• 대한기계학회논문집A
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• 제34권9호
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• pp.1217-1225
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• 2010

소듐을 냉각재로 사용하는 고속로의 증기발생기에서는 소듐과 물의 화학적 반응을 최소화하는 것이 중요한 문제이다. 소듐과 물의 반응 가능성을 줄여 증기발생기의 신뢰성을 향상시키기 위한 한가지 방안으로 이중벽관을 전열관으로 사용하는 증기발생기를 개발하고 있다. 이 증기발생기에서 중요한 현안은 이중벽관에서의 열전달 성능을 향상시키는 문제와 원자로 운전 중에 소듐과 물 반응사고가 일어나기 전에 전열관의 파손을 감지하는 기술을 개발하는 것이다. 이 논문에서는 이 현안을 극복할 수 있는 방안을 제시하였고, 이 기술을 활용하여 증기발생기의 개념을 설계하였다. 또한 이 개념에 적용되는 이중벽관을 설계 및 예비 제작하여 기계적 시험을 수행하였다.

• 에너지공학
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• 제11권2호
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• pp.122-129
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• 2002

액체금속로의 소듐-물 반응사고에 따른 압력거동 분석을 위하여 한국원자력연구소 KALIMER 개발팀이 개발한 SPIKE코드의 해석 모형 및 알고리즘을 소개하였으며 검증 계산 결과를 제시하였다. KALIMER IHTS의 소듐-물 반응사고로 인한 계통내 압력 거동을 분석하였다. 소듐-물 반응사고의 초기는 압력파 전달과 질량 전달 영역으로 구성됨을 확인하였다. 압력파 전달 영역에서의 압력 거동은 계통의 설계 특성과 무관하나 질량 전달 영역에서는 Cover gas 체적과 파열판 파열 압력에 크게 의존함을 확인하였다. KALIMER IHTS의 초기 소듐-물반응사고 해석 결과는 적절한 Cover gas체적과 파열판 압력 설정을 통해 압력 진동이 설계 압력 범위로 조절할 수 있음을 확인하였다.

• 콘크리트학회논문집
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• 제12권5호
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• pp.141-151
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• 2000

Compressive strength, sulfate deterioration factor(SDF) and length change of 5 types of mortars immersed in sodium sulfate solution were observed. As the results of tests, it was found that the sulfate resistance of blended cement mortars were superior to that of portland cement mortars. Pore volume with diameter larger than 0.1 $\mu\textrm{m}$ of 5 types of pastes indicated that the micro-structures of blended cement pastes were denser, due to pozzolan reaction and latent hydraulic properties, than those of portland cement pastes. The XRD, ESEM, EDS and TG analyses demonstrated that the reactants such as ettringite and gypsum were significantly formed in portland cement pastes. Besides, compared with the $Ca(OH)_2$ content of ordinary portland cement pastes immersed in water and sodium sulfate solution, the $Ca(OH)_2$ contents of fly ash blended cement and ground granulated blast-furnace slag cement paste were about 58% and 28% in water, and 55% and 20% in sodium sulfate solution, respectively.

• 한국수소및신에너지학회논문집
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• 제24권6호
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• pp.518-523
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• 2013

This paper describes the reduction of a hydrogen sulfide ($H_2S$) generated from a biogas plant. Micro bubble system is adopted to supply air into the water in the reaction chamber, which can increase the contact area of the supplied air to the reserving water. Two stage reaction chambers having two reaction rooms are designed and manufactured to enhance the reduction rate of a hydrogen sulfide. Sodium hydroxide (NaOH) is also considered to get rid of a hydrogen sulfide. Air volume rate to the water in a reaction chamber is maintained between 0.5 and $1.0m^3/min$. Throughout experimental measurement of the concentration of a hydrogen sulfide by changing the volume of supplied air into the water, reduction rate of a hydrogen sulfide increases as air volume increases. Adding sodium hydroxide to the water with the air supply can reduce effectively a hydrogen sulfide up to 99.5% from biogas. It is noted that a hydrogen sulfide generated by a biogas plant can reduce by supplying micro bubble air and sodium hydroxide effectively.

• 한국응용과학기술학회지
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• 제15권3호
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• pp.33-37
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• 1998

The hardening test of gelatin with 2,4-dichloro-6-hydroxy-1,3,5-triazine mono sodium salt was studied at pH 5, 7, 8 and about increasing temperature, respectively. The hardener was prepared by the reaction of cyanuric chloride with sodium hydroxide, disodium hydrogenphosphate-12-water and trisodium phosphate-12-water in the presence of water. The product was identified by elemental analyzer. IR spectrophotometer. Novel hardener can be used in photographic emulsion and showed very good hardening effect.

