• 제목/요약/키워드: site contaminants

검색결과 138건 처리시간 0.02초

오염토양의 효율적 조사기법과 측정불확도의 평가방법 (Cost-effective Investigation on Contaminated Land and Assessment of Measurement Uncertainty)

  • 이종천
    • 자원환경지질
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    • 제37권1호
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    • pp.49-59
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    • 2004
  • The concectration and distribution of contaminants obtained from a contaminated land investigation or an environmental geochemistry survey constitutes the basis of a decision-making process on environmental policies or of scientific researches. As the quality of data determines the reliability of the result, the investigation plan should be adjusted according to the purpose of the investigation. In general, the effort to improve the data quality had been focused mainly on the QA/QC procedures in laboratories. The rapid progress of analytical instrument has also contributed toward improving the analytical precision to a sacrificable degree. Nevertheless, in many cases, it is not the analytical precision that needs improvement for the better precision of overall measurement process: it is rather during the sampling process in the field that is responsible for the poor precision. To assess the data quality on a measured value, ISO recommends to provide information on "measurement uncertainty" along with the measured value. The measurement uncertainty in an environmental measurement context can be explained as the statistical number that expresses the degree of the uncertainty stemming from the sampling and analytical procedures. There is a cost involved in order to improve the precision of sampling and analytical methods so as to decrease the degree of measurement uncertainty. The economical point of compromise in an investigation planning can be achieved when the allowable degree of uncertainty has been set before-hand. The investigation can then be planned accordingly not to exceed the uncertainty limit. Furthermore, if the measurement uncertainty estimated from the preliminary investigation can be separated into sampling and analytical uncertainties, it can be used as a criterion where the resources for the investigation should be allotted cost-effectively to reinforce the weakest link of the whole investigation process. This paper aims to present a method of estimating the level of measurement uncertainty of a measured contamination concentration at a site used as an example and to show how the estimated uncertainty can be applied to serve the particular purpose of an investigation.

호흡량에 기준한 강둑여과지 주변 표층토의 무기질소 변환 (Biotransforamtion of inorganic nitrogens in soil of near bank filtration sites using respirometer)

  • 공인철;배진희;최은영;김승현
    • 한국토양환경학회지
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    • 제4권3호
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    • pp.35-43
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    • 1999
  • 강둑여과의 적지로 판단되는 지역의 배후 농경지 표층토에 대한 무기질소 변환 활동도를 호흡량 측정기에서 소비한 산소량에 기준하여 조사하였다. 초기 표층토 pH(약 4.8~5.7)를 변화시키지 않고 수분함량을 약 20%로 조정한 상태에서 무기질소의 변환을 관찰한 결과 대조군과 실험군의 뚜렷한 호흡량 및 무기질소변환은 관찰할 수 없었고 조사한 실험조건에서 수분 25%, pH 8 정도에서 가장 활발한 미생물 활동도가 관찰되었다. 또한 초기 ${NH_4}_2$$SO_4$400 mg $NH_4$-N의 농도에서 98%정도의 질산화가 조사되었으나 탈질화는 거의 발생하지 않았다.

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광물찌꺼기에 함유된 오염물질의 안정화를 위한 표면 차폐재의 성능 평가 (Evaluation of Surface Water-preventing Materials on Stabilization of Contaminants in Tailings)

  • 김영규;정명채;김중열;김유성;이진수;박관인
    • 한국지하수토양환경학회지:지하수토양환경
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    • 제16권4호
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    • pp.53-61
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    • 2011
  • This study examined evaluation on stabilization of major and trace elements in tailings by various surface water-preventing materials. Six columns were filled with tailings of the Sinlim mine, then covered with tailings only, compacted soils, clay, soil-bentonite mixture, pozzolan and bentonite mat. After injection of artificial rain water, the leachate was sampled with times (3, 6, 9 and 12 pore volume) and analysed for major (Ca, Na, Mg, K) and trace elements (As, Cd, Cu, Pb, Zn) by ICP-AES. With exception to pozzolan type, the pH values of leachate from the other types became stabilized from 5.5 to 7.5, and EC (electric conductivity) of leachate from them decreased with times. For the pozzolan type, however, the pH and EC of leachate increased with time due to its alkalinity producing system. Concentrations of most major and trace elements in leachate decreased and stabilized with time. Consequently, soil-bentonite mixed cover shows the best ability of water-preventing and reducing mobility of elements in tailings site.

