• Conservation Science in Museum
• /
• v.23
• /
• pp.91-108
• /
• 2020

This study conducted non-destructive analyses of the material features of seven gilt-bronze crowns of Baekje Kingdom that were excavated in the Cheonan, Gongju, Seosan, Iksan, Naju, and Hapcheon areas. A typical Baekje gilt-bronze crown has a conical inner crown and an outer crown embellished with vertical ornaments on the front and the back, a tube topped with a hemispherical ornament, and other ornamentation. Diverse designs (e.g., dragon, bonghwang, flowers, and plants) were applied using a range of techniques, including repoussé, chasing, openwork, and engraving. Formal features differ among the crowns according to their period of production and site of excavation. The substrate metal of the crowns is either pure copper or mixed copper with a small amount of lead. The crowns were amalgam-plated on the surface with pure gold or gold with a small amount of silver. The crown from Okjeon Tomb No. 23 in Hapcheon in the ancient Gaya region has a high silver content, which appears to be a regional feature. In addition, this crown from Okjeon Tomb No. 23, which can be categorized as Baekje-style gilt-bronze crown, seems to be plated at most three times, while the gilt-bronze crowns found within Baekje Kingdom territory were plated once or twice.

• Macromolecular Research
• /
• v.17 no.6
• /
• pp.378-387
• /
• 2009

This research compared three methods for producing and processing nanocomposite polypropylene filament yarns with permanent antimicrobial efficiency. The three methods used to mix antimicrobial agents based on silver nano particles with PP were as follows: 1) mixing of PP powder and inorganic nanocomposite filler with the appropriate concentration using a twin-screw extruder and preparing granules, 2) method 1 with a singlerather than twin-screw extruder, and 3) producing the masterbatch by a twin-screw extruder and blending it with PP in the melt spinning process. All pure polypropylene samples and other combined samples had an acceptable spinnability at the spinning temperature of $240^{\circ}C$ and take-up speed of 2,000 m/min. After producing as-spun filament yarns by a pilot plant, melt spinning machine, the samples were drawn, textured and finally weft knitted. The physical and structural properties (e.g., linear density, tenacity, breaking elongation, initial modulus, rupture work, shrinkage and crystallinity) of the as-spun and drawn yarns with constant and variable draw ratios (the variable draw ratio was used to gain a constant breaking elongation of 50%) were investigated and compared, while DSC, SEM and FTIR techniques were used to characterize the samples. Finally, the antibacterial efficiency of the knitted samples was evaluated. The experimental results revealed that the crystallinity reduction of the as-spun yarn obtained from method 1 (5%) was more than that of method 2 (3%), while the crystallinity of the modified as-spun yarns obtained with method 3 remained unchanged compared to pure yarn. However, the drawing procedure compensated for this difference. By applying methods 2 and 3, the drawing generally improved the tenacity and modulus of the modified fibers, whereas method 1 degraded the constant draw ratio. Although the biostatic efficiency of the nanocomposite yarns was excellent with all three methods, the modified fabrics obtained from methods 1 and 2 showed a higher bioactivity.

• Bulletin of the Korean Chemical Society
• /
• v.8 no.2
• /
• pp.69-72
• /
• 1987

