• Title/Summary/Keyword: simulated fuel

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Corrosion characteristics and interfacial contact resistances of TiN and CrN coatings deposited by PVD on 316L stainless steel for polymer electrolyte membrane fuel cell bipolar plates

  • Lee, Jae-Bong;Oh, In Hwan
    • Corrosion Science and Technology
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    • v.12 no.4
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    • pp.171-178
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    • 2013
  • In a polymer membrane fuel cell stack, the bipolar plate is a key element because it accounts for over 50% of total costs of the stack. In order to lower the cost of bipolar plates, 316L stainless steels coated with nitrides such as TiN and CrN by physical vapor deposition were investigated as alternative materials for the replacement of traditional brittle graphite bipolar-plates. For this purpose, interfacial contact resistances were measured and electrochemical corrosion tests were conducted. The results showed that although both TiN and CrN coatings decreased the interfacial contact resistances to less than $10m{\Omega}{\cdot}cm^2$, they did not significantly improve the corrosion resistance in simulated polymer electrolyte membrane fuel cell environments. A CrN coating on 316L stainless steel showed better corrosion resistance than a TiN coating did, indicating the possibility of using modified CrN coated metallic bipolar plates to replace graphite bipolar plates.

The nuclear fuel cycle code ANICCA: Verification and a case study for the phase out of Belgian nuclear power with minor actinide transmutation

  • Rodriguez, I. Merino;Hernandez-Solis, A.;Messaoudi, N.;Eynde, G. Van den
    • Nuclear Engineering and Technology
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    • v.52 no.10
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    • pp.2274-2284
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    • 2020
  • The Nuclear Fuel Cycle Code "ANICCA" has been developed by SCK•CEN to answer particular questions about the Belgian nuclear fleet. However, the wide range of capabilities of the code make it also useful for international or regional studies that include advanced technologies and strategies of cycle. This paper shows the main features of the code and the facilities that can be simulated. Additionally, a comparison between several codes and ANICCA has also been made to verify the performance of the code by means of a simulation proposed in the last NEA (OECD) Benchmark Study. Finally, a case study of the Belgian nuclear fuel cycle phase out has been carried out to show the possible impact of the transmutation of the minor actinides on the nuclear waste by the use of an Accelerator Driven System also known as ADS. Results show that ANICCA accomplishes its main purpose of simulating the scenarios giving similar outcomes to other codes. Regarding the case study, results show a reduction of more than 60% of minor actinides in the Belgian nuclear cycle when using an ADS, reducing significantly the radiotoxicity and decay heat of the high-level waste and facilitating its management.

Dissolution behavior of SrO into molten LiCl for heat reduction in used nuclear fuel

  • Kang, Dokyu;Amphlett, James T.M.;Choi, Eun-Young;Bae, Sang-Eun;Choi, Sungyeol
    • Nuclear Engineering and Technology
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    • v.53 no.5
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    • pp.1534-1539
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    • 2021
  • This study reports on the dissolution behavior of SrO in LiCl at varying SrO concentrations from low concentrations to excess. The amount of SrO dissolved in the molten salt and the species present upon cooling were determined. The thermal behavior of LiCl containing various concentrations of SrO was investigated. The experimental results were compared with results from the simulated results using the HSC Chemistry software package. Although the reaction of SrO with LiCl in the standard state at 650 ℃ has a slightly positive Gibbs free energy, SrO was found to be highly soluble in LiCl. Experimentally determined SrO concentrations were found to be considerably higher than those present in used nuclear fuel (<2 g/kg). As Sr-90 is one of the most important heat-generating nuclides in used nuclear fuel, this finding will be impactful in the development of fast, simple, and proliferation-resistant heat reduction processes for used nuclear fuel without the need for separating nuclear materials. Heat reduction is important as it decreases both the volume necessary for final disposal and the worker handling risk.

Computational Analysis of Nitrogen Oxides Reduction in Exhaust Gas from Livestock Manure Solid Fuel Using Urea-based Selective Non-catalytic Reduction (우레아 기반 SNCR 적용에 따른 가축분뇨 고체연료 배기가스 NOx 저감에 대한 전산해석)

  • Donghwan Shin;Hyeongwon Lee;Junghwan Kim;Jongyoung Jo
    • New & Renewable Energy
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    • v.20 no.3
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    • pp.1-11
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    • 2024
  • Livestock manure solid fuel has been studied as a promising domestic energy resource for reducing greenhouse gas emissions in agricultural fields. To successfully commercialize this technology, the environmental facilities require optimization in accordance with domestic environmental standards. In the present study, a computational analysis model of a livestock manure solid fuel boiler system was developed using Aspen Plus® to investigate nitrogen oxides (NOx) emissions and NOx conversion efficiency using urea-based selective non-catalytic reduction (SNCR). All data were compared across different livestock species and simulated at various operating temperatures. The simulation showed that NOx emissions were the highest from chicken manure and the lowest from swine manure. However, when converted to an oxygen concentration of 12%, NOx emissions were the highest from cattle manure. Dominant factors influencing NOx emissions through a range of temperatures were analyzed, and the optimal operating temperature range (875-950℃) was derived.