대전광역시 소유역에서 합류식 하수관거 월류수(CSOs)의 배출특성 모델링 (Modeling of Discharge Characteristics of Combined Sewer Overflows(CSOs) from a Small Urban Watershed in Daejeon City)

  • 김정곤;고익환
    • 대한환경공학회지
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    • 제28권6호
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    • pp.654-660
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    • 2006
  • 본 연구에서는 대전천에 위치한 오정천지역의 소유역을 대상으로 CSOs 배출특성에 관한 모델링을 실시하였다. SWMM을 이용하여 대상유역에서 $2001{\sim}2004$년까지의 연간 유량, 수질, 및 부하량 변화에 대하여 모의를 실시하였다. 모의결과에 의하면, 강우에 의해 발생된 SS 유출부하량은 강우가 집중되는 $7{\sim}8$월에 가장 높게 나타났으나, 이때 강우의 증가에 비하여 부하량의 증가는 크지 않았는데 이는 강우가 잦은 $7{\sim}8$월에는 짧은 건기일수로 인하여 유출수의 SS농도가 낮아졌기 때문이다. $2001{\sim}2004$년 동안의 유량과 수질을 기초로 유출부하량을 산정한 결과 SS가 연간 하천에 미치는 부하량은 건기에 9.3%, 우기에 90.7%로 우기시에 미치는 영향이 매우 큰 것으로 나타났다. 우기시에 우수토실에서 월류를 통해 유출되는 CSOs는 38.4%, 차집관거로 차집 되어 하수처리장 방류구를 통해 방류되는 부분은 61.6%로 산정되었다.

제주항 내에 서식하는 신복족류 Thais clavigera의 연중 생식주기 및 임포섹스 현상에 관한연구 (Report on the Annual Reproductive Cycle and Imposex Phenomenon of the Rock-Shell, Thais clavigera in Jeju Port)

  • 양현성;김봉규;박흥식;최광식
    • 한국패류학회지
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    • 제26권1호
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    • pp.97-105
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    • 2010
  • 제주 항 내에 서식하는 대수리 Thais clavigera를 조직학적 방법을 이용하여 1998년 3월부터 1999년 2월까지 생식소 발달과 생식주기 그리고 imposex 현상에 대해 조사하였다. 조직학적 관찰 결과, 배우자형성은 암,수 모두 10월에 처음 시작 되었고, 성숙한 알들은 주로 5월에서부터 7월 사이에 관찰되었다. 생식소단면적 지수 역시 알이 성숙하는 5월과 7월 사이 급격히 증가하였으며, 8월에 급격히 낮아져, 7월과 8월 사이에 집중적인 산란이 있었던 것으로 사료되었다. 유기주석화합물에 의한 imposex 현상의 진행 정도를 나타내는 RPSI는 월 평균 59.5-173.4%로 다른 지역에 비하여 비교적 높게 나타났으며, 이는 제주 항 내의 유기주석화합물에 의한 것으로 추정되었다.

도로노면 유출수의 비점오염원 배출 특성(1): 기본 수질 항목 (Characteristics of Non-point Pollutants from the Road Runoff (1): Water Quality)

