• Title/Summary/Keyword: single scattering model

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Filled Skutterudites: from Single to Multiple Filling

  • Xi, Lili;Zhang, Wenqing;Chen, Lidong;Yang, Jihui
    • Journal of the Korean Ceramic Society
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    • v.47 no.1
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    • pp.54-60
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    • 2010
  • This paper shortly reviews our recent work on filled skutterudites, which are considered to be one of the most promising thermoelectric (TE) materials due to their excellent power factors and relatively low thermal conductivities. The filled skutterudite system also provides a platform for studying void filling physics/chemistry in compounds with intrinsic lattice voids. By using ab initio calculations and thermodynamic analysis, our group has made progresses in understanding the filling fraction limit (FFL) for single fillers in $CoSb_3$, and ultra-high FFLs in a few alkali-metal-filled $CoSb_3$ have been predicted and then been confirmed experimentally. FFLs in multiple-element-filled $CoSb_3$ are also investigated and anonymous filling behavior is found in a few specific systems. The calculated and measured FFLs, in both single and multiple-filled $CoSb_3$ systems, show good accordance so far. The thermal transport properties can be understood qualitatively by a phonon resonance scattering model, and it seems that a scaling rule may exist between the lattice thermal resistivity and the resonance frequency of filler atoms in filled system. Even though a few things become clear now, there are still many unsolved issues that call for further work.

Ultrahigh Vacuum Study for the Model Systems of Ziegler-Natta Catalyst

  • 이창섭
    • Bulletin of the Korean Chemical Society
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    • v.16 no.7
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    • pp.661-666
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    • 1995
  • The surface structure of the adsorption site for the identification of active sites involved in the Ziegler-Natta catalyst was studied by surface science techniques. As an example of a real catalyst, TiCl3 single crystals were prepared in a gradient furnace designed for this study and characterized by Auger Electron Spectroscopy (AES) and Low Energy Electron Diffraction (LEED) under ultrahigh vacuum condition. The chlorine covered Ti (0001) surface was employed as a model catalyst for the study of Ziegler-Natta catalyst. The diffuse LEED (DLEED) technique for the surface structural determination was applied to this disordered chlorine adsorbed on Ti (0001) surface. The diffuse scattering intensities were measured by a TV-computer method using a low light level video camera. From an analysis of two catalyst systems, the informations for the surface structure of the model catalyst surfaces were derived.

Effect of Gold Substrates on the Raman Spectra of Graphene

  • Kim, Na-Young;Oh, Min-Kyung;Park, Sung-Ho;Kim, Seong-Kyu;Hong, Byung-Hee
    • Bulletin of the Korean Chemical Society
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    • v.31 no.4
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    • pp.999-1003
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    • 2010
  • Raman spectra of a single layer graphene sheet placed in different gold substrates were obtained and are discussed in the context of surface enhanced Raman scattering (SERS). The gold substrates were composed of a combination of a thermally deposited gold film and a close-packed gold nanosphere layer. The SERS effects were negligible when the excitation wavelength was 514 nm, while the Raman signals were enhanced 3-to 50-fold when the excitation wavelength was 633 nm. The large SERS enhancement accompanied a spectral distortion with appearance of several unidentifiable peaks, as well as enhancement of a broadened D peak. These phenomena are interpreted as the local field enhancement in the nanostructure of the gold substrates. The difference in the enhancement factors among the various gold substrates is explained with a model in which the spatial distribution and polarization of the local field and the orientation of the inserted graphene sheet are considered important.

Fracture characterization with high frequency single-hole EM survey

  • Seo, Soon-Jee;Song, Yoon-Ho;Kim, Hee-Joon;Lee, Ki-Ha;Suh, Jung-Hee
    • Proceedings of the KSEEG Conference
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    • 1999.04a
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    • pp.90-93
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    • 1999
  • We present a high frequency electromagnetic (EM) inversion scheme for detecting and characterizing a fracture using single-hole data. At high frequencies, say above tens of mega-hertz, since displacement currents cannot be ignored, electrical permittivity as well as electrical conductivity is to be considered together for analyzing the EM scattering data. In this paper, we have developed a three-step inversion scheme to map the fracture and to evaluate its electrical conductivity and permittivity. We performed EM profiling along the z-axis using three-component receivers for each source. The model was excited by a vertical magnetic dipole and the resistant magnetic fields were inverted using the non-linear least-squares method. Background resistivity and permittivity were easily obtained using vertical magnetic fields below 1 MHz and above 10 MHz, respectively. Both the vertical and dipping sheets were successfully mapped using the phase difference between 40 and 41 MHz. The electrical property of the sheet was well resolved using the information obtained in the previous two steps and secondary magnetic fields. Our study shows the potential of imaging the fracture in single-hole survey environment using the high frequency EM method.