Estimation of the chemical compositions and corresponding microstructures of AgInCd absorber under irradiation condition

  • Chen, Hongsheng;Long, Chongsheng;Xiao, Hongxing;Wei, Tianguo;Le, Guan
    • Nuclear Engineering and Technology
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    • v.52 no.2
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    • pp.344-351
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    • 2020
  • AgInCd alloy is widely used as neutron absorber in nuclear reactors. However, the AgInCd control rods may fail during service due to the irradiation swelling. In the present study, a calculational method is proposed to calculate the composition change of the AgInCd absorber. Calculated results show that neutron fluence has significant impact on the chemical compositions. Ag and In contents gradually decrease while Cd and Sn conversely increases from the center to the rim of AgInCd absorber due to the depression of neutron flux. The composition change at the surface is higher almost two times than that at the center. Based on the calculated compositions, six simulated AgInCdSn alloys were prepared and examined. With the increase of Cd and Sn, the simulated AgInCdSn alloys transform from a single fcc phase into the mixed fcc and hcp phases, and finally into the single hcp phase. The atomic volume of the hcp phase is obviously larger than the fcc phase. The fcc-hcp transformation results in considerable volume swelling of the AgInCd absorber. Moreover, the lattice parameters of the fcc and hcp phases gradually increase with Cd and Sn contents, which also can induce small volume swelling.

A Case Study of Decreasing Environment Pollution Caused by Energy Consumption of a Dormitory Building Which Only Using Electricity by Efficiently Simulating Applying Residential SOFC (Solid Oxide Fuel Cell)

  • Chang, Han;Lee, In-Hee
    • Architectural research
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    • v.21 no.1
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    • pp.21-29
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    • 2019
  • Recent years in Korea, some new developed buildings are only using electricity as power for heating, cooling, bathing and even cooking which means except electricity, there is no natural gas or other kinds of energy used in such kind of building. In vehicle industry area, scientists already invented electric vehicle as an environment friendly vehicle; after that, in architecture design and construction field, buildings only using electricity appeared; the curiosity of the environment impact of energy consumption by such kind of building lead me to do this research. In general, electricity is known as a clean energy resource reasoned by it is noncombustible energy resource; however, although there is no environmental pollution by using electricity, electricity generation procedure in power plant may cause huge amount of environment pollution; especially, electricity generation from combusting coal in power plant could emit enormous air pollutants to the air. In this research, the yearly amount of air pollution by energy using under traditional way in research target building that is using natural gas for heating, bathing and cooking and electricity for lighting, equipment and cooling is compared with yearly amount of air pollution by only using electricity as power in the building; result shows that building that only uses electricity emits much more air pollutants than uses electricity and natural gas together in the building. According to the amount of air pollutants comparison result between two different energy application types in the building, residential SOFC (Solid oxide fuel cell) is simulated to apply in this building for decreasing environment pollution of the building; furthermore, high load factor could lead high efficiency of SOFC, in the scenario of simulating applying SOFC in the building, SOFC is shared by two or three households in spring and autumn to increase efficiency of the SOFC. In sum, this research is trying to demonstrate electricity is a conditioned environment friendly energy resource; in the meanwhile, SOFC is simulated efficiently applying in the building only using electricity as power to decrease the large amount of air pollutants by energy using in the building. Energy consumption of the building is analyzed by calibrated commercial software Design Builder; the calibrated mathematical model of SOFC is referred from other researcher's study.

High Efficiency Power Conversion System of Non Isolated Type Applied in Fuel Cell Generator Used to Fire Prevention Installation (소방 방재설비용 연료전지 발전시스템의 비절연형 고효율 전력변환기 설계)

  • Kwak, Dong-Kurl
    • Journal of the Microelectronics and Packaging Society
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    • v.13 no.3 s.40
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    • pp.19-26
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    • 2006
  • In this paper, author proposes to a fuel cell generation system used to fire prevention installation at emergency. The proposed system is used with a power source of fire prevention installation in preparation for breaking of commercial power supply at emergency. A part of most power loss of the fuel cell generation system is power converter. And the major losses of power converter are switching losses of power semiconductor switches used to power conversion. This parer is designed with a high efficiency power converter of non isolated type in order to increase efficiency of fuel cell power system. The controlling switches used in power conversion system are operated with soft switching, which is applied to partial resonant method to reduce switching loss. The result is that the fuel cell power system gets to high efficiency. Some computer simulated results and experimental results are confirmed to the validity of the analytical results.