  • 박상우;오재일;최영화;서정우
    • 상하수도학회지
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    • 제21권2호
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    • pp.225-233
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    • 2007
  • Road runoff water is one of the non-point sources (NPSs) of pollution negatively influencing drinking water source. Numerous road runoff NPS waters have been studied for over the last decade. However, the sources of pollution can be conditional, seasonal, or accidental. Therefore, measurement of pollutant loadings in different site is necessary to estimate the effect of road runoff water. The objective of this study was to examine the quality of road runoff water from a city bridge in Seoul, Korea. This study was conducted for two years to assess annual discharge pollution loads. In this study, key water quality parameters including chemical oxygen demand ($COD_{Cr}$), biochemcial oxygen demand ($BOD_5$), total nitrogen (T-N), total phosphorus (T-P), and suspended solid (SS) were measured at 18 different events. The results showed that typically the pollutant concentrations are higher at the beginning of each event and decrease afterwards. The first 20% of the volume of the runoff from each event is transporting 46% ($COD_{Cr}$), 48% ($BOD_5$), 50% (T-N), 34% (T-P), 30% (SS), respectively. The event mean concentrations (EMCs) were $COD_{Cr}$ (199 mg/L), $BOD_5$ (41.2 mg/L), T-N (7.97 mg/L), T-P (0.42 mg/L) and SS (113 mg/L). Although the results were consistent with the previous study (Barbosa and Hvitved-Jacobsen, 1999), $COD_{Cr}$, $BOD_5$, T-N exhibit a stronger first flush effect compared to the other contaminants.

한국의 경사지 밭의 토양 및 물의 보전 관리 전략 (Management Strategies to Conserve Soil and Water Qualities in the Sloping Uplands in Korea)

  • 양재이;유진희;김시주;정덕영
    • 농업과학연구
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    • 제37권3호
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    • pp.435-449
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    • 2010
  • Soils in the sloping uplands in Korea are subject to intensive land use with high input of agrochemicals and are vulnerable to soil erosion. Development of the environmentally sound land management strategy is essential for a sustainable production system in the sloping upland. This report addresses the status of upland agriculture and the best management practices for the uplands toward the sustainable agriculture. More than 60% of Korean lands are forest and only 21% are cultivating paddy and upland. Uplands are about 7% of the total lands and about 62% of the uplands are in the slopes higher than 7%. Due to the site-specificity of the upland, many managerial and environmental problems are occurring, such as severe erosion, shallow surface soils with rocky fragments, and loadings of non-point source (NPS) contaminants into the watershed. Based on the field trials, most of the sloping uplands were classified as Suitability Class III-V and the major limiting factor was slope and rock fragments. Due to this, soils were over-applied with N fertilizer, even though N rate was the recommendation. This resulted in decreases in yield, degradation of soil quality and increases in N loading to the leachate. Various case studies drew management practices toward sustainable production systems. The suggested BMP on the managerial, vegetative, and structural options were to practice buffer strips along the edges of fields and streams, winter cover crop, contour and mulching farming, detention weir, diversion drains, grassed waterway, and slope arrangement. With these options, conservation effects such as reductions in raindrop impact, flow velocity, runoff and sediment loss, and rill and gully erosion were observed. The proper management practice is a key element of the conservation of the soil and water in the sloping upland.

유류오염대수층 공기분사공정상의 미생물 제한효소다형성법 적용 평가 (Analysis of Microbial Community in the TPH-Contaminated Groundwater for Air Sparging using Terminal-Restriction Fragment Length Polymorphism)

  • 이준호;이상훈;조재창;박갑성
    • 한국물환경학회지
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    • 제22권4호
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    • pp.590-598
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    • 2006
  • In-situ Air sparging (IAS) is a groundwater remediation technique, in which organic contaminants volatilize into air form the saturated to vadose zone. This study was carried out to evaluate the effect of sludge and soil microbial community structure on air sparging of Total Petroleum Hydrocarbons (TPH) contaminated groundwater soils. In the laboratory, diesel (10,000 mg TPH/kg) contaminated saturated soil. The Air was injected in intermittent (Q=1500 mL/min, 10 minute injection and 10 minute idle) modes. For Terminal-Restriction Fragment Length Polymorphism (T-RFLP) analysis of eubacterial communities in sludge of wastewater treatment plants and soil of experiment site, the 16S rDNA was amplified by Polymerase Chain Reaction (PCR) from the sludge and the soil. The obtained 16S rDNA fragments were digested with Msp I and separated by electrophoresis gel. We found various sequence types for experiment with sludge soil samples that were closely related to Agrococcus, Flavobacterium, Thermoanaerobacter, Flexibacter and Shewanella, etc, in the clone library. The results of the present study suggests that T-RFLP method may be applied as a useful tool for the monitoring in the TPH contaminated soil the fate of microorganisms in natural microbial community.

