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http://dx.doi.org/10.4313/JKEM.2022.35.3.13

Investigation on Ferroelectric and Magnetic Properties of Pb(Fe1/2Nb1/2)O3 Fe-Site Engineered with Antisymmetric Exchange Interaction  

Park, Ji-Hun (Department of Materials Science and Engineering & Jülich-UNIST Joint Leading Institute for Advanced Energy Research (JULIA), Ulsan National Institute of Science and Technology (UNIST))
Lee, Ju-Hyeon (Department of Materials Science and Engineering & Jülich-UNIST Joint Leading Institute for Advanced Energy Research (JULIA), Ulsan National Institute of Science and Technology (UNIST))
Cho, Jae-Hyeon (Department of Materials Science and Engineering & Jülich-UNIST Joint Leading Institute for Advanced Energy Research (JULIA), Ulsan National Institute of Science and Technology (UNIST))
Jang, Jong Moon (Department of Functional Ceramics, Ceramic Materials Division, Korea Institute of Materials Science (KIMS))
Jo, Wook (Department of Materials Science and Engineering & Jülich-UNIST Joint Leading Institute for Advanced Energy Research (JULIA), Ulsan National Institute of Science and Technology (UNIST))
Publication Information
Journal of the Korean Institute of Electrical and Electronic Material Engineers / v.35, no.3, 2022 , pp. 297-302 More about this Journal
Abstract
We investigated the origin of magnetic behaviors induced by an asymmetric spin exchange interaction in Fe-site engineered lead iron niobate [Pb(Fe1/2Nb1/2)O3, PFN], which exhibits a room-temperature multiferroicity. The magnitude of spin exchange interaction was regulated by the introduced transition metals with a distinct Bohr magneton, i.e., Cr, Co, and Ni. All compositions were found to have a single-phase perovskite structure keeping their ferroelectric order except for Cr introduction. We discovered that the incorporation of each transition metal imposes a distinct magnetic behavior on the lead iron niobate system; antiferro-, hard ferro-, and soft ferromagnetism for Cr, Co, and Ni, respectively. This indicates that orbital occupancy and interatomic distance play key roles in the determination of magnetic behavior rather than the magnitude of the individual Bohr magneton. Further investigations are planned, such as X-ray absorption spectroscopy, to clarify the origin of magnetic properties in this system.
Keywords
Multiferroics; Ferromagnetism/ferromagnetic oxides; Superexchange interaction; Ferroelectricity/ferroelectric oxides; Lead iron niobate;
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