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A three-dimensional two-hemisphere model for unmanned aerial vehicle multiple-input multiple-output channels

  • Zixu Su;Wei Chen;Changzhen Li;Junyi Yu;Guojiao Gong;Zixin Wang
    • ETRI Journal
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    • v.45 no.5
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    • pp.768-780
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    • 2023
  • The application of unmanned aerial vehicles (UAVs) has recently attracted considerable interest in various areas. A three-dimensional multiple-input multiple-output concentric two-hemisphere model is proposed to characterize the scattering environment around a vehicle in an urban UAV-to-vehicle communication scenario. Multipath components of the model consisted of lineof-sight and single-bounced components. This study focused on the key parameters that determine the scatterer distribution. A time-variant process was used to analyze the nonstationarity of the proposed model. Vital statistical properties, such as the space-time-frequency correlation function, Doppler power spectral density, level-crossing rate, average fade duration, and channel capacity, were derived and analyzed. The results indicated that with an increase in the maximum scatter radius, the time correlation and level-crossing rate decreased, the frequency correlation function had a faster downward trend, and average fade duration increased. In addition, with the increase of concentration parameter, the time correlation, space correlation, and level-crossing rate increased, average fade duration decreased, and Doppler power spectral density became flatter. The proposed model was compared with current geometry-based stochastic models (GBSMs) and showed good consistency. In addition, we verified the nonstationarity in the temporal and spatial domains of the proposed model. These conclusions can be used as references in the design of more reasonable communication systems.

Regional variation of the coda Q in the Korean Peninsula (한반도 coda Q의 지역적 변화)

  • Yun, Suk-Young;Lee, Won-Sang;Lee, Kie-Hwa
    • 한국지구물리탐사학회:학술대회논문집
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    • 2005.05a
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    • pp.37-42
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    • 2005
  • We analyzed spectral attenuation of coda waves and estimated coda Q values in the crust of the Korean peninsula. 574 NS-component seismograms registered by the Korea Meteorological Administration (KMA) and Korea Institute of Geology, Mining and Materials (KIGAM) seismic networks with epicentral distances less than 100 km and sampling rate greater than 80 Hz were selected for this study. We estimated coda Q values using the single isotropic scattering model at center frequencies of 1.5, 3, 6, 9, 12, 15, and 18 Hz with 20 s time window starting from double of the S-wave arrival times. Estimated coda Q value at 1 Hz ($Q_0$) and n value range 50 to 250 and 0.5 to 1.0, respectively, and they are well correlated with the regional geology in the Korean peninsula. The $Q_0$ values in western Korea agree well with those of eastern China.

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Analysis of the Scattering Property of Dielectric Scatterer with Impedance Boundary Condition (임피던스 경계면 조건을 적용한 유전체의 산란 특성 분석)

  • Hwang, Ji-Hwan;Park, Sin-Myeong;Oh, Yisok
    • The Journal of Korean Institute of Electromagnetic Engineering and Science
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    • v.25 no.10
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    • pp.1087-1094
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    • 2014
  • An numerical technique of impedance boundary condition to improve an efficiency in the process of moment method with CFIE(Combined Field Integral Equation), which is widely used to analyze the scattering property of dielectric scatterers, and results of its cross-validations are presented in this study. Application of the impedance boundary allows to represent the equivalent surface currents of dielectric scatterer depicted by both kinds of electric/magnetic surface currents(Js, Ms) to the single surface current by Js or Ms only. Accuracy of this technique is validated by the existing CFIE and theoretical values such as Mie-series solution and small perturbation scattering model. The computational difference of less than 1 dB was verified within an imaginary part of dielectric constant more than 12, as well.