The structures of dehydrated $Ag_9Cs_3$-A treated with hydrogen gas at three different temperatures have been determined by single-crystal X-ray diffraction techniques. Their structures were solved and refined in the cubic space group Pm3m at 23(1) $^{\circ}C$. All crystals were ion exchanged in flowing streams of aqueous $AgNO_3$/$CsNO_3$ with a mole ratio 1:3.0 to achieve the desired crystal composition. The structures treated with hydrogen at $23^{\circ}C(a=12.288(1)\;{\AA})\;and\;310^{\circ}C(a=12.291(2)\;{\AA})$ refined to the final error indices R1 = 0.091 and R2 = 0.079, and 0.065 and 0.073, respectively, using the 216 and 227 reflections, respectively, for which I >3${\sigma}$(I). In both of these structures, eight $Ag^+$ ions are found nearly at 6-ring centers, and three $Cs^+$ ions lie at the centers of the 8-rings at sites of $D_{4h}$ symmetry. One $Ag^{\circ}atom$, presumably formed from the reduction of a $Ag^+$ ion by an oxide ion of a residual water molecule or of the zeolite framework during the dehydration process, is retained within the zeolite, perhaps in a cluster. In these two structures hydrogen gas could not enter the zeolite to reduce the $Ag^+$ ions because the large $Cs^+$ ions blocked all the 8-windows. However, hydrogen could slowly diffuse into the zeolite and was able to reach and to reduce about half of the $Ag^+$ ions in the structure only at high temperature ($470^{\circ}C$). The silver atoms produced migrated out of the zeolite framework, and the protons generated led to substantial crystal damage.

• Bulletin of the Korean Chemical Society
• /
• v.5 no.3
• /
• pp.117-121
• /
• 1984

The structure of $CS_{7.3}Ag_{4.7}Si_{12}Al_{12}O_{48}$, vacuum dehydrated zeolite A with all Na+ ions replaced by $Cs^+$ and $Ag^+$ as indicated, has been determined by single-crystal x-ray diffraction techniques in the cubic space group, Pm3m (a = 12.282 (1) ${\AA}$). The structure was refined to the final error indices $R_1$$R_2$ (weighted) = 0.099 using 347 independent reflections for whind intlch $I_0\;>\;3{\sigma}(I_0)$. Although deydration occurred at $360^{\circ}C$, no silver atoms or clusters have been observed. The 8-ring sites are occupied only by $Cs^+$ ion, and the 4-ring sites only by a single $Ag^+$ ion. The 6-ring sites contain $Ag^+$ and $Cs^+$ ions with $Ag^+$ nearly in 6-ring planes and $Cs^+$ well off them, one on the sodalite unit side. With regard to the 6-rings, the structure can be represented as a superposition of two types of unit cells: about 70 % have $4Ag^+$ and $4Cs^+$ ions, and the remaining 30 % have $3Ag^+$ and $5Cs^+$. In all unit cells, $3Cs^+$ ions lie at the centers of the 8-rings at sites of D4h symmetry; these ions are approximately 0.3 ${\AA}$ further from their nearest framework-oxygen neighbors than the sum of the appropriate ionic radii would indicate. To minimize electrostatic repulsions, the $Cs^+$ ions at Cs(1) are not likely to occupy adjacent 6-rings in the large cavity; they are likely to be tetrahedrally arranged when there are 4.

• Journal of Conservation Science
• /
• v.37 no.3
• /
• pp.270-281
• /
• 2021

The Yongjam of Oejae, Yi Dan-ha's wife, is an ornamental hairpin with a dragon-shaped engraving; designated as National Folklore Cultural Heritage No. 4. It is also a component of the ceremonial costume, and an artifact of great value as it clearly identifies the position of the wearer and the period of this artifact. The Yongjam has been well preserved in general; however, various pollutants and corrosive products have affected the engraved patterns, requiring conservation treatment. Furthermore, a non-destructive analysis was conducted to identify the components of the materials and the manufacturing techniques used in the ornament. The Yongjam is hollow inside to reduce its weight when placed in the hair and has a color contrast of gold, red, and black. The decorative part and the body were made separately. That is, the body was made from an alloy of copper, silver, and zinc, and its joint was elaborately connected without any overlaps. In the decorative part, different alloy ratios were identified in the dragon's face, beard, horn, body, and fin. Further, for the dragon's face with its delicate patterns, an alloy of silver and copper was used, likely to make the face appear as realistic as possible.

