• Corrosion Science and Technology
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• 제7권3호
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• pp.182-186
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• 2008

The microstructures of the oxide scale developed at high temperature on steels are very complex and their development depends on many factors including time, temperature, oxidation conditions and alloying elements. The classical model of an oxide scale on steel consisting of wüstite, magnetite and haematite layers, is more complicated in reality and its properties change with the factors that affect their development. An understanding of the oxide scale formation and its properties can only be achieved by careful examination of the scale microstructure. The oxide scale microstructure may be difficult to characterise by conventional techniques such as optical or standard scanning electron microscopy. An unambiguous characterisation of the scale and the correct identification of the phases within the scale are difficult unless the crystallographic structure for each phase in the scale is considered and a simultaneous microstructure-microtexture analysis is carried out. In the current study Electron Backscatter Diffraction (EBSD) has been used to investigate the microstructure of iron oxide layers grown on low carbon steels at different times and temperatures. EBSD has proved to be a powerful technique for identifying the individual phases in the oxide scale accurately. The results show that different grain shapes and sizes develop for each phase in the scale depending on time and temperature.

• Bulletin of the Korean Chemical Society
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• 제30권2호
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• pp.449-453
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• 2009

A mesoporous assembly of layered titanate with well-dispersed Pt cocatalysts has been synthesized via a restacking of exfoliated titanate nanosheets and a simultaneous adsorption of Pt nanoparticles. According to powder X-ray diffraction analysis, the obtained mesoporous assembly shows amorphous structure corresponding to the disordered stacking of layered titanate crystallites. Field emission-scanning electron microscopy and $N_2$ adsorption-desorption isotherm measurement clearly demonstrate the formation of mesoporous structure with expanded surface area due to the house-of-cards type stacking of the titanate crystallites. From high resolution-transmission electron microscopy and elemental mapping analyses, it is found that Pt nanoparticles with the size of ~2.5 nm are homogeneously dispersed in the mesoporous assembly of layered titanate. In comparison with the protonated titanate, the present mesoporous assembly of layered titanate exhibits better photocatalytic activity for the photodegradation of organic molecules. This finding underscores that the restacking of exfoliated nanosheets is quite useful not only in creating mesoporous structure but also in improving the photocatalytic activity of titanium oxide.

• KSBB Journal
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• 제26권5호
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• pp.422-426
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• 2011

Alginate bead has been supplemented with various polymers to control permeability and to enhance mechanical strength. In this report, fibroin-reinforced alginate hydrogel was prepared, in which spatial localization of fibroin molecules was investigated. Confocal laser scanning microscopy revealed that fibroin molecules formed a fibrous network in the alginate-fibroin beads, which was expected to enhance mechanical strength as same as in many composite materials. Uniaxial compression test showed that fibroin-reinforced alginate beads had increased mechanical strength only after methanol treatment that caused ${\beta}$-sheet formation among fibroin molecules. Simultaneous curing and dialysis of alginate beads were carried out to remove excesscalcium but to retain fibroin in the dialysis chamber, which fabricated beads without internal fibrous fluorescent stains. Fibroin molecules were only found beneath the surface of the beads. The fibroin-diffused shell was further processed to form a thick wall after drying or was mobilizedto the centre of the bead by methanol treatment. Accordingly, the structure analyses provide processing methods of fibroin to form a wall or center clumps, which could be applied to design controlled delivery device.

• Applied Microscopy
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• 제44권4호
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• pp.111-116
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• 2014

This study investigates the developmental pattern of adhesive discs (ADs) to highlight the ontogeny and structural changes that occur during the growth of Boston ivy. Initiation to postmortem features of ADs were examined through light and scanning electron microscopy. The study also reveals a new finding of the dislocation of peripheral tissues of adaxial origin. Four phases of attachment are suggested with regards to its climbing behavior: 1) pre-attachment, 2) upon attachment, 3) after attachment, and 4) final attachment. During initiation, several ADs originate from tendril primordia without epidermal differentiation. However, different growth rates in the epidermis results in completely different ADs. ADs were discerned by size, shape, and color during expansion, but cells in the adaxial surface remained alive longer than the other side. Upon contact, the ADs demonstrate simultaneous growth and deterioration, but once attachment is established the latter process subdues to final stages. Epidermal transformation, adhesive secretion, cellular disruption, and mechanical stress were essential for the self-clinging nature of Boston ivy. The post-attachment sequence is also believed to be critical in achieving maximum mechanical strength to provide extensive support. The developmental process of ADs is prompted by tactile stimulation but in a highly organized and systematic manner.

