Journal of the Korean Institute of Electrical and Electronic Material Engineers (한국전기전자재료학회논문지)

The Korean Institute of Electrical and Electronic Material Engineers (한국전기전자재료학회)
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Investigation on Ferroelectric and Magnetic Properties of Pb(Fe1/2Nb1/2)O3 Fe-Site Engineered with Antisymmetric Exchange Interaction

반대칭 교환 상호작용을 갖도록 Fe-Site가 제어된 PbFe1/2Nb1/2O3의 강유전/자기적 특성 연구

  • Park, Ji-Hun (Department of Materials Science and Engineering & Jülich-UNIST Joint Leading Institute for Advanced Energy Research (JULIA), Ulsan National Institute of Science and Technology (UNIST)) ;
  • Lee, Ju-Hyeon (Department of Materials Science and Engineering & Jülich-UNIST Joint Leading Institute for Advanced Energy Research (JULIA), Ulsan National Institute of Science and Technology (UNIST)) ;
  • Cho, Jae-Hyeon (Department of Materials Science and Engineering & Jülich-UNIST Joint Leading Institute for Advanced Energy Research (JULIA), Ulsan National Institute of Science and Technology (UNIST)) ;
  • Jang, Jong Moon (Department of Functional Ceramics, Ceramic Materials Division, Korea Institute of Materials Science (KIMS)) ;
  • Jo, Wook (Department of Materials Science and Engineering & Jülich-UNIST Joint Leading Institute for Advanced Energy Research (JULIA), Ulsan National Institute of Science and Technology (UNIST))
  • 박지훈 (울산과학기술원 신소재공학과 및 JULIA 연구센터) ;
  • 이주현 (울산과학기술원 신소재공학과 및 JULIA 연구센터) ;
  • 조재현 (울산과학기술원 신소재공학과 및 JULIA 연구센터) ;
  • 장종문 (한국재료연구원 세라믹재료연구본부 기능세라믹연구실) ;
  • 조욱 (울산과학기술원 신소재공학과 및 JULIA 연구센터)
  • Received : 2022.03.08
  • Accepted : 2022.03.16
  • Published : 2022.05.01
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Abstract

We investigated the origin of magnetic behaviors induced by an asymmetric spin exchange interaction in Fe-site engineered lead iron niobate [Pb(Fe1/2Nb1/2)O3, PFN], which exhibits a room-temperature multiferroicity. The magnitude of spin exchange interaction was regulated by the introduced transition metals with a distinct Bohr magneton, i.e., Cr, Co, and Ni. All compositions were found to have a single-phase perovskite structure keeping their ferroelectric order except for Cr introduction. We discovered that the incorporation of each transition metal imposes a distinct magnetic behavior on the lead iron niobate system; antiferro-, hard ferro-, and soft ferromagnetism for Cr, Co, and Ni, respectively. This indicates that orbital occupancy and interatomic distance play key roles in the determination of magnetic behavior rather than the magnitude of the individual Bohr magneton. Further investigations are planned, such as X-ray absorption spectroscopy, to clarify the origin of magnetic properties in this system.

Keywords

Acknowledgement

본 연구는 과학기술정보통신부가 지원하는 한국연구재단의 해외우수연구기관 유치사업(2017K1A4A3015437) 및 울산과학기술원 2022년 연구 기금(1.220024.01)의 연구비 지원을 받아 수행되었습니다.

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