• Conservation Science in Museum
• /
• v.21
• /
• pp.53-66
• /
• 2019

This study describes the processes undertaken for the conservation treatment of metal artifacts excavated in Hasong-ri, Yeongwol, Gangwon-do and the results of the related surface composition analysis. X-ray fluorescence analysis (XRF) was applied to analyze the surface composition of a small gilt-bronze wind chime, two clappers, and a small gourd-shaped bronze bottle. The gourd-shaped bronze bottle was investigated using radiography to examine its internal structure. The wind chime and clappers were excavated from the same location. A gilt layer was identified on the wind chime, but surface corrosion made it difficult to identify any such layers on the clappers. The element analysis revealed that the wind chime was made of bronze in a Cu-Sn-Pb ternary system and was gilt-plated using mercury amalgam. The clappers were made from copper with a small amount of gold detected, but did not show any evidence of mercury. Since a thick corrosion layer was affixed to the surface of each clapper, it was impossible to identify the surface composition and determine if the clappers had been gilded. It is possible that the gold detected from the clappers was a foreign substance or had detached from the giltbronze wind chime buried alongside them. The small gourd-shaped bronze bottle was investigated through surface element analysis and radiography to verify if it was a type of silver bottle used as currency during the Goryeo dynasty. The radiography photography identified that a small hole in the middle of the base had been stopped up. The general surface analysis did not detect silver, which suggests that the bottle was made of bronze instead and was not one of the silver bottles used as a means of currency.

• Journal of Plant Biotechnology
• /
• v.40 no.4
• /
• pp.224-230
• /
• 2013

Lily is an important cut-flower in Korea and world as well due to it's a variety of flower colors and various sizes of flowers. To develop elite lily cultivars, conventional breeding techniques have been used so far. However, an introduction of tissue culture system in mass propagation of bulbs and regeneration of shoots with a high efficiency is prerequisite at this moment. Especially, growth of bulbs and shoots as well as reduction of browning is critical factor to proliferate bulbs with shoots of superior lines or cultivar in lily. For this purpose, we tried to test whether ascorbic acid, citric acid and silver nitrate in medium to facilitate growth of bulbs and shoots as well as reduction of browning of bulb scales in lily. As a result, ascorbic acid and silver nitrate showed no significant differences compared to control plants in the growth of bulbs and shoots. When bulb scales were treated with $150mg{\cdot}l^{-1}$ of citric acid, formations of shoots and bulbs showed best result. While, bulb scale treated with $100mg{\cdot}l^{-1}$ of citric acid showed the growth of shoot and root as well as increasing of fresh weight compared to other treatments. Regarding the reduction of browning, $150mg{\cdot}l^{-1}$ of ascorbic acid showed the best result with the less than 2%. Although more experiments with several commercial varieties are needed in the future to establish mass propagation of bulbs of lily, results obtained in this study are supposed to provide the basic knowledge and contribution in tissue culture system of lily.

• Korean Journal of Heritage: History & Science
• /
• v.56 no.4
• /
• pp.24-37
• /
• 2023

This study analyzes the materials and external characteristics of the Angbu-ilgu, a kind of scaphe sundial, which was newly designated as a Korean Treasure in 2022. The Angbu-ilgu Treasure is owned by three institutions - the National Palace Museum Of Korea, Gyeongju National Museum, and Sungshin Women's University Museum - and is similar as a twin in its material, size, outward appearance, as well as production techniques that include casting, silver inlays, and metal joints. The Three-Treasure Angbu-ilgu is made of brass in the ratio of 90.6: 6.0: 1.8 with Cu: Zn: Pb. This composition clearly differs from Treasure No. 845, an Angbuilgu which has a composition ratio of 82.2: 3.7: 11.8 with Cu: Zn: Pb. In this new Angbu-ilgu Treasure, the hemisphere's stand has four vertical pillars sculpted in a dragon pattern and bilateral wings carved in a cloud pattern on the pillars, which are joined to the hemisphere's horizontal ring with rivets and silver solders, respectively. The dragon-in-clouds pillar (雲龍柱) shows the most outstanding formative beauty of the various Angbu-ilgu pillars produced in the late Joseon Dynasty. It can be seen that the altitude of the north pole engraved on the Angbu-ilgu was made after 1713. Production is, however, actually estimated to have occurred close to the 19th century, the era of the Jinju Kang family, who were professional Angbuilgu makers. Hopefully, this study will lead to a historical science and technology review with modern scientific instruments analyzing the materials and external characteristics of the three Angbu-ilgus designated as a Korean Treasure in 2022.

