• Title/Summary/Keyword: simulated fuel

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Treatment of Simulated Soil Decontamination Waste Solution by Ferrocyanide-Anion Exchange Resin Beads (Ferrocyanide-음이온 교환수지에 의한 모의 토양제염 폐액 처리)

  • Won Hui Jun;Kim Min Gil;Kim Gye Nam;Jung Chong Hun;Park Jin Ho;Oh Won Zin
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.3 no.1
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    • pp.41-47
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    • 2005
  • Preparation of ferrocyanide-anion exchange resin and adsorption test of the prepared resin on the Cs$^{+}$$ion were performed. Adsorption capability of the prepared resin on the Cs$^{+}$ion in the simulated citric acid based soil decontamination waste solution was 4 times greater than that of the commercial cation exchange resin. Adsorption equilibrium of the prepared resin on the Cs$^{+}$ion reached within 360 minutes. Adsorption capability on the Cs$^{+}$ion became to decrease above the necessary Co$^{2+}$ion concentration in the experimental range. Recycling test of the spent ion exchange resin by the successive application of hydrogen peroxide and hydrazine was also performed. It was found that desorption of Cs$^{+}$ion from the resin occurred to satisfy the electroneutrality condition without any degradation of the resin.

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Recovery of Zirconium and Removal of Uranium from Alloy Waste by Chloride Volatilization Method

  • Sato, Nobuaki;Minami, Ryosuke;Fujino, Takeo;Matsuda, Kenji
    • Proceedings of the IEEK Conference
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    • 2001.10a
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    • pp.179-182
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    • 2001
  • The chloride volatilization method for the recovery of zirconium and removal of uranium from zirconium containing metallic wastes formed in spent fuel reprocessing was studied using the simulated alloy waste, i.e. the mixture of Zr foil and UO$_2$/U$_3$O$_{8}$ powder. When the simulated waste was heated to react with chlorine gas at 350- l00$0^{\circ}C$, the zirconium metal changed to volatile ZrCl$_4$showing high volatility ratio (Vzr) of 99%. The amount of volatilized uranium increases at higher temperatures causing lowering of decontamination factor (DF) of uranium. This is thought to be caused by the chlorination of UO$_2$ with ZrCl$_4$vapor. The highest DF value of 12.5 was obtained when the reaction temperature was 35$0^{\circ}C$. Addition of 10 vol.% oxygen gas into chlorine gas was effective for suppressing the volatilization of uranium, while the volatilization ratio of zirconium was decreased to 68% with the addition of 20 vol.% oxygen. In the case of the mixture of Zr foil and U$_3$O$_{8}$, the V value of uranium showed minimum (44%) at 40$0^{\circ}C$ with chlorine gas giving the highest DF value 24.3. When the 10 vol.% oxygen was added to chlorine gas, the V value of zirconium decreased to 82% at $600^{\circ}C$, but almost all the uranium volatilized (Vu=99%), which may be caused by the formation of volatile uranium chlorides under oxidative atmosphere.ere.

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Numerical Analysis-Based Design of PEMFC Channel, Fabrication of Channels, and Performance Test Using SU-8 (수치해석을 통한 PEMFC 채널의 설계와 SU-8을 이용한 채널 제작 및 성능 평가)

  • Choi, In-Jea;Wang, Hak-Min;Choi, Kap-Seung;Kim, Hyung-Man
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.34 no.4
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    • pp.349-354
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    • 2010
  • Fuel cells have attracted enormous interest as new power sources because the cells can be used to solve the problem of environmental pollution as well as the natural-resource exhaustion problem. In this study, hydrogen-gas flow in microchannels of different shapes was numerically analyzed to improve the efficiency of a microfuel cell. Flow characteristics in six microchannels of different shapes but under identical boundary conditions were simulated. The analysis result shows that the flow characteristics such as velocity, uniformity, and flow rate, greatly depend upon the channel shape. This implies that the efficiency of microfuel cell can be expected to be increased by adopting the optimal configuration of channel shape for hydrogen-gas flow. The experimental results show that power density of a PEMFC with a microflow channel is higher than that of a PEMFC without a microflow channel; however, a durable catalyst is required in MEA.

