saturation > exchangeable Mg > exchangeable Ca > $SO{_4}^{2-}$. The principal factor analysis revealed four factor groups of the chemical properties studied. The groups for sandy loam were as follows; ; 1. salt components, 2. soil reaction components, 3. fixed and adsorption components, 4. CEC components. The groupings of loam soils were similar to sandy loam except that exchangeable Na substituted the CEC of sandy loam.

• Journal of the Korean GEO-environmental Society
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• v.11 no.4
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• pp.5-12
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• 2010

Soil mixture using bentonite as a cutoff material is used a lot for various structures such as landfills, banks and dams as cutoff materials. But seepage water is expected to seep since shear failure of filter layer occurs due to external load, embankment load when constructed. Generally, only coefficient of permeability of Soil Mixture is considered irrespective of the changes of intensity on amount of additives. This research is to study on how the changes of amount of bentonite affects permeability and strength of soil mixture. So successive experiments for measuring permeability and strength were conducted as the amount of bentonite changes from 0 to 4%, mixing with the bed material and then making specimens. Around construction site of B dam. As a result, 2.085E-07 cm/sec was shown when the amount of Soil Mixture was 4%. It is proved that unconfined compressive strength and tensile strength increase as the amount of bentonite increases, but saturation shear strength of bentonite soil mixture from the CD experiment is hardly influenced by the amount of bentonite.

• Journal of Korea Soil Environment Society
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• v.4 no.3
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• pp.17-24
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• 1999

The effects of hydrophobic chain length and its structure of nonionic surfactants on surfactant adsorption and contaminated diesel removal were studied in kaolin soil. Hydrocarbon chain length and double bond in hydrophobic tail group of nonionic surfactants affected surfactant adsorption and diesel removal efficiency from kaolin soil. The degrees of surfactant adsorption and diesel removal were closely related each other. Among nonionic surfactants we studied, surfactants with shorter hydrophobic chain length and higher HLB value showed lower degree of adsorption and higher efficiency of diesel removal. The existence of unsaturated carbons in the structure of hydrophobic chain enhanced diesel removal by reducing surfactant adsorption to kaolin soil. The best diesel removal was obtained after adsorption saturation was reached. If surfactant concentration was higher than a critical value, diesel removal was reduced probably because of precipitation. liquid crystal formation, or coacervation of surfactants at high concentration.

• Earthquakes and Structures
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• v.11 no.1
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• pp.83-107
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• 2016

In this study, the response and behavior of machine foundations resting on dry and saturated sand was investigated experimentally. A physical model was manufactured to simulate steady state harmonic load applied on a footing resting on sandy soil at different operating frequencies. Total of (84) physical models were performed. The parameters that were taken into consideration include loading frequency, size of footing and different soil conditions. The footing parameters are related to the size of the rectangular footing and depth of embedment. Two sizes of rectangular steel model footing were used. The footings were tested by changing all parameters at the surface and at 50 mm depth below model surface. Meanwhile, the investigated parameters of the soil condition include dry and saturated sand for two relative densities; 30 % and 80 %. The dynamic loading was applied at different operating frequencies. The response of the footing was elaborated by measuring the amplitude of displacement using the vibration meter. The response of the soil to dynamic loading includes measuring the stresses inside soil media by using piezoelectric sensors. It was concluded that the final settlement (St) of the foundation increases with increasing the amplitude of dynamic force, operating frequency and degree of saturation. Meanwhile, it decreases with increasing the relative density of sand, modulus of elasticity and embedding inside soils. The maximum displacement amplitude exhibits its maximum value at the resonance frequency, which is found to be about 33.34 to 41.67 Hz. In general, embedment of footing in sandy soils leads to a beneficial reduction in dynamic response (displacement and excess pore water pressure) for all soil types in different percentages accompanied by an increase in soil strength.

• Asian Journal of Turfgrass Science
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• v.9 no.1
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• pp.81-89
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• 1995

The variations of the soil texture, $SiO_2$ /$Al_2$$O_3$ ratio, buffer action, exchangeable base, ex-changeable hydrogen, and mineral nutrients were investigated to estimate the grade of the soil fertility of the soil derived from the different parent rocks such as the granite in Kwangnung and the basalt in Chejudo. The results investigated were showed as follows : Basalt soils in Chejudo belong to sandy clay, light clay and sandy clay loam, while gramite soils in Kwangnung sandy loam. The $SiO_2$ /$AI_2$$O_3$ ratio of the grassland in Chejudo was 1.11 and that of the oak forest soils was 1.24, while granite soils in Kwangnung 1.54 and 1.46, respectively. The buffer actions of ba-salt soils against the N /10 HCI and $Ca(OH)_2$ were stronger than those of granite soils. The $SiO_2$/$Al_2$$O_3$ + $Fe_2$$O_3$ ratios of grassland and oak forest soils of basalt in Chejudo showed 1.10 and 1.24 respectively, while those of the grassland and oak forest of Kwangnung 1.44 and 1.33. The base exchange capacity of basalt soils which has higher value of exchangeable hydrogen was stronger than that of granite soils. But the base saturation of granite soils showed higher value than that of basalt soils. Water contents of basalt soils in Chejudo was lower than that of granite soils fo Kwangnung Basalt soils in Chejudo contain still more humus and total nitrogen than gran-ite soils in kwangnung, The amount of available nitrogen, available phosphorus and exchangeable calcium of granite soils were more than that of basalt soils, Therefore, estimating the soil fertility, granite soils in Kwangnung is higher than that of basalt soils in Chejudo.

• Geomechanics and Engineering
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• v.21 no.3
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• pp.247-258
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• 2020

The shear strength of unsaturated soils, a research hotspot in geotechnical engineering, has great guiding significance for geotechnical engineering design. Although kinds of calculation models for the shear strength of unsaturated soil have been put forward by predecessors, there is still need for new models to extensively consider the nonlinear variation of shear strength, particularly for the nonlinear effect of the net normal stress on the shear strength of unsaturated soil. Here, the shear strength of unsaturated soils is explored to study the nonlinear effects of net normal stress with the introduction of a general nonlinear Mohr-Coulomb (M-C) strength criterion, and the relationship between the matric suction (or suction stress) and degree of saturation (DOS) constructed by the soil-water characteristics curve (SWCC) of van Genuchten is also applied for unsaturated soil. Then, two calculation models (i.e., an envelope shell model and an effective stress model) are established for the shear strength of unsaturated soils under the nonlinear strength theory. In these two models, the curve of the shear strength of unsaturated soils versus the net normal stress exhibits a tendency to gently. Moreover, the proposed formulas have flexibility and convenience with five parameters (for the effective stress model) or six parameters (for the envelope shell model), which are from the M-C strength parameters of the saturated soil and fitting parameters of SWCC of van Genuchten. Thereafter, by comparison with the classical theory of the shear strength of unsaturated soils from some actual cases, the rationality and accuracy of the present models were verified.