• Journal of Energy Engineering
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• v.27 no.2
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• pp.55-60
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• 2018

In this study investigated the Controlled Low Strength Materials using coal ash and steel slag(KR slag) as the main material in the thermal power plant classified as waste resource. Bottom ash and KR slag are mixed at a ratio of 7: 3 to expand the use of industrial by-products through carbonate($CO_2$-fixation) reactions and inhibit the exudation of heavy metals. The results showed that the water content increased as the content of bottom ash increased. It was confirmed that as the powder content increased, the bleeding ratio decreased. Also, as the content of one kind of ordinary portland cement (OPC) decreased, activation of hydration reaction decreased and compressive strength decreased. However, when the mixed composition is appropriately adjusted, the compressive strength of 2.0 MPa required for the controlled low-strength material can be satisfied.

• Journal of Conservation Science
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• v.26 no.2
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• pp.171-182
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• 2010

The slag excavated from Gyesil-ri in Gongju, Yeonje-ri in Cheongwon and Beopcheonsaji (temple) site in Wonju are analyzed by X-ray Fluorescence Analyzer, metallurgical microscope, SEM-EDS etc., for chemical composition and microstructure to figure out the raw material and the iron manufacturing technique. First of all, as a result of principal component analysis, the total Fe-content of slag from Gyesil-ri is 39 to 44% and the modified rate is 15 to 21%, which is common in ancient iron slag. Yeonje-ri site is found the ancient iron-smelting furnace. The total Fe-content of slag from Yeonje-ri is 41 to 43% and modified rate is 18~30%, which is also the general value in the ancient slag. However only slag is excavated in the residential area at Beopcheonsaji site and there is no iron making relic. In addition, the result of principal component analysis contains that the total Fe-content of Beopcheonsaji site is 52 to 57%, and modified rate is 8 to 14%. It shows that the total Fe-content of Beopcheonsaji site is higher than relic from Gyesil-ri and Yeonje-ri and the modified rate is lower than other sites. This results mean that recollecting rate of Fe in Beopcheonsaji site is lower than other sites. Also, as a result of minor elements analysis, the slag from Gyesil-ri has the higher level of Ti, V and Zr than other sites and the microstructure are observed as magnetite and ulvospinel, so that the raw material of slag is iron sand. But the slag from Yeonje-ri and Beopcheonsaji site are identified to use iron ore. As a result of microstructure observation, fayalite, gray-columnar crystal, is found in the slag from Yeonje-ri and big wustite as main phase is observed in the slag from Beopcheonsaji site. This study show that the slag from Yeonje-ri is made of smelt ash produced during smelting works and the slag from Beopcheonsaji site is made of forging ash produced during forging work concerning the excavated location and the microstructure.

• Journal of the Korean Ceramic Society
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• v.39 no.1
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• pp.99-107
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• 2002

Impedance Spectroscopy (IS) has been used to study microstructure and hydration mechanism of cement pastes. In this work, the early hydration behaviour of portland cement paste with different blame values and contents of blast-furnace slag was investigated by IS. As slag was added to portland cement, the values of $R_{t(s+1)}$ (the solid-liquid phase resistance) and $R_{t(int)}$ were decreased in the early hydration period. It showed that hydration of cement paste containing slag was slower than it of the reference cement paste. As the content of slag was increased, the values of $R_{t(s+1)}$ was decreased. Furthermore, the diameter of semicircle, $R_{t(int)}$ observed at 72 hours was decreased with the increment of slag content. However, the values of $R_{t(s+1)}$ and $R_{t(int)}$ were increased with blame value of slag from the early hydration period.

• Journal of the Korea institute for structural maintenance and inspection
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• v.20 no.2
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• pp.26-33
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• 2016

The alkali-slag-red mud(ASRC) cement belongs to clinker free cementitious material, which is made from alkali activator, blast-furnace slag(BFS) and red mud in designed proportion. This study is to investigate strength and pore characteristics of alkali-activated slag cement(NC), clinker free cementitious material, and ordinary portland cement(C) mortars using polymer according to red mud content. The results showed that the hardened alkali-activated slag-red mud cement paste was mostly consisted of C-S-H gel, being very fine in size and extremely irregular in its shape. So the hardened ASRC cement paste has lower total porosity, less portion of larger pore and more portion of smaller pore, as compared with those of hardened portland cement paste, and has higher strength within containing 10 wt.(%) of alkali-activated slag cement(NC) substituted by red mud.