Analysis of electron mobility in LDD region of NMOSFET (NMOSFET에서 LDD 영역의 전자 이동도 해석)

  • 이상기;황현상;안재경;정주영;어영선;권오경;이창효
    • Journal of the Korean Institute of Telematics and Electronics A
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    • v.33A no.10
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    • pp.123-129
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    • 1996
  • LDD structure is widely accepted in fabricating short channel MOSFETs due to reduced short channel effect originated form lower drain edge electric field. However, modeling of the LDD device is troublesome because the analysis methods of LDD region known are either too complicated or inaccurate. To solve the problem, this paper presents a nonlinear resistance model for the LDD region based on teh fact that the electron mobility changes with positive gate bias because accumulation layer of electrons is formed at the surface of the LDD region. To prove the usefulness of the model, single source/drain and LDD nMOSFETs were fabricated with 0.35$\mu$m CMOS technolgoy. For the fabricated devices we have measured I$_{ds}$-V$_{gs}$ characteristics and compare them to the modeling resutls. First of all, we calculated channel and LDD region mobility from I$_{ds}$-V$_{gs}$ characteristics of 1050$\AA$ sidewall, 5$\mu$m channel length LDD NMOSFET. Then we MOSFET and found good agreement with experiments. Next, we use calculated channel and LDD region mobility to model I$_{ds}$-V$_{gs}$ characteristics of LDD mMOSFET with 1400 and 1750$\AA$ sidewall and 5$\mu$m channel length and obtained good agreement with experiment. The single source/drain device characteristic modeling results indicates that the cahnnel mobility obtained form our model in LDD device is accurate. In the meantime, we found that the LDD region mobility is governed by phonon and surface roughness scattering from electric field dependence of the mobility. The proposed model is useful in device and circuit simulation because it can model LDD device successfully even though it is mathematically simple.

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Under-Developed and Under-Utilized Eclipsing Binary Model Capabilities

  • Wilson, R.E.
    • Journal of Astronomy and Space Sciences
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    • v.29 no.2
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    • pp.115-121
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    • 2012
  • Existing but largely unused binary star model capabilities are examined. An easily implemented scheme is parameterization of starspot growth and decay that can stimulate work on outer convection zones and their dynamos. Improved precision in spot computation now enhances analysis of very precise data. An existing computational model for blended spectral line profiles is accurate for binary system effects but needs to include damping, thermal Doppler, and other intrinsic broadening effects. Binary star ephemerides had been found exclusively from eclipse timings until recently, but now come also from whole light and radial velocity curves. A logical further development will be to expand these whole curve solutions to include eclipse timings. An attenuation model for circumstellar clouds, with several absorption and scattering mechanisms, has been applied only once, perhaps because the model clouds have fixed locations. However the clouds could be made to move dynamically and be combined into moving streams and disks. An area of potential interest is polarization curve analysis, where incentive for modeling could follow from publication of observed polarization curves. Other recent advances include direct single step solutions for temperatures of both stars of an eclipsing binary and third body kinematics from combined light and velocity curves.

Development of Single-Frame PIV Velocity Field Measurement Technique Using a High Resolution CCD Camera (고해상도 CCD카메라를 이용한 Single-Frame PIV 속도장 측정기법 개발)

  • Lee, Sang-Joon;Shin, Dae-Sig
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.24 no.1
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    • pp.21-28
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    • 2000
  • Although commercial PIV systems have been widely used for the non-intrusive velocity field measurement of fluid flows, they are still under development and have considerable room for improvement. In this study, a single-frame double-exposure PIV system using a high-resolution CCD camera was developed. A pulsed Nd:Yag laser and high-resolution CCD camera were synchronized by a home-made control circuit. In order to resolve the directional ambiguity problem encountered in the single-frame PIV technique, the second particle image was genuinely shifted in the CCD sensor array during the time interval dt. The velocity vector field was determined by calculating the displacement vector at each interrogation window using cross-correlation with 50% overlapping. In order to check the effect of spatial resolution of CCD camera on the accuracy of PIV velocity field measurement, the developed PIV system with three different resolution modes of the CCD camera (512 ${\times}$ 512, lK ${\times}$ IK, 2K ${\times}$ 2K) was applied to a turbulent flow which simulate the Zn plating process of a steel strip. The experimental model consists of a snout and a moving belt. Aluminum flakes about $1{\mu}m$ diameter were used as scattering particles for the liquid flow in the zinc pot and the gas flow above the zinc surface was seeded with atomized olive oil with an average diameter of 1-$3{\mu}m$. Velocity field measurements were carried out at the strip speed $V_s$=1.0 m/s. The 2K ${\times}$ 2K high-resolution PIV technique was significantly superior compared to the smaller pixel resolution PIV system. For the cases of 512 ${\times}$ 512 and 1K ${\times}$ 1K pixel resolution PIV system, it was difficult to get accurate flow structure of viscous flow near the wall and small vortex structure in the region of large velocity gradient.