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The Influence of Mechanical Milling on the Structure and Magnetic Properties of Sm-Fe-N Powder Produced by the Reduction-Diffusion Process

  • Lee, Jung-Goo;Kang, Seok-Won;Si, Ping-Zhan;Choi, Chul-Jin
    • Journal of Magnetics
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    • v.16 no.2
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    • pp.104-107
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    • 2011
  • In the present study, we systematically investigated the effect of mechanical milling on the magnetic properties of $Sm_2Fe_{17}N_x$ powders produced by the reduction-diffusion process. The Sm-Fe powders obtained by the reduction-diffusion process were composed of an $Sm_2Fe_{17}N_x$ single phase. After nitrogenation, the coercivity and saturation magnetization of the powders were 0.48 kOe and 13.32 kG, respectively. The particle size largely decreased down to less than $2\;{\mu}m$ in diameter after ball milling for 30 hours. However, there is no evidence that the $Sm_2Fe_{17}N_x$ was decomposed to Sm-N and ${\alpha}$-Fe even after ball milling for 30 hours. The coercivity was significantly improved up to 8.82 kOe after milling for 60 hours. However, the magnetization decreased linearly with the ball milling time.

Characterization of Silver Nanoparticles Synthesized by Using Marine Isolate Streptomyces albidoflavus

  • Prakasham, Reddy Shetty;Kumar, Buddana Sudheer;Kumar, Yannam Sudheer;Shankar, Guntuku Girija
    • Journal of Microbiology and Biotechnology
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    • v.22 no.5
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    • pp.614-621
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    • 2012
  • Silver nanoparticles production by the green chemistry approach was investigated using an isolated marine actinomycetes strain. The isolated strain was identified as Streptomyces albidoflavus based on chemotaxonomic and ribotyping properties. The strain revealed production of silver nanoparticles both extracellular and intracellularly. Surface Plasmon Resonance analysis with the function of time revealed that particle synthesis by this strain is reaction time dependent. The produced particles were spherical shaped and monodispersive in nature and showed a single surface plasmon resonance peak at 410 nm. Size distribution histograms indicated production of 10-40-nm-size nanoparticles with a mean size of 14.5 nm. FT-IR spectra of nanopartilces showed N-H, C-H, and C-N stretching vibrations, denoting the presence of amino acid/peptide compounds on the surface of silver nanoparticles produced by S. albidoflavus. Synthesized nanoparticles revealed a mean negative zeta potential and electrophoretic mobility of -8.5 mV and -0.000066 $cm^2/Vs$, respectively. The nanoparticles produced were proteinaceous compounds as capping agents with -8.5 mV zeta potential and revealed antimicrobial activity against both Gram-negative and -positive bacterial strains. Owing to their small size, these particles have greater impact on industrial application spectra.

Preparation of Platinum catalysts for PEM Fuel cells

  • Sasikumar G.;Ryu H.
    • 한국전기화학회:학술대회논문집
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    • 2003.07a
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    • pp.189-192
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    • 2003
  • In this work, we have prepared platinum catalyst by various methods, investigated fuel cell performance and compared performance with commercially available $20\%$ Pt supported on carbon (Pt/C) catalyst. We have found that Pt/C prepared by reduction of chloroplatinic acid in mixed solvent (water+ethylene glycol) gives better performance compared to that produced by reduction of aqueous chloroplatinic acid, which can be attributed to smaller catalyst particle size and lower agglomeration in the mixed solvent. We have also prepared a novel platinum electrocatalyst by depositing platinum on Nafion coated carbon powder and it shows great promise. The performance of electrode prepared using $20\%Pt$ onn Nafion coated carbon mixed with Pt/C was found to be higher than the performance of electrodes using commercially available $20\%$ Pt/C, up to a current density of about $1100mA/cm^2$. The cell voltages obtained were respectively 621 and 603mV, at a current density of: $1000mA/cm^2$, in a single cell using $0.25mgPt/cm^2$ and Nafion 10035 membrane at $80^{\circ}C$ using hydrogen/oxygen reactants at 1 atm pressure.

