• Title/Summary/Keyword: soil gas

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Evaluation of Organochlorine Pesticide Residues in the Mud Flat (연안(沿岸) 패류(貝類) 서식지(棲息地) 저니토중(底泥土中) 유기염소계(有機鹽素系) 농약(農藥)의 잔류평가(殘留評價))

  • Suh, Yong-Tack;Im, Geon-Jae;Shim, Jae-Han
    • Korean Journal of Environmental Agriculture
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    • v.5 no.2
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    • pp.113-118
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    • 1986
  • After selecting four places in the main shellfish habitat, 118 items of the sample were collected in the mud flat from August to October in 1983, in order to analyze organochlorine pesticide residues by a gas chromatograph equipped with an electron capture detector. The results obtained were summarized as follows; ${\alpha}-BHC,\;{\gamma}-BHC\;&\;PCNB,\;heptachlor,\;{\gamma}-endosulfan,\;{\beta}-endosulfan,$ p, p'-DDE, dieldrin, o, p'-DDT and p, p'-DDT were detected in the range from 2 to 98 percent and their levels of mean residues ranged from trace to 0.041ppm, in the order of ${\gamma}-BHC\;&\;PCNB,\;{\alpha}-BHC,\;heptachlor{\approx}{\alpha}-endosulfan{\approx}p, p`-DDE{\approx}dieldrin{\approx}{\beta}-endosulfan{\approx}$o, p'-DDT, and p, p'-DDT. The mean of total residues in regions was Kangjin(0.058ppm), Kwangyang(0.080ppm), Yoch'on (0.016ppm), and Yonggwang(0.75ppm). ${\gamma}-BHC\;&\;PCNB$ peak were separated by column packed with DC-200. PCNB was identified by making a PCA(pentachloroaniline), the reduced derivative of PCNB, and this confirmed that PCNB residues were detected in the soil sample.

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Enterococcus faecium LKE12 Cell-Free Extract Accelerates Host Plant Growth via Gibberellin and Indole-3-Acetic Acid Secretion

  • Lee, Ko-Eun;Radhakrishnan, Ramalingam;Kang, Sang-Mo;You, Young-Hyun;Joo, Gil-Jae;Lee, In-Jung;Ko, Jae-Hwan;Kim, Jin-Ho
    • Journal of Microbiology and Biotechnology
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    • v.25 no.9
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    • pp.1467-1475
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    • 2015
  • The use of microbial extracts containing plant hormones is a promising technique to improve crop growth. Little is known about the effect of bacterial cell-free extracts on plant growth promotion. This study, based on phytohormonal analyses, aimed at exploring the potential mechanisms by which Enterococcus faecium LKE12 enhances plant growth in oriental melon. A bacterial strain, LKE12, was isolated from soil, and further identified as E. faecium by 16S rDNA sequencing and phylogenetic analysis. The plant growth-promoting ability of an LKE12 bacterial culture was tested in a gibberellin (GA)-deficient rice dwarf mutant (waito-C) and a normal GA biosynthesis rice cultivar (Hwayongbyeo). E. faecium LKE12 significantly improved the length and biomass of rice shoots in both normal and dwarf cultivars through the secretion of an array of gibberellins (GA1, GA3, GA7, GA8, GA9, GA12, GA19, GA20, GA24, and GA53), as well as indole-3-acetic acid (IAA). To the best of our knowledge, this is the first study indicating that E. faecium can produce GAs. Increases in shoot and root lengths, plant fresh weight, and chlorophyll content promoted by E. faecium LKE12 and its cell-free extract inoculated in oriental melon plants revealed a favorable interaction of E. faecium LKE12 with plants. Higher plant growth rates and nutrient contents of magnesium, calcium, sodium, iron, manganese, silicon, zinc, and nitrogen were found in cell-free extract-treated plants than in control plants. The results of the current study suggest that E. faecium LKE12 promotes plant growth by producing GAs and IAA; interestingly, the exogenous application of its cell-free culture extract can be a potential strategy to accelerate plant growth.

