• Title/Summary/Keyword: single phase structure

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Effects of Metal Ions Mole Ratio, pH and Heat Treatment Condition on the Magnetic Properties and Formation of Co-precipitated M-type Barium Ferrite Powders (공침법으로 합성한 바륨 페라이트(BaM)의 형성과 자기적 성질에 미치는 금속이온 몰 비 및 pH와 열처리 조건의 영향)

  • Baek, In-Seung;Nam, In-Tak
    • Journal of the Korean Magnetics Society
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    • v.19 no.6
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    • pp.209-215
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    • 2009
  • M-type barium ferrite (BaFe12O19) powders were synthesized through the co-precipitation method. Starting material composition $Fe^{3+}:\;Ba^{2+}$ mole ratio was fixed as 8 and the relative amount of $Fe^{3+}$ and $Ba^{2+}$ was controlled. Structure and magnetic properties and powder morphology were investigated using XRD, SEM, VSM. Powder showing high coercivity and small magnetization was obtained at pH8 and $Fe_{3+}:\;Ba_{2+}$ of 12 : 1.5. Small magnetization value was originated from the existence of ${\alpha}-Fe_2O_3$. Single-phase Mtype barium ferrite were obtained regardless of the heat treatment condition and the amount of $Fe_{3+}\;and\;Ba_{2+}$ at pH$\approx$10. The largest value of magnetization (55.7 emu/g) under investigation were obtained when $Fe_{3+}:\;Ba_{2+}$ of 13.6 : 1.7 and furnace cooled powder in $O_2$. Particle size of powder was in the range of 50~200 nm.

Layout Principles of Renaissance Classicism Architectural Style and Its Application on Modern Fashion Design - Focused on Classic Style Fashion after the Year 1999 - (르네상스 고전주의 건축양식의 조형원리와 현대패션디자인에의 적용 - 1999년 이후 클래식 스타일 패션을 중심으로 -)

  • Lee, Shin-Young
    • The Research Journal of the Costume Culture
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    • v.18 no.2
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    • pp.261-276
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    • 2010
  • The analysis of an art trend in the principle dimension starts by observing the object of work in the perspective of formative composition and recognizing it as a universal system. It can be said that it is consistent with an interpretation method for a form theory of formal history by Heinrich W$\ddot{o}$lfflin, a leading form critic in art criticism. Hence, the purpose of this study was to find out what are the formative principles in Renaissance Classicism as a design principle to be applicable to modern fashion by reviewing the formative characteristics of Renaissance Classicism Architecture with which W$\ddot{o}$lfflin directly dealt. As for the theoretical literature review, I used W$\ddot{o}$lfflin's theoretical framework and looked at the Renaissance Classicism Architecture that he studied and examined the possibility of utilizing his theory as a layout principle and the characteristics. As for analysis of design cases, I applied the aforementioned architecture layout principle to modern fashion and conducted case study analysis to delve into distinctive layout principles found in fashion. The study showed that the Renaissance Classicism Architectural Style is marked by linearity, planarity, closing and multiple unity: linearity was expressed in the observation form in fixed frontal view and an emphasis on a tangible silhouette homeogenous and definite line structures; planarity was achieved in the form of paralleled layers of frontal view element, planarity style, and identical and proportional repetition of various sizes.; closing signified the pursuit of complete and clear regularity, and architecture developed in a constructive phase through organizational inevitability and absolute invariability.; multiple unity was expressed in self-completedness and independent parallel of discrete forms and harmony of emphasized individual elements in a totality. Applying these layout characteristics of the Renaissance Classicism Architectural style and to see their individual expressive features, I found out that in adopting layout principles of the Renaissance Classicism Architecture to modern fashion, it turned out to be an emphasis of individual silhouettes, a flattened space, completed objects, organic harmony among independent parts: the emphasis of individual silhouettes was expressed in individual definitiveness of formative lines of clothes in accordance with body joints and an emphasis on formative lines of clothes; the flattened space was marked by single layer structure, planarity of elements of clothes, and listing arrangement by appropriate proportion.; the completedness of the objects was expressed by the stationary state where overall image is fixed, the construction of homogeneous and complete space, and absolute inevitability of internal layout in proportion; lastly, organic harmony of independent parts was stressed in independent completedness of each detail, and organic harmony of the whole. The expressive features would lead to a unique expression style of linear emphasis, proportion, constructive forms, and two-dimensional arrangement. The meaning of this study is follows: The characteristics of art school of thought are given shape by appling & analysing the architectural layout principles of historical art school of thought to modern fashion in the view point of formal construction dimension. The applied possibility of historical art school of thought as the source of inspiration about the fashion design is extended.