• 한국산학기술학회:학술대회논문집
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• 한국산학기술학회 2010년도 춘계학술발표논문집 1부
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• pp.108-112
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• 2010

Confocal Imaging System is an essential machine for a wide range of inspection wafer. For concurrent and fast acquiring the image data of four channels, the new image acquisition system used the protocol of camera-link standard with the full mode of configuration in interconnection with a frame grabber integrated in a computer, which is popularly used for many cameras, so the programming environment of image processing is optional such as Visual C++, Matlab. In addition, many conventional methods were coordinately used for contribution to build the high quality of images for precise processing analog signals of PhotoMutiplier Tubes(PMTs), accurate control of scanning device, sensitivity of PMTs, and laser source. The prototype of new image acquisition system, could meet the goal of development, it is used in LSCM for high content screening to investigation the processes of elements of living specimens at the same time by simultaneous grab image data on 4 PMTs channels.

• Journal of Electrochemical Science and Technology
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• 제9권4호
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• pp.260-275
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• 2018

The corrosion inhibition of cast iron in 1 M HCl by Phenanthroline (Phen) was investigated using potentiodynamic polarization (PDP) curves, electrochemical impedance spectroscopy (EIS), surface analysis and theoretical calculations. It is found that Phen exhibits high inhibition activity towards the corrosive action of HCl and its adsorption obeys the Langmuir adsorption isotherm model. The results showed that inhibition efficiency increases with Phen concentration up to a maximum value of 96% at 1.4 mM, and decreases slightly with the increase in temperature. The free adsorption energy value indicates that Phen adsorbs on cast iron surface in 1 M HCl via a simultaneous physisorption and chemisorption mechanism. Scanning electron microscopy (SEM) micrographs, atomic force microscopy (AFM) and FTIR analysis confirmed the formation of a protective film on cast iron surface, resulting in the improvement of its corrosion resistance in the studied aggressive solution. Quantum chemical calculations at the DFT level were achieved to correlate electronic structure parameters of Phen molecules with their adsorption mode.

• Journal of the Korean Wood Science and Technology
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• 제47권4호
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• pp.472-485
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• 2019

When wood plastic composites (WPCs) have been used for a certain period of time, they become waste materials and should be recycled to reduce their environmental impact. Waste WPCs can be transformed into reinforced composites, in which fillers are used to improve their performance. In this study, recycled WPCs were prepared using different proportions of waste WPCs, nanoclay, and glass fiber. The effects of nanoclay and glass fiber on the microstructural, mechanical, thermal, and water absorption properties of the recycled WPCs were investigated. X-ray diffraction showed that the nanoclay intercalates in the WPCs. Additionally, scanning electron micrographs revealed that the glass fiber is adequately dispersed. According to the analysis of mechanical properties, the simultaneous incorporation of nanoclay and glass fiber improved both tensile and flexural strengths. However, as the amount of fillers increases, their dispersion becomes limited and the tensile and flexural modulus were not further improved. The synergistic effect of nanoclay and glass fiber in recycled WPCs enhanced the thermal stability and crystallinity ($X_c$). Also, the presence of nanoclay improved the water absorption properties. The results suggested that recycled WPCs reinforced with nanoclay and glass fiber improved the deteriorated performance, showing the potential of recycled waste WPCs.

• Structural Engineering and Mechanics
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• 제83권1호
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• pp.79-92
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• 2022

In this paper, the impact of a vernacular pozzolanic kaolinite mine on concrete alkali-silica reaction and strength has been evaluated. For making the samples, kaolinite powder with various levels has been used in the quality specification test of aggregates based on the ASTM C1260 standard in order to investigate the effect of kaolinite particles on reducing the reaction of the mortar bars. The compressive strength, X-Ray Diffraction (XRD) and Scanning Electron Microscope (SEM) experiments have been performed on concrete specimens. The obtained results show that addition of kaolinite powder to concrete will cause a pozzolanic reaction and decrease the permeability of concrete samples comparing to the reference concrete specimen. Further, various machine learning methods have been used to predict ASR-induced expansion per different amounts of kaolinite. In the process of modeling methods, optimal method is considered to have the lowest mean square error (MSE) simultaneous to having the highest correlation coefficient (R). Therefore, to evaluate the efficiency of the proposed model, the results of the support vector machine (SVM) method were compared with the decision tree method, regression analysis and neural network algorithm. The results of comparison of forecasting tools showed that support vector machines have outperformed the results of other methods. Therefore, the support vector machine method can be mentioned as an effective approach to predict ASR-induced expansion.

