• Title/Summary/Keyword: soda glass

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Waste Glass as an Activator in Class-C fly Ash/GGBS based Alkali Activated Material

  • Sasui, Sasui;Kim, Gyu Yong;Lee, Sang Kyu;Son, minjae;Hwang, Eui Chul;Nam, Jeong Soo
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2020.11a
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    • pp.77-78
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    • 2020
  • An alkaline activator was synthesized by dissolving waste glass powder (WGP) in NaOH-4M solution to explore its effects on the Class-C fly ash (FA) and ground granulated blast furnace slag (GGBS) based alkali-activated material (AAM). The compressive strength and porosity were measured, and (SEM-EDX) were used to study the hydration mechanism and microstructure. Results indicated that the composition of alkali solutions was significant in enhancing the properties of the obtained AAM. As the amount of dissolved WGP increased in alkaline solution, the silicon concentration increased, causing the accelerated reactivity of FA/GGBS to develop Ca-based hydrate gel as the main reaction product in the system, thereby increasing the strength. Further increase in WGP dissolution led to strength loss, which were believed to be due to the excessive water demand of FA/GGBS composites to achieve optimum mixing consistency. Increasing the GGBS proportion in a composite also appeared to improve the strength which contributed to develop C-S-H-type hydration.

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Investigation of the 19th~20th century Hat String Materials at the National Folk Museum of Korea: Amber, Tortoise Shell, Plastics, Glass (국립민속박물관 소장 19~20세기 갓끈 재질 조사: 호박, 대모, 플라스틱, 유리를 중심으로)

  • Oh, Joon-Suk;Lee, Sae-Rom;Hwang, Min-Young;Noh, Soo-Jung;Lee, Young-Min;Park, Sung-Hee;Lim, Sung-Hee
    • Korean Journal of Heritage: History & Science
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    • v.51 no.4
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    • pp.66-83
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    • 2018
  • This article focuses how the materials of hatstrings of the 19th to 20th century gat, the Korean top hat for men among the collections of National Folk Museum of Korea, was transformed after port opening treaties with overseas since 1876. As a result of analyzing the materials of the hatstrings, amber, tortoiseshell, wood and bamboo as the traditional materials were used, and ivory, glass (soda glass, lead glass, alkali mixed glass) and plastics (cellulose nitrate, phenol-formaldehyde, polystyrene, acryl) were newly used for the hatstrings. Bamboo, wood and amber were the most frequently used materials. Bamboo was mainly used for the pipe of hatstring and were combined with beads and central decorations of other materials. This shows the trend of bamboo hatstring according to the simplification of the clothing and the culture by Regent Heungseon Daewongun. Ambers were used in the central decorations and beads and the origin of ambers was baltic amber just like the amber relics found in Korea. Compositions of glass were soda glass and alkali mixed glass which were excavated or handed down in Korea from ancient times to Joseon dynasty. But in the case of lead glass, Na2O was detected and it is considered to be a new type lead glass for crafts which came from overseas after port opening since 1876 because it showed the characteristic that it deviates from the lead glass component found in Korea. Plastics such as cellulose nitrate and phenol-formaldehyde were used as new synthetic materials to replace traditional materials such as tortoiseshell, amber, and coral as in the West. Cracks, crazing, crumbly and yellowing of cellulose nitrate of hatstrings were observed by deterioration. The survey of the materials of the 19th to 20th century hatstrings among the collections of National Folk Museum of Korea showed that the introduction of new materials such as glass and plastics were used to replace natural materials such as tortoiseshell and amber along with the use of traditional materials after port opening since 1876.

A study on the flaking phenomenon by the reaction between glass and solution (유리와 수용액의 반응에 의한 Flaking 현상 연구)

  • 김명석;장원식;심영재;이기강;김정환
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.8 no.1
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    • pp.179-186
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    • 1998
  • We have been investigated the effects of the initial pH of the aquous solution, reaction temperature and time for the flaking of the soda-lime glass container. Flaking of glass occuurred in the cases of the $121^{\circ}C$, above pH 11 of solution with no $Mg^{2+}$ ions in solution. The pH of the solution approached to pH 10 under the conditions of below pH 9 of start solution. The flaking mechanism of the glass seem to be composed of formation of leached layer of $Ca^{2+}$ and $Na^{2+}$ ion and separation of these layers during the cooling by the difference of thermal expansion between leached layer and glass surface. The leaching of alkali ions in glass depends on the pH condition of the start solution and the temperature. In the case of $Mg^{2+}$ ions are added, $Mg^{2+}$ ions accelerate the flaking of the sodalime glasses and forms the magnesium silicate compound which result in the decrease of the pH of the solution.