The Crystallographic and Magnetic Properties of $Fe_{0.8}Co_{0.18}(BN_{0.02}$ Synthesized by Heat Treatment and Plastic Deformation ($Fe_{0.8}Co_{0.18}(BN_{0.02}$의 열처리 및 소성변형에 의한 결정구조와 자기적 성질)

  • 김정기;한경훈;이상문;정재윤;김예니;신경호
    • Journal of the Korean Magnetics Society
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    • v.10 no.5
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    • pp.225-231
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    • 2000
  • The crystallographic and magnetic properties of the sample F $e_{0.8}$ $Co_{0.18}$(BN)$_{0.02}$ synthesized by microwave arc-melting with the maximum power of 3.5 kW have been studied by the methods of an X-ray diffraction and the measurement of the magnetic hysteresis using the vibrating sample magnetometer at room temperature. The samples were prepared in a form of pellet pressed under the pressure of 9,000 N/c $m^2$, rolled coldly, and treated with the different temperatures. The X-ray diffraction pattern of pelleted sample shows that the crystal structure of the sample is bcc as same as that of Fe with a good uniformity. The X-ray diffraction pattern shows that a residual stress, which exists in the sample, is eliminated by final 90$0^{\circ}C$ annealing. As rolling rate and heat treatment temperature increases, the saturation magnetization and the remanence of the samples increase whereas the coercivity of the samples shows decrease. Also the saturation magnetization and the remanence of the samples were affected by rolling rate and rolling direction than heat treatment temperature, but the coercivity of the samples was affected by rolling rate and direction as well as heat treatment temperature. This means that a domain wall motion is easy due to elimination of a residual stress and an inclusion which exists in the sample by rolling and heat treatment and a local induced-magnetization easy axis was also formed to parallel to the rolling direction due to creation of the like-atom pairs across the slip plane by rolling......

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Subarray Channel Calibration and Performance Analysis for Digital Beam-Forming (디지털 빔 형성을 위한 부배열 채널 보정 및 성능 분석)

  • Jang, Sung-Hoon;Ahn, Chang-Soo;Kim, Dong-Hwan;Kim, Seon-Ju
    • The Journal of Korean Institute of Electromagnetic Engineering and Science
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    • v.25 no.2
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    • pp.235-244
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    • 2014
  • This paper describes the subarray channel configuration and calibration method for airborne AESA radar antenna. AESA radar demonstrator was designed and implemented for the digital beam-forming performance test of the 12 channel subarray structure. Magnitude and phase difference can be exist between the manufactured subarray channel. In this paper, calibration method for the subarray difference error was suggested. We measured digital monopulse slope in the subarray channel and verified the channel calibration effect. To verify the subarray channel operation, digital monopulse channel was compared with analog monopulse channel performance. AESA radar demonstrator was tested in the ground far field test range. Emulated single target was generated to test the detection and tracking performance of the demonstrator with the same waveform and search pattern. We verified that the detection and tracking performance of the 12 subarray digital monopulse channel was similar with the conventional analog monopulse channel. Also, ABF(Adaptive Beam-Forming) function for the sidelobe jammer was tested and effective operation was verified.

Fabrication and Permeation Properties of Tubular $Ba_{0.5}Sr_{0.5}Co_{0.8}Fe_{0.2}O_{3-{\delta}}$ Membranes for Oxygen Separation (산소분리를 위한 $Ba_{0.5}Sr_{0.5}Co_{0.8}Fe_{0.2}O_{3-{\delta}}$ 관형 분리막 제조 및 투과 특성)

