• Bulletin of the Korean Chemical Society
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• 제27권6호
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• pp.875-880
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• 2006

A new, simple and fast flow injection analysis (FIA) method has been developed for the indirect determination of nitrite. The proposed indirect automatic method is based on the oxidation of nitrite to nitrate using a lead(IV) dioxide oxidant microcolumn where the flow of the sample through the microcolumn reduces the $PbO_2$ solid phase reagent to Pb(II), which is measured by flame atomic absorption spectrometry. The absorbance of Pb(II) are proportional to the concentration of nitrite in the samples. The calibration curve was linear up to 30 mg $L ^{-1}$, with a detection limit of 0.11 mg $L ^{-1}$ for a 400 mL injected sample volume and a sampling rate of about 80 $h ^{-1}$. The results exhibit no interference from the presence of large amounts of ions. The developed procedure was found to be suitable for the determination of nitrite in foodstuffs and wastewaters. A relative standard deviation better than 0.9% was obtained in a repeatability study. The reliability of the method was established by parallel determination against the standard method.

• Bulletin of the Korean Chemical Society
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• 제33권8호
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• pp.2724-2730
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• 2012

A new heterogeneous acidic catalyst was successfully prepared by impregnation of silica (Aerosil 300) by an acidic ionic liquid, named 1-(4-sulfonic acid)butylpyridinium hydrogen sulfate [$PYC_4SO_3H$][$HSO_4$], and characterized using FT-IR spectroscopy, the $N_2$ adsorption/desorption analysis (BET), thermal analysis (TG/DTG), and X-ray diffraction (XRD) techniques. The amount of loaded acidic ionic liquid on Aerosil 300 support was determined by acid-base titration. This new solid acidic supported heterogeneous catalyst exhibits excellent activity in the synthesis of 2-aryl-2,3-dihydroquinazolin-4(1H)-ones by cyclocondensation reaction of 2-aminobenzamide with aromatic aldehydes under solvent-free conditions and the desired products were obtained in very short reaction times with high yields. This catalyst has the advantages of an easy catalyst separation from the reaction medium and lower problems of corrosion. Recycling of the catalyst and avoidance of using harmful organic solvent are other advantages of this simple procedure.

• 대한화학회지
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• 제55권3호
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• pp.430-435
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• 2011

화력발전소에서 배출되는 석탄회를 이용하여 메조다공성 소재인 MCM-41을 제조하였다. 제조한 소재는 XRD, FTIR, SEM 및 EDS 방법으로 특성을 규명하였다. 이 소재의 촉매활성을 방향족 알데히드와 malonontrile의 Knoevenagel축합 반응에서 5-arylindene malononitriles의 합성에 대해 연구하였다. 이 방법의 특징은 쉬운 취급법, 안정성, 촉매의 재사용 및 생태친화성, 고수율, 짧은 반응시간, 간단한 실험과정 및 마무리 절차 등을 들 수 있다.

• 대한임베디드공학회논문지
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• 제15권1호
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• pp.25-33
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• 2020

Multipath routing protocols with unmanned aerial vehicles have been proposed to improve reliability in tactical ad hoc networks. Most of existing studies tend to establish the paths with multiple metrics. However, these approaches suffer from link loss and congestion problems according to the network condition because they apply same metric for both ground and air path or employ the simple weight value to combine multiple metrics. To overcome this limitation, in this study, we propose new routing metrics for path over unmanned aerial vehicles and use the multi-criteria decision making (MCDM) method to determine the weight factors between multiple metrics. For the case studies, we extend the ad-hoc on-demand distance vector protocol and propose a strategy for modifying the route discovery and route recovery procedure. The simulation results show that the proposed mechanism is able to achieve high end-to-end reliability and low end-to-end delay in tactical ad hoc networks.

• 대한관절경학회지
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• 제10권1호
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• pp.112-117
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• 2006

심부 정맥 혈전증(deep vein thrombosis)과 폐색전증(pulmonary embolism)은 정형외과적 수술 후 발생할 수 있는 심각하고 치명적인 합병증이다. 대부분의 시술은 인공관절 치환술등 절개가 큰 시술 후에 발생한다. 반면 슬관절의 관절경적 시술 같은 최소 침습적 수술의 경우, 그 위험도 및 예방적 조치에 대해 명확하게 밝혀지지 않고 있다. 슬관절의 관절경적 시술 후 발생한 폐색전증의 국외보고는 다소 있으나 국내보고는 아직 없어 2례에 대하여 보고하고자 한다.