전자빔 조사에 의한 오염토양중의 PAHs및 PCBs의 분해 (Removal of PAHs and PCBs in artificially contaminated soils using electron beam irradiation)

  • 김석구;정장식;김이태;배우근
    • 한국지하수토양환경학회지:지하수토양환경
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    • 제7권3호
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    • pp.61-70
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    • 2002
  • 난분해성 유기오염물로 오염된 토양 복원을 위한 전자빔 직접조사 공정의 적용가능성을 평가하기 위하여 PAHs 와 PCBs로 오염시킨 토양에 대한 전자빔 조사실험을 수행하였다 전자빔 흡수선량 600kGy에서 PAHs의 제거율은 약 97% 이었고 PCBs는 800kGy에서 약 70%가 제거되었다. PAHs는 PCBs에 비해 낮은 흡수선량에서도 높은 제거율을 나타내었다. 오염물의 분해는 가속된 전자와 물의 반응으로 생성된 반응성 높은 중간생성물에 의한 산화/환원 반응보다는 고에너지 전자와 대상오염물의 직접적인 반응에 기인한다. 전자빔 조사에 의해 난분해성 오염물질로 오염된 토양을 효과적으로 제거할 수 있으나 이를 위해 높은 에너지를 요구하므로 비경제적인 공법이 될 수 있다. 따라서, 전자빔 직접조사 공정보다는 기존 토양복원 공법의 후처리 공정으로 개발하는 것이 경제적이고 실용화 가능할 것으로 판단된다.

생물막공법을 이용한 도시하수처리에 관한 연구 (A Study on the Municipal Wastewater Treatment Using Biofilm Process)

  • 곽병찬;탁성제;김남천;황용우
    • 상하수도학회지
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    • 제14권1호
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    • pp.62-75
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    • 2000
  • Most of biological treatment to remove contaminants in municipal wastewater have been conducted by activated sludge process. But, the process have several probIems such as enormous site needed for construction of treatment facilities, unstable treatment due to limited ability to control load fluctuation, frequent sludge bulking and appearance of lots of surplus sludge. In this study, the experiments were performed through submerging biofilm of PEPP media in existing aeration tank with raw water from municipal wastewater treatment plant and then submerging PVDC and PEPP media, different from shape and chemical peculiarity in anoxic reactor. Throughout the experience, nutrient removal efficiency according to HRT, nitrogen phosphorous removal efficiency, behavior of nitrogen and dewatering efficiency have been compared and analysed with those of activated sludge process. As the results, BOD removal efficiency according to BOD volumetric load and F/M ratio was not found any differency in two processes, but was decreased below 90% as going along the condition of high load in activated sludge process. Kinetic coefficient was $K_{max}=1.162day^{-1}$, $K_s=53.77mg/L$, $Y=0.166mgVSS/mgBOD_{rem}$. and $K_d=0.019day^{-1}$. It was found that the removal efficiency, even though in aerobic condition, in biofilm process equipped anoxic reactor was higher than the one in activated sludge process within the range of 70~80%, and became better as HRT increased. Phosphorous removal efficiency was not found any differency in two processes. In biofilm process, treament efficiency even in conditions of high load was not decreased, because the biomass concentration could be maintained in high condition compared with activated sludge process. As HRT increased, suspended and attached biomass was increased and the other hand, F/M ratio was decreased as biomass' increasing. Biomass thickness was increased. from $10.43{\mu}m$ to $10.55{\mu}m$ as HRT increased and density of biomass within $40.79{\sim}41.16mg/cm^2$. The results also present that the dewatering efficiency of sludge generated in biofilm process was higher than in activated sludge process, and became better as HRT increased.

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