Biotechnology for the Mitigation of Methane Emission from Landfills (매립지의 메탄 배출 저감을 위한 생물공학기술)

  • Cho, Kyung-Suk;Ryu, Hee-Wook
    • Microbiology and Biotechnology Letters
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    • v.37 no.4
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    • pp.293-305
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    • 2009
  • Methane, as a greenhouse gas, is some 21~25 times more detrimental to the environmental than carbon dioxide. Landfills generally constitute the most important anthropogenic source, and methane emission from landfill was estimated as 35~73 Tg per year. Biological approaches using biocover (open system) and biofilter (closed system) can be a promising solution for older and/or smaller landfills where the methane production is too low for energy recovery or flaring and installation of a gas extraction system is inefficient. Methanotrophic bacteria, utilizing methane as a sole carbon and energy source, are responsible for the aerobic degradation (oxidation) of methane in the biological systems. Many bench-scale studies have demonstrated a high oxidation capacity in diverse filter bed materials such as soil, compost, earthworm cast and etc. Compost had been most often employed in the biological systems, and the methane oxidation rates in compost biocovers/boifilters ranged from 50 to $700\;g-CH_4\;m^{-2}\;d^{-1}$. Some preliminary field trials have showed the suitability of biocovers/biofilters for practical application and their satisfactory performance in mitigation methane emissions. Since the reduction of landfill methane emissions has been linked to carbon credits and trading schemes, the verified quantification of mitigated emissions through biocovers/biofilters is very important. Therefore, the assessment of in situ biocovers/biofilters performance should be standardized, and the reliable quantification methods of methane reduction is necessary.

A Study on the Pyrolysis System Development for Oil Recovery from Waste Fishing Nets and Ropes (오일 회수를 위한 폐로프와 폐어망 열분해 장치 개발에 대한 연구)

  • Kim Yong-Seop;Yu Jeong Seok
    • Journal of the Korean Society for Marine Environment & Energy
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    • v.4 no.2
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    • pp.43-51
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    • 2001
  • Now our ocean environment pollution is very serious. Its harm hinders in marine breeding and the safe navigation of ships at the coast. We have used an assembly system for a measure taken against environment pollution like this. But, here are some problems awaiting solution. First, most of combustible materials among ocean waste are high polymer, so it is necessary some special equipment to incinerate them. In the process we can't overlook air pollution by exhaust gas. Also, when we reclaim these wastes, we remember that they can't be decomposed naturally and leaking water may pollute soil. Thus now a days new treatment method has been developed, it recycles and doesn't product secondary pollution materials by recovering oil from pyrolysis. For it, this study investigated chemicalㆍphysical properties of wastes. And it found condition of recovering the most oil. Also it probed that the variation of temperature raising speed affects the weight reduction characteristics of wastes. Also, while studying recovered oil by waste pyrolysis and the rate of non-condensing gas in accordance with the variation of temperature raising speed. Finally we had confidence the development of pyrolysis oil recovery would succeed because we carried out evaluation at an economic point of view about it.

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Gas Chromatographic Performances for Simultaneous Determination of Multi-pesticide Residues and Extraction of Pesticides with Three Partition Solvents (잔류농약 다성분 동시분석을 위한 기체 크로마토그래피 분석성능과 3종 분배용매에 의한 농약추출)

  • Kim, Chan-Sub;Kim, Jin-Bae;Im, Geon-Jae;Park, Hyun-Ju;Lee, Young-Deuk
    • The Korean Journal of Pesticide Science
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    • v.13 no.3
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    • pp.133-147
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    • 2009
  • In order to develop the simultaneous analytical method for pesticide residues which ones in soil are rapidly and inexpensively measured by, many analytical methods for individual pesticide residue and several methods for multi-pesticide residues in agricultural commodities and food were reviewed. Various gas chromatographic conditions and pre-treatment procedures were intensively investigated and modified. And then new optimum procedure was established and its proficiency was validated. The response on detectors of simultaneous determination of 180 pesticides out of pesticides used in Korea was tested. The number of pesticides that their limits of detection (LOD) equal or lower than $0.05\;mg\;kg^{-1}$ were 137 pesticides on ECD, 170 pesticides on NPD and 179 pesticides on ECD/NPD integrated. The retention times of most pesticides ranged appropriately between 10 minutes and 40 minutes in the proposed chromatographic conditions. But about 90 pesticides eluded between 20 minutes and 30 minutes and so they were not resolved enough. In partition with dichloromethane, ethyl acetate/hexane (1:1) and ethyl acetate, number of pesticides whose extraction efficiency ranged from 70% to 120%, were 163, 154 and 147, respectively.