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Comparison of Numerical and Experimental Stability of Dual Subsea Pipeline in Trench (트렌치내에서 복합 해저 관로 안정성의 수치해석과 실험해석 비교)

  • Chul H. Jo;Young S. Shin;Sung G. Hong;Kyoung H. Min;Chung, Kwang-Sic
    • Proceedings of the Korea Committee for Ocean Resources and Engineering Conference
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    • 2001.05a
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    • pp.254-259
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    • 2001
  • There are advantages in the installation of dual subsea pipelines over two separate single lines. In many case it can reduce the cost for trench, back-filling and installation. However the installation of dual pipelines often requires technical challenges. Dual Pipelines should be placed to be stable to external loading not only during the installation but also in the design life. Dual pipelines in trench can reduce the influence of external forces. To investigate applied forces as slope changes, number of experiments are conducted with PIV (Particle Image Velocimetry) in a circulating water channel. Numerical approaches are also made to compare with experimental results. The velocity fields around dual pipelines in trench are investigated and analysed. Comparison of both results show similar pattern of flow around dual pipelines. it is proved that the trench slope affects the pipeline stability significantly. The results can be applied in the stability design of dual pipelines in trench section. The complex flow patterns can be referenced effectively linked in the understanding of fluid around circular bodies in trench.

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Structural and Magnetic Properties of Cr-Zn Nanoferrites Synthesized by Chemical Co-Precipitation Method

  • Powar, Rohit R.;Phadtare, Varsha D.;Parale, Vinayak G.;Pathak, Sachin;Piste, Pravina B.;Zambare, Dnyandevo N.
    • Journal of the Korean Ceramic Society
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    • v.56 no.5
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    • pp.474-482
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    • 2019
  • Chromium-doped zinc ferrite nanoparticles with the general formula CryZnFe2-yO4 (y = 0, 0.025, 0.05, 0.075, and 0.1) were synthesized by a surfactant-assisted chemical co-precipitation route using metal nitrate salt precursors. The phase purity and structural parameters were determined by powder X-ray diffraction. The concentration of Cr3+ doped into ZnFe2O4 (ZF) noticeably affected the crystallite size, which was in the range of 22 nm to 36 nm, and all samples showed a single cubic spinel structure without any secondary phase or impurities. The lattice parameter, X-ray density, and skeletal density increased with an increase in the Cr-doping concentration; on the other hand, a decreasing trend was observed for the particle size and porosity. The influence of Cr3+ substitution on ZF magnetic properties were studied under an applied field of 15 kOe. The overall results revealed that the incorporation of a small amount of Cr dopant changed the structural, electrical, and magnetic properties of ZF.

Theory of Radiative Transfer for 3.3-micron $CH_4$ emissions from the Auroral Regions of Jupiter

  • Kim, Sang Joon;Sohn, Mirim
    • The Bulletin of The Korean Astronomical Society
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    • v.39 no.1
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    • pp.66.1-66.1
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    • 2014
  • Radiative transfer programs to simulate the 3-micron auroral $CH_4$ emissions of Jupiter have been developed. The formalism of the radiative transfer calculations including the thermal, fluorescent, and auroral emissions of the $CH_4$ bands for an atmospheric layer having an optical depth of ${\tau}_v$ is given by: ${\mu}dI_v/d{\tau}_v=I_v-{\varpi}_v{^*}J_v(1-{\varpi}_v{^*})B_v-{\varpi}{^*}F_{ov}{e}{x}{p}(-{\tau}_v/{\mu}_o)4{\pi}-hv{\varpi}{^*}V/4{\pi}$ where ${\varpi}_v{^*}$ is the single scattering albedo of $CH_4$ consisting of Einstein A coefficient and collisional deexcitation rate. Other terms are usual radiative transfer parameters appearing in textbooks including the terms for scattered ${\varpi}_v{^*}J_v$, thermal $(1-{\varpi}_v{^*})B_v$, and attenuated solar radiations $F_{ov}$ at the certain atmospheric layer. For auroral excitations, we include V, which is the number of excited states per $cm^3$ persec by auroral particle bombardments. We apply this formalism to the high-resolution spectra of the auroral regions observed with GNIRS/Gemini North, and will present preliminary results for the 3 micron auroral processes of Jupiter.