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Simulation of Asymmetric Fuel Thermal Behavior Using 3D Gap Conductance Model (3 차원 간극 열전도도 모델을 이용한 핵연료봉의 열적 비대칭 거동 해석)

  • Kang, Chang Hak;Lee, Sung Uk;Yang, Dong Yol;Kim, Hyo Chan;Yang, Yong Sik
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.39 no.3
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    • pp.249-257
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    • 2015
  • A fuel assembly consists of fuel rods composed of pellets (UO2) and a cladding tube (Zircaloy). The role of the fuel rods in the reactor is to generate heat by nuclear fission, as well as to retain fission products during operation. A simulation method using a computer program was used to evaluate the safety of the nuclear fuel rods. This computer program has been called the fuel performance code. In the analysis of a light water reactor fuel rod, the gap conductance, which depended on the distance between the pellets and cladding tube, mainly influenced the thermomechanical behavior of the fuel rod. In this work, a 3D gap element was proposed to simulate the thermo-mechanical behavior of the nuclear fuel rod, considering the gap conductance. To implement the proposed 3D gap element, a 3D thermo-mechanical module was also developed using FORTRAN90. The asymmetric characteristics of the nuclear fuel rod, such as the MPS (missing pellet surface) and eccentricity, were simulated to evaluate the proposed 3D gap element.

Experimental Analysis of Fretting Wear Behaviors in Elastic Deformable Contacts (탄성변형 접촉에서 프레팅 마멸거동의 실험적 분석)

  • Lee, Young-Ho;Kim, Hyung-Kyu
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.34 no.1
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    • pp.49-54
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    • 2010
  • Fretting wear behavior under elastic deformable contacts was experimentally examined by using a simulated dual cooled fuel rod and its supporting structure. As this fuel rod has larger outer diameter than the typical solid rod to accommodate sufficient internal flow, new supporting structure geometries should be designed and their reliabilities (i.e. vibration characteristics, fretting wear resistance, etc.) are also examined with both analytical and experimental methods. In this study, the supporting structure characteristics and fretting wear behaviors are analyzed and examined by using one of the supporting structure candidates which has an embossing shape. The supporting structure characteristics were examined by using a specially designed test rig and their results were compared with that of analytical method. Based on the test results, the relationship between the supporting structure characteristics and their fretting wear behaviors was discussed in detail.

Experimental and Numerical Assessment of the Effects of Various Coolant Temperature in Gasoline Vehicle on Fuel Consumption and Emissions (냉각수온 변화가 가솔린 차량의 연비 및 배출가스에 미치는 영향에 관한 실험 및 수치적 평가)

  • Jeong, SooJin;Kim, SeoKyu;Lee, GumSu;Jeong, Jinwoo;Kim, MyungHwan
    • Transactions of the Korean Society of Automotive Engineers
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    • v.25 no.3
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    • pp.297-308
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    • 2017
  • One of the major engine thermal management system(TMS) strategies for improving fuel economy is to operate the engine in high temperatures. Therefore, this work performed a numerical and experimental study to examine the effect of several different STOs(Starting Temperature of Opening) of wax-thermostat, ranging from $85^{\circ}C$ to $105^{\circ}C$, of gasoline engine on fuel economy and emission characteristics. In this study, a gasoline car equipped with waxthermostat was tested and simulated under FTP-75 and HWFET mode. CRUISE $M^{TM}$ was used to simulate vehicle dynamics, transient engine performance and TMS. The test results showed fuel savings for both drive cycles due to higher STO of $100^{\circ}C$, which is slightly worse than that of $90^{\circ}C$ and amounts between 0.34 and 0.475 %. These controversial results are attributed to experimental errors and uncertainty. The computational results for three STOs, $85^{\circ}C$, $95^{\circ}C$ and $105^{\circ}C$, showed that fuel savings attributed to the application of higher STOs of $95^{\circ}C$ and $105^{\circ}C$ are relatively small and range from 0.306 to 0.363 %. It is also found that the amount of HC and CO emissions from the tailpipe tends to decrease with higher engine coolant temperature because of faster catalyst light-off and improved combustion.