Quantitative Comparison of Univariate Kriging Algorithms for Radon Concentration Mapping (라돈 농도 분포도 작성을 위한 단변량 크리깅 기법의 정량적 비교)

  • KWAK, Geun-Ho;KIM, Yong-Jae;CHANG, Byung-Uck;PARK, No-Wook
    • Journal of the Korean Association of Geographic Information Studies
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    • v.20 no.1
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    • pp.71-84
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    • 2017
  • Radon, which enters the interior environment from soil, rocks, and groundwater, is a radioactive gas that poses a serious risk to humans. Indoor radon concentrations are measured to investigate the risk of radon gas exposure and reliable radon concentration mapping is then performed for further analysis. In this study, we compared the predictive performance of various univariate kriging algorithms, including ordinary kriging and three nonlinear transform-based kriging algorithms (log-normal, multi-Gaussian, and indicator kriging), for mapping radon concentrations with an asymmetric distribution. To compare and analyze the predictive performance, we carried out jackknife-based validation and analyzed the errors according to the differences in the data intervals and sampling densities. From a case study in South Korea, the overall nonlinear transform-based kriging algorithms showed better predictive performance than ordinary kriging. Among the nonlinear transform-based kriging algorithms, log-normal kriging had the best performance, followed by multi-Gaussian kriging. Ordinary kriging was the best for predicting high values within the spatial pattern. The results from this study are expected to be useful in the selection of kriging algorithms for the spatial prediction of data with an asymmetric distribution.

A study on the black core formation of artificial lightweight aggregates at various sintering atmospheres (인공경량골재의 소성조건이 블랙코어에 미치는 영향)

  • Kim, Yoo-Taek;Ryu, Yu-Gwang;Jang, Chang-Sub;Lee, Ki-Gang;Kang, Seung-Gu;Kim, Jung-Hwan
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.19 no.6
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    • pp.318-323
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    • 2009
  • The lightweight aggregates made of bottom ash (70 wt%) and dredged soil (30 wt%) were prepared to investigate the property differences at various sintering atmospheres. The green aggregates were sintered at $1150^{\circ}C$ and $1200^{\circ}C$ with oxidized, neutralized and reduced atmospheres. The aggregates sintered with oxidized atmosphere showed a clear border between shell and black core area. However, the aggregates sintered with a reduced atmosphere showed only black core area in the entire cross-section of the aggregates. The black core area of the aggregates sintered with a neutralized atmosphere increased with increasing $N_2$ gas flow rates. It was determined that the sintering atmosphere was similar to that of rotary kiln when the CO gas flow was 100 cc/min to make a reduced atmosphere in tube furnace. The water absorption rates of both aggregates from tube furnace with reduced atmosphere and rotary kiln were very similar to each other.

Characteristics of Aerosol Mass Concentration and Chemical Composition of the Yellow and South Sea around the Korean Peninsula Using a Gisang 1 Research Vessel (기상1호에서 관측된 한반도 서해 및 남해상의 에어로졸 질량농도와 화학조성 특성)

  • Cha, Joo Wan;Ko, Hee-Jung;Shin, Beomchel;Lee, Hae-Jung;Kim, Jeong Eun;Ahn, Boyoung;Ryoo, Sang-Boom
    • Atmosphere
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    • v.26 no.3
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    • pp.357-372
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    • 2016
  • Northeast Asian regions have recently become the main source of anthropogenic and natural aerosols. Measurement of aerosols on the sea in these regions have been rarely conducted since the experimental campaigns such as ACE-ASIA (Asian Pacific Regional Aerosol Characterization Experiment) in 2001. Research vessel observations of aerosol mass and chemical composition were performed on the Yellow and south sea around the Korean peninsula. The ship measurements showed six representative cases such as aerosol event and non-event cases during the study periods. On non-event cases, the anthropogenic chemical and natural soil composition on the Yellow sea were greater than those on the south sea. On aerosol event cases such as haze, haze with dust, and dust, the measured mass concentrations of anthropogenic chemical and element compositions were clearly changed by the events. In particular, methanesulfonate ($MSA^-$, $CH_3SO_3^-$), a main component of natural oceanic aerosol important for sulfur circulation on Earth, was first observed by the vessel in Korea, and its concentration on the Yellow sea was three times that on the south sea during the study period. Sea salt concentration important to chemical composition on the sea is related to wind speed. Coefficients of determination ($R^2$) between wind speed and sea salt concentration were 0.68 in $PM_{10}$ and 0.82 in $PM_{2.5}$. Maximum wave height was not found to be correlated to the sea salt concentration. When sea-salt comes into contact with pollutants, the total sea-salt mass is reduced, i.e., a loss of $Cl^-$ concentration from NaCl, the main chemical composing sea salt, is estimated by reaction with $HNO_3$(gas) and $H_2SO_4$(gas). The $Cl^-$ concentration loss by $SO_4^{2-}$ and $NO_3^-$ more easily increased for $PM_{10}$ compared to $PM_{2.5}$. The results of this study will be applied to verifying a dust-haze forecasting model. In addition, continued vessel measurements of aerosol data will become important to research for climate change studies in the future.