A-KRS GoldSim Model Verification: A Comparison Study of Performance Assessment Model (KAERI A-KRS 골드심 성능평가 모델 비교 검증 연구)

  • Lee, Youn-Myoung;Jeong, Jongtae
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.11 no.2
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    • pp.103-114
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    • 2013
  • The Korea Atomic Energy Research Institute has developed a performance assessment model implementing the A-KRS concept, which was constructed with the GoldSim. In the A-KRS concept, spent nuclear fuel produced from pressurized-water-reactor operations would be pyroprocessed to reduce waste volume and radioactivity. The wastes to be disposed of in a geologic repository are comprised of metal and ceramic waste forms. In this study, results of simulations conducted to establish credibility and build confidence for the A-KRS model are presented. Specifically, release rates and breakthrough times simulated using the A-KRS model were compared to corresponding results from the U.S. NRC SOAR model. In addition, the A-KRS model results were compared to published release rates from the SKB repository performance assessment. This comparison of the A-KRS model results to other independent performance assessments is expected to form part of a suite of model verification and validation activities to provide confidence that the A-KRS model has been implemented appropriately.

Ion Conductivity of Membrane in Proton Exchange Membrane Fuel Cell (고분자전해질 연료전지에서 고분자 막의 이온 전도도)

  • Hwang, Byungchan;Chung, Hoi-Bum;Lee, Moo-Seok;Lee, Dong-Hoon;Park, Kwonpil
    • Korean Chemical Engineering Research
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    • v.54 no.5
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    • pp.593-597
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    • 2016
  • The effects of relative humidity, current density and temperature on the ionic conductivity were studied in PEMFC (Proton Exchange Membrane Fuel Cell). Water contents and water flux in the electrolyte membrane largely affected ion conductivity. The water flux was modelled and simulated by only electro-osmotic drag and back-diffusion of water. Ion conductivities were measured at membrane state out of cell and measured at MEA (Membrane and Electrode Assembly) state in condition of operation. The water contents in membrane increase as relative humidity increased in PEMFC, as a results of which ion conductivity increased. Current enhanced electro-osmotic drag and back diffusion and then water contents linearly increased. Enhancement of current density results in ion conductivity. Ion conductivity of about 40% increased as the temperature increased from $50^{\circ}C$ to $80^{\circ}C$.

Investigation of molten fuel coolant interaction phenomena using real time X-ray imaging of simulated woods metal-water system

  • Acharya, Avinash Kumar;Sharma, Anil Kumar;Avinash, Ch.S.S.S.;Das, Sanjay Kumar;Gnanadhas, Lydia;Nashine, B.K.;Selvaraj, P.
    • Nuclear Engineering and Technology
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    • v.49 no.7
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    • pp.1442-1450
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    • 2017
  • In liquid metal fast breeder reactors, postulated failures of the plant protection system may lead to serious unprotected accidental consequences. Unprotected transients are generically categorized as transient overpower accidents and transient under cooling accidents. In both cases, core meltdown may occur and this can lead to a molten fuel coolant interaction (MFCI). The understanding of MFCI phenomena is essential for study of debris coolability and characteristics during post-accident heat removal. Sodium is used as coolant in liquid metal fast breeder reactors. Viewing inside sodium at elevated temperature is impossible because of its opaqueness. In the present study, a methodology to depict MFCI phenomena using a flat panel detector based imaging system (i.e., real time radiography) is brought out using a woods metal-water experimental facility which simulates the $UO_2-Na$ interaction. The developed imaging system can capture attributes of the MFCI process like jet breakup length, jet front velocity, fragmented particle size, and a profile of the debris bed using digital image processing methods like image filtering, segmentation, and edge detection. This paper describes the MFCI process and developed imaging methodology to capture MFCI attributes which are directly related to the safe aspects of a sodium fast reactor.

Scramjet Research at JAXA, Japan

  • Chinzei Nobuo
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • v.y2005m4
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    • pp.1-1
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    • 2005
  • Japan Aerospace Exploration Agency(JAXA) has been conducting research and development of the Scramjet engines and their derivative combined cycle engines as hypersonic propulsion system for space access. Its history will be introduced first, and its recent advances, focusing on the engine performance progress, will follow. Finally, future plans for a flight test of scramjet and ground test of combined cycle engine will be introduced. Two types of test facilities for testing those hypersonic engines. namely, the 'Ramjet Engine Test Facility (RJTF)' and the 'High Enthalpy Shock Tunnel (HIEST)' were designed and fabricated during 1988 through 1996. These facilities can test engines under simulated flight Mach numbers up to 8 for the former, whereas beyond 8 for the latter, respectively. Several types of hydrogen-fueled scramjet engines have been designed, fabricated and tested under flight conditions of Mach 4, 6 and 8 in the RJTF since 1996. Initial test results showed that the thrust was insufficient because of occurrence of flow separation caused by combustion in the engines. These difficulty was later eliminated by boundary-layer bleeding and staged fuel injection. Their results were compared with theory to quantify achieved engine performances. The performances with regards to combustion, net thrust are discussed. We have reached the stage where positive net thrust can be attained for all the test coditions. Results of these engine tests will be discussed. We are also intensively attempting the improvement of thrust performance at high speed condition of Mach 8 to 15 in High Enthalpy Shock Tunnel (HIEST). Critical issues for this purposemay be air/fuel mixing enhancement, and temperature control of combustion gas to avoid thermal dissociation. To overcome these issues we developed the Hypermixier engine which applies stream-wise vortices for mixing enhancement, and the M12-engines which optimizes combustor entrance temperature. Moreover, we are going to conduct the flight experiment of the Hypermixer engine by utilizing flight test infrastructure (HyShot) provided by the University of Queensland in fall of 2005 for comparison with the HIEST result. The plan of the flight experiment is also presented.