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ANALYSIS OF THIN FILM POLYSILICON ON GLASS SYNTHESIZED BY MAGNETRON SPUTTERING

  • Min J. Jung;Yun M. Chung;Lee, Yong J.;Jeon G. Han
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2001.11a
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    • pp.68-68
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    • 2001
  • Thin films of polycrystalline silicon (poly-Si) is a promising material for use in large-area electronic devices. Especially, the poly-Si can be used in high resolution and integrated active-matrix liquid-crystal displays (AMLCDs) and active matrix organic light-emitting diodes (AMOLEDs) because of its high mobility compared to hydrogenated _amorphous silicon (a-Si:H). A number of techniques have been proposed during the past several years to achieve poly-Si on large-area glass substrate. However, the conventional method for fabrication of poly-Si could not apply for glass instead of wafer or quartz substrate. Because the conventional method, low pressure chemical vapor deposition (LPCVD) has a high deposition temperature ($600^{\circ}C-1000^{\circ}C$) and solid phase crystallization (SPC) has a high annealing temperature ($600^{\circ}C-700^{\circ}C$). And also these are required time-consuming processes, which are too long to prevent the thermal damage of corning glass such as bending and fracture. The deposition of silicon thin films on low-cost foreign substrates has recently become a major objective in the search for processes having energy consumption and reaching a better cost evaluation. Hence, combining inexpensive deposition techniques with the growth of crystalline silicon seems to be a straightforward way of ensuring reduced production costs of large-area electronic devices. We have deposited crystalline poly-Si thin films on soda -lime glass and SiOz glass substrate as deposited by PVD at low substrate temperature using high power, magnetron sputtering method. The epitaxial orientation, microstructual characteristics and surface properties of the films were analyzed by TEM, XRD, and AFM. For the electrical characterization of these films, its properties were obtained from the Hall effect measurement by the Van der Pauw measurement.

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Compositions and Characteristics on the Glass Beads Excavated from Ancient Tombs of Jeongchon in Naju, Korea (나주 정촌 고분군 출토 유리구슬의 화학 조성과 특징)

  • Yun, Ji Hyeon;Han, Woo Rim;Han, Min Su
    • Journal of Conservation Science
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    • v.34 no.2
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    • pp.119-128
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    • 2018
  • This study revealed the material composition and characteristics of 19 glass fragments excavated from stone chamber No. 1 of Jeongchon Tomb in Naju through chemical composition analyses and observations. These characteristics were compared with the characteristics of the glass fragments excavated from No. 3 tomb of Bogam-ri in Naju. The purpose of this study was to identify the characteristics of the ancient glass of the Mahan-Baekje period. The glass fragments excavated from the Jeongchon Tombs can be classified into purplish blue, light-purplish blue, greenish blue, green, and mixture of purple blue and purple, based on their color. These beads were made using a drawn and casting technique. In addition, blue glass fragments were primarily excavated form No. 3 tomb of Bogam-ri. However, red glass fragments were not excavated from either of the tombs. According to chemical composition analyses, soda glass group and potash glass group were common in both the tombs. Additionally, alkali mixed glass group and lead barium glass group were excavated from Jeongchon Tombs and No. 3 tomb of Bogam-ri, respectively. The glass fragments excavated from No. 3 tomb of Bogam-ri have more color variations than those excavated from Jeongchon Tombs.

A study on the fabrication of foamed glass by using refused coal ore and its physical properties (석탄 폐석을 이용한 발포유리의 제조 및 물리적 특성 연구)

  • Lim, Tae-Young;Ku, Hyun-Woo;Hwang, Jong-Hee;Kim, Jin-Ho;Kim, Jung-Kook
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.21 no.6
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    • pp.266-273
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    • 2011
  • Foamed glass was fabricated by using glass powder and foaming agents. For the glass powder, we used sodalime glass which's manufactured by using refused coal ore obtained as by-product from Dogye coal mine in Samcheok. And for the foaming agents, we used Calcium carbonate, Calcium phosphate and powder of shale type refused coal ore itself which has high content of carbon materials. We additionally used liquid binder for forming, and mixed together. And we formed rectangular shape and treated $800^{\circ}C$ for 20 min in an electrical furnace. The various kinds of foam glass samples were fabricated according to the kinds of foaming agents. The physical properties of samples, as specific gravity and compressive strength, were measured. Pore structure of each samples were investigated too. Foam glass with specific gravity of 0.4~0.7 and compressive strength of 30~72 kg/$cm^2$. Especially we get satisfying foam glass sample with low specific gravity of 0.47 and high compressive strength of 72 kg/$cm^2$ by the use of liquid calcium phosphate as foaming agent. It also had small and even shape of pore structure. Therefore, it is concluded that refused coal ore can be used for raw materials to manufacture secondary glass products such as a foamed glass panel for construction and industrial materials.