• Conservation Science in Museum
• /
• v.20
• /
• pp.13-30
• /
• 2018

Ancient metal objects with inlaid designs were mainly decorated using the wire inlay technique in which "V"- or "U"-shaped grooves were cut in a metal object and then filled with gold or silver. Previous studies on ancient metal objects featuring wire inlay generally attempted to ascertain the inlay techniques applied by examining photomicroscopes acquired during conservation treatment. However, they had limitations when examining wire inlay technique to the minute details. Wire inlay technique can be better investigated by enlarging X-ray films of relics using stereoscopic microscopy under transmitted light. The core processes of the wire inlay technique involve cutting grooves using a chisel and creating the inlay wires, but researchers hold varying opinions about the two processes. This study analyzed the entirety of the materials able to shed light on the main processes applied in Baekje wire inlay by examining X-ray films of relics through stereoscopic microscopy. This exhaustive research revealed that two types of techniques were used for wire inlay during the Baekje period. One is a plastic process of engraving dotted lines using a chisel and is found mostly in objects from the Cheonan and Gongju areas. The other is a cutting process that incises fine lines and was used mostly in relics from the Osan, Seosan, and Wanju areas. It is likely that the Baekje wire inlay techniques feature regional differences because the respective techniques were used or introduced by different groups of people.

• Applied Microscopy
• /
• v.10 no.1_2
• /
• pp.7-17
• /
• 1980

Electron microscope radioautography introduced by Liquier-Milward (1956) is now used routinely in many laboratories. Most of the technical difficulties in specimen preparation have been overcome. This method is modified from loop method for improvement of EM radioautographic techniques. The advantages of this method are: 1. the use of single specimens on small corks and of a large wire loop, allows the experimenter to avoid the blemishes in the membrane; 2. the surfactant dioctyl sodium sulphosuccinate is added to diluted ILford L4, thus greatly prolonging the period of time over which good emulsion layers can be made; 3. corks can be handled in perspex holder which allows about 20 specimens to be developed simultaneously. The steps of the method comprise: 1. Cut ribbons of ultrathin sections of silver interference colour 2. Pick them up on formvar-coated 200 mesh grids 3. Prestaining of tissues 4. Coat the specimens with a thin layer of carbon by evaporation (30-60A) 5. Mount the specimens on corks (about 1cm apical diameter) using double-sided scotch tape 6. Emulsion coating; a. Take a 250m1 beaker, place it on the pan of a sliding weight balance and weigh it. Add 10 grams extra to the beam. Add pieces of ILford L4 emulsion to the beaker until the balance is swinging freely. Add the 20ml of distilled water that was previously measured out. b. Surfactant dioctyl sodium sulphosuccinate is added to diluted ILford L4. 7. Prepare a series of membranes of gelled emulsion with the wire loop and apply one to each cork-borne specimen. 8. Put the specimens away to expose by pushing the corks into short length of PVC tubing, each tube having a small hole in the side 9. Place the tubes in small boxes together with silica gel. 10. Exposure 11. Developer - Kodak Microdol X for 3 minutes 12. Fixer - A perspex holder can be manufactured which allows 20 specimens to be developed simultaneously. 12. Fixer - 30% sodium thiosulfate for 10 minutes 13. Examination with Siemens Elmiskop 1A electron microscope