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Dynamic Simulation of the Water-steam System in Once-through Boilers - Sub-critical Power Boiler Case - (관류보일러 물-증기 계통의 동적 시뮬레이션 - 아임계 동력보일러 사례 -)

  • Kim, Seongil;Choi, Sangmin
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.41 no.5
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    • pp.353-363
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    • 2017
  • The dynamics of a water-steam system in a once-through boiler was simulated based on the physics-based modeling approach, representing the system in response to large load change or scale disturbance simulations. The modeling considered the mass, energy conservation, and momentum equation in the water pipe and the focus was limited to the sub-critical pressure region. An evaporator tube modeling was validated against the reference data. A simplified boiler system consisting of economizer, evaporator, and superheater was constructed to match a 500 MW power boiler. The dynamic response of the system following a disturbance was discussed along with the quantitative response characteristics. The dynamic response of the boiler system was further evaluated by checking the case of an off-design point operation of the feedwater-to-fuel supply ratio. The results re-emphasized the significance of controlling the feedwater-to-fuel supply ratio and additional design requirements of the water-steam separator and spray attemperator.

Modeling and Simulation of O2/CH4 Gas Supply System of Afterburner for Fuel-rich Gas of Gas Generator (가스발생기의 연료과잉가스 후연소용 O2/CH4 가스 공급시스템 설계)

  • Wang, Seungwon;Lee, Kwangjin;Chung, Yonggahp;Han, Yeoungmin
    • Journal of the Korean Society of Propulsion Engineers
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    • v.18 no.2
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    • pp.86-92
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    • 2014
  • Combustion Chamber Test Facility (CCTF) to be constructed in Naro Space Center for re-burning the fuel-rich gas of gas generator have afterburner system. The afterburner system is supplied the Oxygon ($O_2$) gas and Methane ($CH_4$) gas to reduced the harmful exhaust gas. The detailed design for the planned CCTF afterburner system is simulated and analysed by AMESim program through the all of gas supply system components. Afterburner system is performed to verify the pipe size, orifice diameter, and gas supply conditions according to the total gas consumption from analysis of gas supply system.

Turret location impact on global performance of a thruster-assisted turret-moored FPSO

  • Kim, S.W.;Kim, M.H.;Kang, H.Y.
    • Ocean Systems Engineering
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    • v.6 no.3
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    • pp.265-287
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    • 2016
  • The change of the global performance of a turret-moored FPSO (Floating Production Storage Offloading) with DP (Dynamic Positioning) control is simulated, analyzed, and compared for two different internal turret location cases; bow and midship. Both collinear and non-collinear 100-yr GOM (Gulf of Mexico) storm environments and three cases (mooring-only, with DP position control, with DP position+heading control) are considered. The horizontal trajectory, 6DOF (degree of freedom) motions, fairlead mooring and riser tension, and fuel consumptions are compared. The PID (Proportional-Integral-Derivative) controller based on LQR (linear quadratic regulator) theory and the thrust-allocation algorithm which is based on the penalty optimization theory are implemented in the fully-coupled time-domain hull-mooring-riser-DP simulation program. Both in collinear and non-collinear 100-yr WWC (wind-wave-current) environments, the advantage of mid-ship turret is demonstrated by the significant reduction in heave at the turret location due to the minimal coupling with pitch mode, which is beneficial to mooring and riser design. However, in the non-collinear WWC environment, the mid-turret case exhibits unfavorable weathervaning characteristics, which can be reduced by employing DP position and heading controls as demonstrated in the present case studies. The present study also reveals the plausible cause of the failure of mid-turret Gryphon Alpha FPSO in milder environment than its survival condition.