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Fabrication of a high magnetization YBCO bulk superconductor by a bottom-seeded melt growth method

  • Hong, Yi-Seul;Park, Soon-dong;Kim, Chan-Joong;Lee, Hee-Gyoun
    • Progress in Superconductivity and Cryogenics
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    • v.21 no.4
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    • pp.19-23
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    • 2019
  • A large grain YBCO bulk superconductor is fabricated by the top-seeded melt growth (TSMG) method. In the TSMG process, the seed crystal is placed on the top surface of a partially melted compact and therefore the seed crystal is frequently tilted during the melt process due to intrinsic unstable nature of Y211 particle +liquid phase mixture. In this work, we report the successful growth of single-domain YBCO bulk superconductors by a bottom-seeded melt growth (BSMG) method. Investigations on the trapped magnetic field and the microstructures of the synthesized specimens show that a bottom-seeded melt growth method has hardly affected on the crystal growth behavior, the microstructure development and the magnetic properties of the large grain YBCO bulk superconductors. The bottom-seeded melt growth method is clearly beneficial for the stable control of seed orientation through the melt process for the fabrication of a large grain YBCO bulk superconductor.

Numerical and Experimental Studies of Dual Subsea Pipelines in Trench

  • Jo, Chul H.;Shin, Young S.;Min, Kyoung H.
    • Journal of Ship and Ocean Technology
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    • v.6 no.2
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    • pp.12-22
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    • 2002
  • Offshore pipelines play an important role in the transportation of gas, oil, water and oil products. It is common to have a group of pipelines in the oil and gas field. To reduce the installation cost and time, dual pipelines are designed. There are great advantages in the installation of dual pipelines over two separate single lines. It can greatly reduce the cost for trench, back-filling and installation. However the installation of dual pipelines often requires technical challenges. Pipelines should be placed to be stable against external loadings during installation and design life period. Dual pipelines in trench can reduce the influence of external forces. To investigate the flow patterns and forces as trench depth and slope changes, number of experiments are conducted with PIV(Particle Image Velocimetry) equipment in a Circulating Water Channel. Numerical approaches to simulate experimental conditions are also made to compare with experimental results. The velocity fields around dual pipelines in trench are investigated and analysed. Comparison of both results show similar patterns of flow around pipelines. It is proved that the trench depth contributes significantly on hydrodynamic stability. The trench slope also affects the pipeline stability. The results can be applied in the stability design of dual pipelines in trench section. The complex flow patterns can be effectively linked in the understanding of fluid motions around multi-circular bodies in trench.

The study on source regions of solar energetic particles detected by widely separated multiple spacecraft

  • Park, Jinhye;Innes, D.E.;Bucik, R.;Moon, Y.J.
    • The Bulletin of The Korean Astronomical Society
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    • v.37 no.2
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    • pp.110.1-110.1
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    • 2012
  • We studied the source regions of 12 solar energetic particle (SEP) events seen between 2010 August and 2012 January at STEREO-A, B and ACE, when the two STEREO spacecraft were separated by about $180^{\circ}$. All events were associated with strong flares (C1 - X6) and fast coronal mass ejections (CMEs) accompanied by type II radio bursts. We have determined the arrival times of the SEP events at the three spacecraft. EUV waves observed in $195{\AA}$ and $193{\AA}$ channels of STEREO and SDO/AIA are tracked across the Sun and the arrival time of the EUV wave at the photospheric source of open field lines extending to the spacecraft connection points at 2.5 Rsun estimated. We found 7 events with flux enhancements in all spacecraft and 4 in two spacecraft. Most events came from a single source. The results show that magnetic field connections between source regions and the spacecraft play an important role in abrupt flux enhancements. In the most cases, EUV waves at the Sun are associated with a wide longitudinal spread of the SEPs.

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Neutron activation analysis: Modelling studies to improve the neutron flux of Americium-Beryllium source

  • Didi, Abdessamad;Dadouch, Ahmed;Jai, Otman;Tajmouati, Jaouad;Bekkouri, Hassane El
    • Nuclear Engineering and Technology
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    • v.49 no.4
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    • pp.787-791
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    • 2017
  • Americium-beryllium (Am-Be; n, ${\gamma}$) is a neutron emitting source used in various research fields such as chemistry, physics, geology, archaeology, medicine, and environmental monitoring, as well as in the forensic sciences. It is a mobile source of neutron activity (20 Ci), yielding a small thermal neutron flux that is water moderated. The aim of this study is to develop a model to increase the neutron thermal flux of a source such as Am-Be. This study achieved multiple advantageous results: primarily, it will help us perform neutron activation analysis. Next, it will give us the opportunity to produce radio-elements with short half-lives. Am-Be single and multisource (5 sources) experiments were performed within an irradiation facility with a paraffin moderator. The resulting models mainly increase the thermal neutron flux compared to the traditional method with water moderator.