• Korean Journal of Environmental Agriculture
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• v.12 no.1
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• pp.9-17
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• 1993

The leaching behavior of $^{14}C-carbofuran$, $^{14}C-bentazon$, and $^{14}C-3,3,4,4'-tetrachloroazobenzene(TCAB)$ in the forms of freshly treated, 3-month-aged, and 6-month-aged residues, respectively, was investigated in a loamy soil column system. The degradation and mobility of pesticides in soil and the possibility of the contamination of groundwater were followed by this approach: The ambient temperature of $15{\pm}2^{\circ}C$, irrigation by the constant-head method on soil columns, and leaching with 1332 ml of simulated precipitation during 90 days. While the fresh residues of $^{14}C-carbofuran$ and $^{14}C-bentazon$ were very mobile, the aged ones were remarkably reduced in their mobility. Fresh and aged residues of $^{14}C-TCAB$ were very immobile, instead. 3-Keto carbofuran phenol(2,3-dihydro-2,2-dimethyl-3-oxo-7-benzofuranol) was the major degradation product present in the leachate from the soil column containing freshly treated $^{14}C-carbofuran$, while no metabolites could be detected in the leachates from the columns containing $^{14}C-bentazon$ or $^{14}C-TCAB$.

• Proceedings of the Korean Geotechical Society Conference
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• 2000.11a
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• pp.447-454
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• 2000

This paper presents fundamental characteristics of a copper slag when used geotechnical materials. For this study, it was conducted laboratory tests such as compaction, large direct shear, hydraulic conductivity, leaching, TDR, frost heave test and so on. The results of laboratory tests shown gradually increase in draining capacity and shearing resistance more slag mixing. The unfrozen water in temperature changes and frost heave amounts in condition of -17 $^{\circ}C$ appeared to decrease. Also, toxicity tests based on the domestic solid waste regulations were satisfied with nonhazardous. By this research results, a copper slag mixed with granite soil may been used as granular base and embankment materials, fill etc.

• Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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• 2003.09a
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• pp.386-390
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• 2003

To evaluate the potential capacity of mine wastes in the production of heavy metal containing acid water, samples from depths of 0, 30 and 60cm were collected and analyzed. The waste from surface showed the lowest pH which indicates the oxidation of wastes and the capacity of contamination of the area around the waste file. And the lower pH values of leachate of the wastes through the leaching tests with pH controlled water(3, 4, 5) may indicate that minerals producing the acidity still exist. Reduction of sulfur contents in wastes after the leaching test well fit to the increased contents of iron oxide.

• Asian Journal of Turfgrass Science
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• v.8 no.3
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• pp.167-177
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• 1994

The relationship between microbial activity and physico-chemical characteristics of golf course soils were investigated in Kyonggi Province with different open years. The increasing tendency of soil PH with depth seemed to the result of mineral leaching. Exchangeable $Ca^2$+ , $Mg^2$+ and K+ showed relatively higher concentration in lower horizon indicating the leaching of minerals. The minerals were heavily leached in older golf course. There was a significant positive correlation between pH and $Ca^2$+.The contents of organic matters, total nitrogen and phosphorus were high in higher horizon.Dehydrogenase activity(DHA) and the content of ATP were determined as an index of soil microbial activity. DHA value was significantly different with golf club as well as golf courses ac-cording todifferent open year. This indicates that DHA was affected by several fertilizertreatments rather than herbicide pesticide treatments. DHA was positively correlated with water holding capacity and total nitrogen. The content of ATP was high in fairway and in golf course with older open year, showing the similar tendency with the results of DHA.

• Journal of Korean Society on Water Environment
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• v.27 no.6
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• pp.862-867
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• 2011

Pozzolanic-based stabilization/solidification (S/S) is an effective and economic remediation technology to immobilize heavy metals in contaminated soils. In this study, quick lime (CaO) was used to immobilize cadmium and zinc present in waste mine contaminated clayey sand soils. Addition of 5% quicklime to the contaminated soils effectively reduced heavy metal leachability after 2 bed volume operation below the drinking water regulatory limits. Lime addition was revealed to increase the immobilization for all heavy metals in tested pH ranges, so it could be an optimal choice for short-term remediation of heavy metal contaminated soil. The mass balances for these column tests show metal reduction of 92% for Cd and 87% for Zn of total resolved mass in case of 5% lime application.

• Economic and Environmental Geology
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• v.45 no.2
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• pp.121-135
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• 2012

Soil dispersion and heavy metal leaching with two heavy metal-contaminated soils were studied to derive the optimal dispersion condition in the course of developing the remedial technology using magnetic separation. The dispersion solutions of pyrophosphate, hexametaphosphate, orthophosphate and sodium dodecylsulfate (SDS) at 1 - 200 mM and the pH of solutions was adjusted to be 9 - 12 with NaOH. The clay content of suspension as an indicator of dispersion rate and the heavy metal concentration of the solution were tested at the different pHs and concentrations of the dispersion solution during the experiment. The dispersion rate increased with increasing the pH and dispersion agent concentration of the solution. The dispersion efficiency of the agents showed as follows: pyrophosphate > hexametaphosphate > SDS > orthophosphate. Arsenic leaching was sharply increased at 50 mM of phosphates and 100 mM of SDS. The adsorption of $OH^-$, phosphates and dodecysulfate on the surface of Fe- and Mn-oxides and soil organic matter and the broken edge of clay mineral might decrease the surface charge and might increase the repulsion force among soil particles. The competition between arsenic and $OH^-$, phosphates and dodecylsulfate for the adsorption site of soil particles might induce the arsenic leaching. The dispersion and heavy metal leaching data indicate that pH 11 and 10 mM pyrophosphate is the optimum dispersion solution for maximizing dispersion and minimizing heavy metal leaching.