  • Kim, Jong-Pyo;Son, Sou-Hwan;Park, Jung-Hoon;Lee, Yong-Taek
    • Korean Chemical Engineering Research
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    • v.49 no.6
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    • pp.804-809
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    • 2011
  • Tubular $Ba_{0.5}Sr_{0.5}Co_{0.8}Fe_{0.2}O_{3-${\delta}$}$ membranes were prepared by extrusion. TGA results of green body membrane after extrusion showed three successive weight losses due to decomposition of organic additives and carbonate. Drying shrinkage rate of tubular $Ba_{0.5}Sr_{0.5}Co_{0.8}Fe_{0.2}O_{3-${\delta}$}$ membranes was no change after 68 h and higher in the membrane with large outer diameter. XRD and SEM results showed the sintered membranes were the single phase structure and dense. The stoichiometric molar ratio agreed well with composition ratio calculated by EDS results for $Ba_{0.5}Sr_{0.5}Co_{0.8}Fe_{0.2}O_{3-${\delta}$}$ membrane. Radial crushing strength of tubular $Ba_{0.5}Sr_{0.5}Co_{0.8}Fe_{0.2}O_{3-${\delta}$}$ membrane with 0.95 mm thickness was 5.7 kgf/$mm^2$ and the oxygen permeation rate of same membrane was 146.85 mL/min ($Jo_2$=2.33 mL/$min{\cdot}cm^2$) at $950^{\circ}C$. Therefore, it was known that use of vacuum pump was more effective than that of sweep gas to obtain higher oxygen permeation flux.

Preparation of Nano Sized Indium Tin Oxide (ITO) Powder with Average Particle Size Below 30 nm from Waste ITO Target by Spray Pyrolysis Process (폐 ITO 타겟으로부터 분무열분해 공정에 의한 평균입도 30 nm 이하의 인듐-주석 산화물 분체 제조)

  • Kim, Donghee;Yu, Jaekeun
    • Resources Recycling
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    • v.27 no.2
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    • pp.24-31
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    • 2018
  • In this study, waste ITO target is dissolved into hydrochloric acid to generate a complex indium-tin chloride solution. Nano sized ITO powder with an average particle size below 30 nm are generated from these raw material solutions by spray pyrolysis process. Also, in this study, thermodynamic equations for the formation of indium-tin oxide (ITO) are established. As the reaction temperature increased from $800^{\circ}C$ to $900^{\circ}C$, the proportion and size of the spherical droplet shape in which nano sized particles aggregated gradually decreased, and the surface structure gradually became densified. When the reaction temperature was $800^{\circ}C$, the average particle size of the generated powder was about 20 nm, and no significant sintering was observed. At a reaction temperature of $900^{\circ}C$, the split of the droplet was more severe than at $800^{\circ}C$, and the rate of maintenance of the initial atomized droplet shape decreased sharply. The average particle size of the powder formed was about 25 nm. The ITO particles were composed of single solid crystals, regardless of reaction temperature. XRD analysis showed that only the ITO phase was formed. Remarkably, the specific surface area decreased by about 30% as the reaction temperature increased from $800^{\circ}C$ to $900^{\circ}C$.

Mössbauer Studies of Manganese Iron Oxide Nanoparticles (망간-철산화물 나노입자의 뫼스바우어 분광 연구)

  • Hyun, Sung-Wook;Shim, In-Bo;Kim, Chul-Sung;Kang, Kyung-Su;Park, Chu-Sik
    • Journal of the Korean Magnetics Society
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    • v.18 no.1
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    • pp.24-27
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    • 2008
  • We have prepared $MnFe_2O_4$ nanoparticles with polyol method. The crystallographic and magnetic properties were measured by using X-ray diffraction(XRD), vibrating sample magnetometer(VSM) and $M\"{o}ssbauer$ spectroscopy. The high resolution transmission electron microscope(HRTEM) shows uniform nanoparticle-sizes with $6{\sim}8$ nm. The crystal structure is found to be single-phase cubic spinel with space group of Fd3m. The lattice constant of $MnFe_2O_4$ nanparticles is determined to be $8.418{\pm}0.001{\AA}$. $M\"{o}ssbauer$ spectrum of $MnFe_2O_4$ nanparticles at room temperature(RT) shows a superparamagnetic behavior. In VSM analysis, the diagnosis of the superparamagnetic behavior is also shown in hysteresis loop at RT. $M\"{o}ssbauer$ spectrum at 4.2K shows that the well developed two sextets are with different hyperfine field $H_{hfA}=498$(A-site) and $H_{hfB}=521$(B-site) kOe.