• KSBB Journal
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• 제23권4호
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• pp.335-339
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• 2008

Biodiesel is an alternative and renewable energy source, which is hoped to reduce global dependence on petroleum and environmental problem. Biodiesel produced from a variety of oil sources such as vegetable oil, animal fat and waste oils, and has properties similar to those associated with petro-diesel, including cetane number, volumetric heating value, flash point, viscosity and so on. In this study, we investigate the effect of quality of raw materials on alkali-catalyzed transesterification for producing of biodiesel. The increase of content of free fatty acid and water in oil were caused the sharp decrease of conversion yield. Also, the low purity of methanol in reactant was inhibited the reaction rate. In the case of addition of sodium sulfate as absorbent to prepare catalyst solution, the content of fatty acid methyl ester in product was increased more about 1.6% than that of control. However, the addition of zeolite, sodium chloride and sodium sulfate as absorbent in reactant to remove water generated from reaction did not show any enhancement in the reaction yield. This result may provide useful information with regard to the choice and preparation of raw materials for more economic and efficient biodiesel production.

• 공업화학
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• 제32권5호
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• pp.532-540
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• 2021

4-도데카노일옥시벤젠술폰산나트륨(sodium dodecanoyl-4-oxybenzenesulfonate; DOBS) 염은 저온에서도 효과적인 표백력과 살균력을 나타내는 물질이다. 본 연구에서는 물(W)-극성 비양자성 용매 계를 사용하는 알칼리 조건하에서 dodecanoyl chloride와 sodium 4-hydroxybenzene sulfonate로부터 DOBS의 온화하고 효율적인 합성방법을 조사하였다. 먼저 물만을 용매로 사용하고 온도 또는 시간을 변화시키며 반응한 결과, 수율은 30 ℃와 1 h 이상의 반응 조건에서 대부분 약 5% 정도로 낮게 나타났다. 효율적인 용매 계를 발견하기 위하여 극성 비양자성 용매의 종류를 변화시키며 물과 혼합하여 제조한 다양한 용매계에서 수율에 미치는 영향을 평가하였다. 수율은 아세톤(acetone; AC)과 물을 혼합한 용매 계에서 가장 우수하였으며, 온화한 반응조건(30 ℃, 1 h 및 상압)의 반응에서 약 82%의 높은 값을 나타냈다. 제조한 DOBS는 높은 표백력 및 살균력을 보여 표백활성화제로서 활용이 가능함을 확인하였다.

• Nuclear Engineering and Technology
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• 제48권5호
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• pp.1162-1173
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• 2016

In this paper, we describe a physicomathematical model of the processes that occur in a sodium circuit with a variable flow cross-section in the case of a water leak into sodium. The application area for this technique includes the possibility of analyzing consequences of this leak as applied to sodium-water steam generators in fast neutron reactors. Hydrodynamic processes that occur in sodium circuits in the event of a water leak are described within the framework of a one-dimensional thermally nonequilibrium three-component gas-liquid flow model (sodium-hydrogen-sodium hydroxide). Consideration is given to the results of a mathematical modeling of experiments involving steam injection into the sodium loop of a circulation test facility. That was done by means of the computer code in which the proposed model had been implemented.

• Nuclear Engineering and Technology
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• 제29권3호
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• pp.240-250
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• 1997

Liquid sodium is widely used as a coolant of LMR(Liquid Metal Reactor) because of its physical and nuclear properties. However, the liquid sodium is very chemically reactive with oxygen and water so that the study on the sodium fire plays an important role in the LMR safety analysis. In this study, a sodium fire model is suggested to analyze the sodium pool fire where both the flame and the reaction products are considered. And also, sodium pool fire analysis computer code, SOPA, is developed. The sensitivity study on the experimental parameters such as the thermal radiation from flame to atmospheric gas, the vessel cooling and the duration of sodium spill was performed. The results showed good agreements with experimental data in the literature.

• 공업화학
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• 제10권4호
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• pp.531-536
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• 1999

누출시험 장치를 이용하여 미량 물 누출 실험을 수행하였다. 2.25Cr-1Mo 시편의 누출경로는 나트륨-물 반응 생성물에 의해 plugging되는 경우가 발생하였으나, 대부분 re-open상태를 나타내었다. 또한 누출 경로가 완전 re-open된 후 나트륨 부위에서 시편의 self-wastage pattern은 온도에 영향을 받지 않음을 알 수 있었으며, 누출경로가 re-open 되면서 나타나는 defected 크기는 대략 5 mm 이내임을 알 수 있었다. 누출 경로가 완전 re-open 되는데 걸리는 시간은나트륨 온도가 높을수록 짧게 나타났으며, 평균적으로 $450^{\circ}C$에서 143분, $475^{\circ}C$의 경우 40.7분, $510^{\circ}C$의 경우 34.7분을 나타내었다.