• 한국건설관리학회논문집
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• 제17권3호
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• pp.32-42
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• 2016

현재 국내 대부분의 토목 건축 구조물이 BIM 정보가 부재한 상황에서 준공 BIM(as-built BIM)의 수요가 점차 증가하고 있다. 준공 BIM 구축을 위한 공간자료 취득에는 고밀도의 포인트 클라우드를 생성할 수 있는 레이저 스캐너가 주로 활용되고 있다. 하지만 기존의 고정식 스캔 시스템은 이동이 번거롭고, 정밀한 위치 선정이 필요 하며, 스캔 자료 정합을 위해 별도의 표지를 설치하거나 공액점을 추출하는 과정이 필요하다. 본 연구에서는 수작업을 최소화하기 위해 기존의 고정식 스캔 시스템을 대체할 수 있는 이동식 스캔 시스템을 제안하고자 하며, 기반 기술로 graph-based SLAM을 적용하였다. 테스트 장비는 총 세 개의 2차원 스캐너를 탑재하고 있으며, 중앙의 한 개는 수평으로 설치되어 graph 구축을 통한 이동경로취득에 사용되었고, 좌우 두 개는 수직으로 설치되어 시스템 진행의 연직 방향으로 주변 구조물에 대한 3차원 스캔 정보 취득에 사용되었다. 개발된 graph-based SLAM은 이동경로 상에 누적된 위치오차를 해소하기 위한 loop closure 처리 방법으로 Adaboost 기계학습을 적용하였다. 이는 특히 본 연구에서 사용한 장비와 같이 기계학습을 위한 다수의 feature 정보를 제공할 수 있는 멀티 스캐너 시스템에 적합한 방식이며, 두 실내공간을 대상으로 한 테스트에서 단일 스캐너 대비 false positive rate를 각각 7.9% 및 13.6%까지 줄일 수 있었다. 최종적으로 연구대상지역의 2차원 및 3차원 지도 구축을 통해 개발된 graph-based SLAM의 효용성을 확인하였다.

• 터널과지하공간
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• 제34권1호
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• pp.1-14
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• 2024

폐광산의 갱도 입구를 통해 고속 라이다(Light Detection And Ranging, LiDAR) 장비가 탑재된 무인이동체를 투입하여 폐광의 갱도를 형상화하기 위한 기술이 제안되었다. 직경이 1.5 m 이상인 좁은 갱도에 바닥이 슬러지 형태로 미끄럽고 장애물이 있는 환경에서 무인 이동체를 운영할 때 고려할 사항을 검토하였다. 육상환경 이동을 위해 4족 보행 로봇을 활용하였으며 항공 환경 이동을 위해 쿼드콥터 드론이 활용되었다. 수중환경의 갱도에 투입하기 위해서 수중 드론이 사용되었다. 무인 이동체를 실제 광산 현장에 투입하여 폐광 현장용 이동체가 고려해야 할 변수들을 도출하였다. 폐광산 갱도 형상화용 센서로서 2차원 영상 기반의 solid-state 라이다가 사용되었다. 방사형으로 측정되는 라이다의 특성을 고려하여 고정 경사각을 두어 회전시켜 운영하여 갱도 형상화를 위한 효율성을 높이고 동시에 장애물 감지도 같이 수행할 수 있도록 제안하였다. Solid-state 라이다를 이용하여 측정데이터로부터 센서의 자세와 로봇의 자세를 반영하여 현실 좌표계 데이터로 변환하기 위한 계산기법이 도출되었다. 라이다 센서와 무인 비행체가 결합하여 실제 현장에 투입하여 갱도 형상을 추출하였다. 마지막으로 실제 현장에서 효용성을 높이기 위한 요소를 도출하였다.