Investigation on Ferroelectric and Magnetic Properties of Pb(Fe1/2Nb1/2)O3 Fe-Site Engineered with Antisymmetric Exchange Interaction (반대칭 교환 상호작용을 갖도록 Fe-Site가 제어된 PbFe1/2Nb1/2O3의 강유전/자기적 특성 연구)

  • Park, Ji-Hun;Lee, Ju-Hyeon;Cho, Jae-Hyeon;Jang, Jong Moon;Jo, Wook
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.35 no.3
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    • pp.297-302
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    • 2022
  • We investigated the origin of magnetic behaviors induced by an asymmetric spin exchange interaction in Fe-site engineered lead iron niobate [Pb(Fe1/2Nb1/2)O3, PFN], which exhibits a room-temperature multiferroicity. The magnitude of spin exchange interaction was regulated by the introduced transition metals with a distinct Bohr magneton, i.e., Cr, Co, and Ni. All compositions were found to have a single-phase perovskite structure keeping their ferroelectric order except for Cr introduction. We discovered that the incorporation of each transition metal imposes a distinct magnetic behavior on the lead iron niobate system; antiferro-, hard ferro-, and soft ferromagnetism for Cr, Co, and Ni, respectively. This indicates that orbital occupancy and interatomic distance play key roles in the determination of magnetic behavior rather than the magnitude of the individual Bohr magneton. Further investigations are planned, such as X-ray absorption spectroscopy, to clarify the origin of magnetic properties in this system.

Ultra-high Temperature EM Wave Absorption Behavior for Ceramic/Sendust-aluminosilicate Composite in X-band (X-Band 영역에서의 세라믹/샌더스트-알루미노실리케이트 복합재의 초고온 전자파 흡수 거동)

  • Choi, Kwang-Sik;Sim, Dongyoung;Choi, Wonwoo;Shin, Joon-Hyung;Nam, Young-Woo
    • Composites Research
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    • v.35 no.3
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    • pp.201-215
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    • 2022
  • This paper presents the development of thin and lightweight ultra-high temperature radar-absorbing ceramic composites composed of an aluminosilicate ceramic matrix-based geopolymer reinforced ceramic fiber and sendust magnetic nanoparticles in X-band frequency range (8.2~12.4 GHz). The dielectric properties with regard to complex permittivity of ceramic/sendust-aluminosilicate composites were proportional to the size of sendust magnetic nanoparticle with high magnetic characteristic properties as flake shape and its concentrations in the target frequency range. The characteristic microstructures, element composition, phase identification, and thermal stability were examined by SEM, EDS, VSM and TGA, respectively. The fabricated total thicknesses of the proposed single slab ultra-high temperature radar absorber correspond to 1.585 mm, respectively, exhibiting their excellent EM absorption performance. The behavior of ultra-high temperature EM wave absorption properties was verified to the developed free-space measurement system linked with high temperature furnace for X-band from 25℃ to 1,000℃.

RANS simulation of secondary flows in a low pressure turbine cascade: Influence of inlet boundary layer profile

  • Michele, Errante;Andrea, Ferrero;Francesco, Larocca
    • Advances in aircraft and spacecraft science
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    • v.9 no.5
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    • pp.415-431
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    • 2022
  • Secondary flows have a huge impact on losses generation in modern low pressure gas turbines (LPTs). At design point, the interaction of the blade profile with the end-wall boundary layer is responsible for up to 40% of total losses. Therefore, predicting accurately the end-wall flow field in a LPT is extremely important in the industrial design phase. Since the inlet boundary layer profile is one of the factors which most affects the evolution of secondary flows, the first main objective of the present work is to investigate the impact of two different inlet conditions on the end-wall flow field of the T106A, a well known LPT cascade. The first condition, labeled in the paper as C1, is represented by uniform conditions at the inlet plane and the second, C2, by a flow characterized by a defined inlet boundary layer profile. The code used for the simulations is based on the Discontinuous Galerkin (DG) formulation and solves the Reynolds-averaged Navier-Stokes (RANS) equations coupled with the Spalart Allmaras turbulence model. Secondly, this work aims at estimating the influence of viscosity and turbulence on the T106A end-wall flow field. In order to do so, RANS results are compared with those obtained from an inviscid simulation with a prescribed inlet total pressure profile, which mimics a boundary layer. A comparison between C1 and C2 results highlights an influence of secondary flows on the flow field up to a significant distance from the end-wall. In particular, the C2 end-wall flow field appears to be characterized by greater over turning and under turning angles and higher total pressure losses. Furthermore, the C2 simulated flow field shows good agreement with experimental and numerical data available in literature. The C2 and inviscid Euler computed flow fields, although globally comparable, present evident differences. The cascade passage simulated with inviscid flow is mainly dominated by a single large and homogeneous vortex structure, less stretched in the spanwise direction and closer to the end-wall than vortical structures computed by compressible flow simulation. It is reasonable, then, asserting that for the chosen test case a great part of the secondary flows details is strongly dependent on viscous phenomena and turbulence.