• Journal of the Korea Institute of Building Construction
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• v.2 no.2
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• pp.145-150
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• 2002

The hydration of cement paste occurs when the cement is miked with water. During the hydration, hydration heat causes the thermal stress depending on the site of concrete and the cement content. Especially in the high-strength concrete, we must give care to the concrete due to its large cement content. In this study conduction calorimeter and concrete insulation hydration heat meter were used to investigation the hydration heat characteristics of cement and concrete. To reduce hydration heat of high-strength concrete, several types of replacement of fly-ash and blast-furnace slag powder were used in this experiment. As a result of this study, it was found that hydration heat of high-strength concrete was reduced by replacement of fly-ash and blast-furnace slag powder. In case of high-strength concrete using blast-furnace slag powder, the max-heat arrival time was delayed but an effect of heat reduction was lower than a case of high-strength concrete using fly-ash, because it was considered that the heat-dependence property of blast-furnace slag powder was higher than that of fly-ash.

• Journal of the Korean Ceramic Society
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• v.48 no.6
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• pp.589-594
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• 2011

Raw mix of molten clinker was fabricated using blast furnace slag as starting material. Raw mix was melted at 1620$^{\circ}C$ for molten clinker fabrication. It was found that molten clinker contained alite and belite equivalent to OPC clinker mineral by optical microscope and SEM. The size of alite was 10~50 ${\mu}m$ and that of belite was 20~80 ${\mu}m$. This result thought to be attributed low $Al_2O_3$ content and cooling condition. Interstitial phase increased with blast furnace slag content and gehlenite was formed by the condition of LSF and SM. So raw mix with 27~41% blast furnace slag could be converted into cement clinker by appropriate choice of melting andcooling methods in this study.

• Proceedings of the Korea Concrete Institute Conference
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• 2002.10a
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• pp.579-584
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• 2002

In this research, the physical properties of self compacting concrete using ground granulated blast furnace slag as a part of cement were investigated. Concrete using ground granulated blast furnace slag was prepared with various ground granulated blast furnace slag replacement(20~80 volume %) for cement and the quantities of coarse aggregate in concrete were 50%, 55% and 60% of ratio of absolute volume of coarse aggregate. The workability, flowing characteristics, air content and compressive strength of concrete using ground granulated blast furnace slag were tested and the results were compared with those of ordinary portland cement concrete. In the experiment, we acquired satisfactory results at the point of flowing characteristics and strengths of concrete using ground granulated blast furnace slag within tile replacement ratio of 50% and the optimum quantity of coarse aggregate in concrete was found to be 50%~55% of ratio of absolute volume of coarse aggregate.

• Journal of the Korean Ceramic Society
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• v.16 no.4
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• pp.237-242
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• 1979

In order to improve hydration reactivity of blast furnace slag, it's composition was changed by adding of CaO. The slags were quenched in water at 1,400℃. Hydration reactivityof modified slags was studied by x-ray diffractometer, conduction calorimeter and so on. Experimental results were summarized as follows. 1. Glass content and hydration reactivity of slag depend significantly on quenching temperature of the slag melt. To enhance the reactivity, slag melts which belongs to Frenkel-type liquid, must be quenched above 1,300℃. 2. Vitrification of slag melts was confirmed as CaO/SiO2 ratio increased up to 1.57 with flux, 1.51 without flux, also their hydration reactivity was improved.

• Proceedings of the Korea Concrete Institute Conference
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• 2003.11a
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• pp.322-325
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• 2003

Recently, as quality river aggregates like sands and gravels become scarce, use of crushed stones and sands, seashore sands, and seashore gravels is increasing abruptly. And, aggregates recycled from slags and waste concretes are used. However, since the converter slag easily expands and breaks due to free lime, differently from the blast-furnace slag, it is not suitable for use as concrete aggregates. Since the atomized steel slag aggregate has slippery surface and spherical shape, the mortar flowing characteristics improved as the atomized steel slag content increases, without regard to the aggregates coarseness and water/cement ratio. The flow characteristics loss rate of the mortar manufactured from steel slag aggregates was similar to that of the mortar manufactured from washed sand only. The compact strength of the mortar manufactured from coarse PS Ball were larger than that manufactured from washing sand only.

• Proceedings of the Korea Concrete Institute Conference
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• 1997.10a
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• pp.215-222
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• 1997

Flow experimental on not to be solid mortar which use Quenched Blast-furnace Slag as a fine aggregate was carried out for basic research data about fundamental study of application possibility of Quenched Blast-furnace Slag as a fine aggregate. It gives following result. The substitution rate is inversely proportional to Flow and C/S-rate same that. The relation with W/C-rate augment appear proportional : in case of C/S-rate, 1:3 increasing degree is a half of sand mortar that. Consequencely, Quenched Blast-furnace Slag motar is a counteraction to Flow in as same water content per unit. But suitable substitution rate and C/S-rate influence a little to the mortar consistency. And that reason, if C/S-rate and substitution rate will be regulated when we mix the mortar with quenched Blast-furnace Slag. that will be economic mixture.