• 한국음향학회지
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• 제10권2호
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• pp.29-35
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• 1991

본 논문에서는 변이음 단위의 Hidden Markov Model (HMM)을 이용하여 고립단어를 인식하는 방법을 논한다. 변이음 단위로 HMM을 구성하여 변이음 사전을 만들고, 이 변이음 사전을 이용하여 단어 사전을 구성한다. 변이음 HMM을 이용하여 단어를 구성하려면 변이음 간의 천이확률이 계산되어야 하므로 본 연구에서는 변이음 간의 천이 확률의 영향을 측정하여 그 변이음으로 이루어지는 임의의 단어를 적응없이 적은 수의 적응 데이터로 단어모델을 구성 인식하는 것을 설명한다. 비교를 위하여 단어인식 HMM으로 인식 실험을 한 결과, 변이음 단위 HMM이 적은 기억 용량과 적은 데이터의 훈련으로 단어단위 HMM 이상의 인식률을 얻을 수 있음을 보였다.

• 한국수학교육학회지시리즈E:수학교육논문집
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• 제28권1호
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• pp.65-79
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• 2014

스토리텔링 기법을 수학 교과서에 적용할 때, 스토리를 전개하는 방법에 따라 늘어나는 학습시간을 효율적으로 조절하는 것은 중요한 문제이다. 특히 고교과정의 수학은 중학교 과정과 비교하여 소화하여야 할 수학적 지식의 양과 질이 차별화 되므로, 각 단원에 적절한 스토리텔링 기법을 개발할 필요가 있다. 본 연구에서는 고등학교 미분적분학 단원을 중심으로, 공학적 도구를 활용하여 수학 문제 풀이에 요구되는 계산 시간을 줄여 개념학습 시간을 충분하게 확보하는 스토리텔링 교과서 개발 사례를 제시한다.

• 시스템엔지니어링학술지
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• 제15권2호
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• pp.57-65
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• 2019

The weapon system applies the rule that the system engineering procedure must be applied at the acquisition stage. Naval ships, which are one of the important naval weapon systems, take a long period of time to acquire, and the leadership must be commissioned. Therefore, in order to acquire a naval ship, high risk management is necessary, and it is necessary to promote business success through effective application of system engineering which is a scientific management method. However, in the case of naval ships, there are no specific procedures and methods for applying the system engineering. Therefore, research on application method of system engineering which can be easily used by person in charge is necessary. This should have a simple approach to ensure effective business performance by systematically refining and simplifying existing works. QFD (Quality Function Deployment) is a way to improve product satisfaction, impress customers, reduce defective products, reduce design errors, and reduce costs. This systematically develops these mutual relationships by converting the needs of customers into quality characteristics of products and defining them as the design quality of products considering the functions, quality, and process elements of parts. The purpose of this research is to present concrete methodology at the practical level using QFD in a way to ensure traceability of requirements which is an important element of system engineering.

• Earthquakes and Structures
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• 제12권3호
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• pp.359-374
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• 2017

The seismic events in Northern Italy, May 2012, have revealed the seismic vulnerability of typical Italian precast industrial buildings. The aim of this paper is to present a seismic fragility model for Italian RC precast buildings, to be used in earthquake loss estimation and seismic risk assessment by comparing two building typologies and three different codes: D.M. 3-03-1975, D.M. 16-01-1996 and current Italian building code that has been released in 2008. Based on geometric characteristics and design procedure applied, ten different building classes were identified. A Monte Carlo simulation was performed for each building class in order to generate the building stock used for the development of fragility curves trough analytical method. The probabilistic distributions of geometry were mainly obtained from data collected from 650 field surveys, while the material properties were deduced from the code in place at the time of construction or from expert opinion. The structures were modelled in 2D frameworks; since the past seismic events have identified the beam-column connection as the weakest element of precast buildings, two different modelling solutions were adopted to develop fragility curves: a simple model with post processing required to detect connection collapse and an innovative modelling solution able to reproduce the real behaviour of the connection during the analysis. Fragility curves were derived using both nonlinear static and dynamic analysis.

• Steel and Composite Structures
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• 제27권1호
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• pp.49-74
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• 2018

Generally, beam-column joints are taken into account as rigid in assessment of seismic performance of reinforced concrete (RC) structures. Experimental and numerical studies have proved that ignoring nonlinearities in the joint core might crucially affect seismic performance of RC structures. On the other hand, to improve seismic behaviour of such structures, several strengthening techniques of beam-column joints have been studied and adopted in practical applications. Among these strengthening techniques, the application of FRP materials has extensively increased, especially in case of exterior RC beam-column joints. In current paper, to simulate the inelastic response in the core of RC beam-column joints strengthened by FRP sheets, a practical joint model has been proposed so that the effect of FRP sheets on characteristics of an RC joint were considered in principal tensile stress-joint rotation relations. To determine these relations, a combination of experimental results and a mechanically-based model has been developed. To verify the proposed model, it was applied to experimental specimens available in the literature. Results revealed that the model could predict inelastic response of as-built and FRP strengthened joints with reasonable precision. The simple analytic procedure and the use of experimentally computed parameters would make the model sufficiently suitable for practical applications.