Impacts of Elevated $CO_2$ on Algal Growth, $CH_4$ Oxidation and $N_2O$ Production in Northern Peatland (이탄습지에서 이산화탄소의 농도가 조류의 증식, 메탄 산화 및 아산화질소 생성에 미치는 영향)

  • Freeman, Chris;Kang, Ho-Jeong
    • Korean Journal of Ecology and Environment
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    • v.34 no.4 s.96
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    • pp.261-266
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    • 2001
  • Effects of elevated carbon dioxide ($CO_2$) on soil microbial processes were studied in a northern peatland. Intact peat cores with surface vegetation were collected from a northern Welsh fen, and incubated either under elevated carbon dioxide (700 ppm) or ambient carbon dioxide (350 ppm) conditions for 4 months. Higher algal biomass was found under the elevated $CO_2$ condition, suggesting $CO_2$ fertilization effect on primary production, At the end of the incubation, trace gas production and consumption were analyzed using chemical inhibitors. For methane ($CH_4$ ), methyl fluoride ($CH_3F$) was applied to determine methane oxidation rates, while acetylene ($C_2H_2$) blocking method were applied to determine nitrification and denitrification rates. First, we have adopted those methods to optimize the reaction conditions for the wetland samples. Secondly, the methods were applied to the samples incubated under two levels of $CO_2$. The results exhibited that elevated carbon dioxide increased both methane production (210 vs. $100\;ng\;CH_4 g^{-1}\;hr^{-1}$) and oxidation (128 vs. $15\;ng\;CH_4 g^{-1}\;hr^{-1}$), resulting in no net increase in methane flux. For nitrous oxide ($N_2O$) , elevated carbon dioxide enhanced nitrous oxide emission probably from activation of nitrification process rather than denitrification rates. All of these changes seemed to be substantially influenced by higher oxygen diffusion from enhanced algal productivity under elevated $CO_2$.

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Gibberellin Production by Newly Isolated Strain Leifsonia soli SE134 and Its Potential to Promote Plant Growth

  • Kang, Sang-Mo;Khan, Abdul Latif;You, Young-Hyun;Kim, Jong-Guk;Kamran, Muhammad;Lee, In-Jung
    • Journal of Microbiology and Biotechnology
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    • v.24 no.1
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    • pp.106-112
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    • 2014
  • Very few plant growth-promoting rhizobacteria (PGPR) are known to produce gibberellins (GAs). The current study aimed to isolate a phytohormone-producing PGP rhizobacterium from soil and assess its potential to enhance plant growth. The newly isolated bacterium was identified as Leifsonia soli sp. SE134 on the basis of partial 16S ribosomal RNA gene sequence. Application of L. soli culture filtrate significantly increased the biomass, hypocotyl, and root lengths of cucumber seeds as compared with non-inoculated sole medium and distilled water treated controls. Furthermore, the PGPR culture was applied to the GA-deficient mutant rice cultivar Waito-C. Treatment with L. soli SE134 significantly increased the growth of Waito-C rice seedlings as compared with controls. Upon chromatographic analysis of L. soli culture, we isolated, detected and quantified different GAs; namely, $GA_1$ ($0.61{\pm}0.15$), $GA_4$ ($1.58{\pm}0.26$), $GA_7$ ($0.54{\pm}0.18$), $GA_8$ ($0.98{\pm}0.15$), $GA_9$ ($0.45{\pm}0.17$), $GA_{12}$ ($0.64{\pm}0.21$), $GA_{19}$ ($0.18{\pm}0.09$), $GA_{20}$ ($0.78{\pm}0.15$), $GA_{24}$ ($0.38{\pm}0.09$), $GA_{34}$ ($0.35{\pm}0.10$), and $GA_{53}$ ($0.17{\pm}0.05$). Plant growth promotion in cucumber, tomato, and young radish plants further evidenced the potential of this strain as a PGP bacterium. The results suggest that GA secretion by L. soli SE134 might prove advantageous for its ameliorative role in crop growth. These findings can be extended for improving the productivity of different crops under diverse environmental conditions.