• Journal of Soil and Groundwater Environment
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• v.11 no.1
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• pp.23-36
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• 2006

Experimental leaching of tailings was performed as a function of times (1, 2, 4, 7, 14, 21 and 30 days) in the laboratory using reaction solutions equilibrated to three different pH set-points (pHs 1,3 and 5). The initial pHs of 5 and 3 stabilized at either 4.6-6.1 or 2.8-3.5 in 2 days and decrease gradually with time afterwards. The results of the leaching tests indicate that the significant increase in the sulfate concentrations and in acidity after 7 days of leaching results from the oxidation of sulfide minerals. There were no significant variations in the extractable Pb found in the leach solutions of pH 5 and 3 within the reaction time (1-30 days), while Zn, Cd and Cu concentrations tend to significantly increase with time. In tailings leaching at an initial pH=1, two trends were observed: i) The 'Zn-type' (Zn, Cd and Cu), with increasing concentrations between days 1 and 30, corresponding to the expected trend when continuous dissolution is the dominant process, ii) the 'Pb-type' (Pb), with decreasing concentrations over time, suggesting rapid dissolution of a Pb source followed by the precipitation of 'anglesite' in relation to the large increase in dissolved sulfates. The high sulfate concentrations were coupled with high concentrations of released Fe, Zn and Cd. Release of Zn and Cd and acidity from these leaching experiments can potentially pose adverse impact to surface and groundwater qualities in the surrounding environment. The kinetic problems could be the important factor which leads to increasing concentrations of trace metals in the runoff water.

• Korean Journal of Soil Science and Fertilizer
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• v.48 no.1
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• pp.64-71
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• 2015

Soil contamination with arsenic and heavy metals is a worldwide problem. Main objective of this research was to evaluated effects of reducing heavy metal leaching under reduced soil condition amended with industrial by-products. The contaminated soil was amended with 3% (w/w) of limestone (Ls), steel slag (SS) and acid mine drainage sludge (AMDS). Synthetic acid rain ($H_2SO_4:HNO_3=6:4$, pH 5.5 fixed) was used for feeding solution with flow rate of $0.78{\sim}0.88mL\;min^{-1}$. Results showed that similar pH and EC of leachate was observed in all treatments regardless of applied industrial by-products. However, arsenic concentration of leachate increased when industrial by-products were mixed. Meanwhile, concentration of heavy metal in the leachate decreased from 11.3 to 4.59 mg for Cd, from 92.3 to 7.93 mg for Pb, and from 11,716 to 1,788 mg for Zn via immobilization in soil with AMDS amended, respectively. Overall, application of industrial by-products can be an environmentally-friendly way to remediate soil and(or) leachate contaminated with metal(loid)s in metal mine site.

• Korean Journal of Soil Science and Fertilizer
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• v.42 no.1
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• pp.37-45
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• 2009

Susceptibility assessment of groundwater contamination is a useful tool for many aspects of regional and local groundwater resources planning and management. It can be used to direct regulatory, monitoring, educational, and policy-making efforts to highly vulnerable areas. In this study, a semi process-based was proposed to evaluate relative susceptibilities to groundwater contamination by nitrate on a regional scale. Numerical simulation based on data from each soil series was done to model water flow within soil profiles that were related to groundwater contamination by nitrate. Relative vulnerability indices for each soil series were produced by manipulation of amount of leaching flux, amount of average water storage in a soil profile, and amount of average water storage change. These indices were designed to convey the trend of leaching flux and to maximize spatial resolution. The resulting vulnerability distribution map was used to locate highly vulnerable sites easily with an appropriate grouping the indices, and was then compared with those from groundwater nitrate concentrations monitored. An excellent agreement was obtained across nitrate concentrations from the highly vulnerable regions and those from the low to stable regions.

• Journal of the Korean Geosynthetics Society
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• v.15 no.4
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• pp.97-104
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• 2016

This paper performed consolidation tests on soft ground with and without artesian pressure conditions to find out characteristics of leaching effects using two types of one-dimensional column equipment(height : 1,100mm, outer diameter : 250mm). Artesian pressure of 5.5kPa was applied to the bottom of soft ground inside column equipment. Distribution of salinity and shear strength with soil depth were measured after the consolidation test. From the results, it was found that distribution of undrained shear strength and salt concentrations were similar at the top of clay ground irrespective of artesian pressure condition. However, at the bottom of clay ground, the values of undrained shear strength and salt concentration under artesian pressure were lower than those without artesian pressure. This result indicates that structure of soft soil with artesian pressure was weakened by salt leaching. Electronic resistance results showed that void ratio under artesian pressure condition was more reduced than that without artesian pressure condition.