A Study on the Development of Equation from Calculation about Emissions of Greenhouse Gases in Glass Manufacturing Industries (유리 제조 산업분야의 온실가스 배출량 산정식 개발에 관한 연구(I))

  • Chung, Jin-Do;Ko, Byong-Su;Kim, Jang-Woo;Chae, Soo-Joh;Koo, Kyung-Wan;Hwang, Seung-Min
    • Journal of Environmental Science International
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    • v.18 no.5
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    • pp.509-515
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    • 2009
  • The aim of this study is investigated greenhouse gas emissions of glass industry, and when calculates greenhouse gas emission, using formula(Tier 3) advising in IPCC(Intergovernmental Panel on Climate Change) and using self designed formula(Tier 3+) authors of this study. Studied to propose calculation formula that can compare these two calculation results and apply to domestic. Formula of Tier 3 calculated to theoretical composition of carbonate material, And Formula of Tier 3+ calculated on the basis of chemical substance formation table that get from glass manufacture company(The S company). As a result, Dolomite, Soda ash, Limestone, Industrial Barium carbonate is calculated value of Tier 3+ lower than value of Tier 3, And Industrial Potassium carbonate, Industrial Strontium carbonate was calculated value of Tier 3 lower than value of Tier 3. This study finding, formula of Tier 3+ has higher confidence than formula of Tier 3 when consider revision about purity of injection raw material. And hereafter, When calculate greenhouse gas emissions about nonmetallic mineral industry, use of Tier 3+ is considered that should be encouraged.

A study on the Material and Characteristics of Glass Beads from Oc Eo Site, Vietnam (베트남 옥 에오(Oc Eo) 유적 출토 유리구슬의 재질 및 특성 연구)

  • Kim, Gyu Ho;Yun, Ji Hyeon;Kwon, Oh Young;Park, Jun Young;Nguyen, Thi Ha
    • Korean Journal of Heritage: History & Science
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    • v.49 no.2
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    • pp.158-171
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    • 2016
  • The observation and analysis results of 9 glass bead samples collected from Oc Eo site in Vietnam, an outport of the ancient port city Funan in East Asia, are as follows. The type of glass beads is round, the colors are reddish brown, greenish blue, green, black and purplish blue, and the chemical composition is soda glass group. This means that they are similar in type, color and chemical compositions to glass beads from the ancient Korean peninsula. There are limitations in data because the glass beads are not from excavation investigation but from earth surface investigation. But it is significant that similar making technique and chemical composition are being observed in both the glass beads from Oc Eo and those of Korea. According to "Nihon Shoki" Kinmeiki, Baekje king sent Funan's goods and 2 slaves to Japan in 543. It is clear that there were direct or indirect exchanges between Baekje and Funan. The possibility has grown that glass beads could be included among goods.

Experimental study of filamentation using ultra fast pulse laser in transparent material (극초단 펄스 레이저를 사용한 유리 내부의 필라멘테이션에 대한 실험적 연구)

  • Choi, Won-Suk;Yoon, Ji-Wook;Kim, Joohan;Choi, Jiyeon;Chang, Won-Seok;Kim, Jae-Goo;Choi, Doo-Sun;Whang, Kyoung Hyun;Cho, Sung-Hak
    • Laser Solutions
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    • v.16 no.1
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    • pp.5-9
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    • 2013
  • We have successfully formed filament inside of a transparent soda-lime glass using a Ti:sapphire based femtosecond laser. To make filament form, keeping the laser intensity higher than critical intensity is essential. Also each of the machining parameters plays an important role for the formation of filament. In this paper, we study what parameter can possibly influence for formation of filament, and we introduce an application using filamentation by femtosecond laser for transparent material.

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The effect on characteristic of ITO(glass) by polyimide thin film process (Polyimide 막 공정이 ITO Glass의 특성에 미치는 영향)

  • Kim, Ho-Soo;Kim, Han-Il;Jung, Soon-Won;Koo, Kyung-Wan;Han, Sang-Ok
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2002.07b
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    • pp.857-860
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    • 2002
  • The material that is both conductive in electricity and transparent to the visible-ray is called transparent conducting thin film. It has many field of application such as solar cell, liquid crystal display, transparent electrical heater, selective optical filter, and a optical electric device. In this study, indium tin oxide (ITO ; Sn-doped $In_2O_3$) thin films were deposited on $SiO_2$/soda-lime glass plates by a dc magnetron sputtering technique. The crystallinity and electrical properties of the films were investigated by X-ray diffraction(XRD), atomic force microscopy (AFM) scanning and 4-point probe. The optical transmittance of ITO films in the range of 300-1000nm were measured with a spectrophotometer. As a result, we obtained polycrystalline structured ITO films with (222), (400), and (440) peak. Transmittance of all the films were higher than 90% in the visible range.

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