• 한국염색가공학회지
• /
• 제14권2호
• /
• pp.85-85
• /
• 2002

The interaction between berberine and tannin in aqueous solution was investigated spectrophotometerically. The dyeing mechanism of silk fabrics (control and tannin treated silk fabrics) with berberine was based on thermodynamic parameters obtained from equilibrium adsorption experiments. In adsorption spectra of aqueous solution of berberine and tannin mixture two isosbestic points (328nm, 357nm) were found and the mole fraction of reaction of components was 1:1. Initial dyeing rates were increased and the diffusion of dye was more effective by tannin treatment. Without regard to tannin treatment the adsorption isotherm of berberine was the langmuir type except high temperature, 80℃. By tannin treatment the saturation dye uptake was increased, the increase of dye uptake appeared to be a result of entropy change rather than enthalpy change. All these results can be interpreted by the hydrophobic interaction between berberine and silk treated with tannin and it is reasonable to conclude that not only the ionic force, but also the hydrophobic interaction contributes to the binding of berberine and tannin treated silk treated with tannin.

• 한국염색가공학회지
• /
• 제14권2호
• /
• pp.9-17
• /
• 2002

The interaction between berberine and tannin in aqueous solution was investigated spectrophotometerically. The dyeing mechanism of silk fabrics (control and tannin treated silk fabrics) with berberine was based on thermodynamic parameters obtained from equilibrium adsorption experiments. In adsorption spectra of aqueous solution of berberine and tannin mixture two isosbestic points (328nm, 357nm) were found and the mole fraction of reaction of components was 1:1. Initial dyeing rates were increased and the diffusion of dye was more effective by tannin treatment. Without regard to tannin treatment the adsorption isotherm of berberine was the langmuir type except high temperature, $80^\circ{C}$. By tannin treatment the saturation dye uptake was increased, the increase of dye uptake appeared to be a result of entropy change rather than enthalpy change. All these results can be interpreted by the hydrophobic interaction between berberine and silk treated with tannin and it is reasonable to conclude that not only the ionic force, but also the hydrophobic interaction contributes to the binding of berberine and tannin treated silk treated with tannin.

• 한국염색가공학회지
• /
• 제6권3호
• /
• pp.67-73
• /
• 1994

The adsorption behaviors of acid dye and disperse dye on silk and nylon fabrics were examined, in one bath dyeing system on silk/nylon blend fabric with disperse dyes and acid dyes. In the dyeing of nylon fabric with C. I. Disperse Red 19 (Red 19) and C. I. Disperse Red 60 (Red 60), dye uptake of Red 19 was higher than that of Red 60. When silk/nylon blend fabric was dyed with Red 19 and Red 0, the dye uptake on nylon was influenced by the ffinity of the dye to the silk fabric. In the dyeing of silk/nylon with C. I. Acid Blue 80 and C. I. Acid Yellow 121, solid shade could not be obtained with the conventional method but could be obtained with the dyeing resist agent for nylon. There was not any relationship between K/S value and Munsell value, but Munsell value tended to change with the K/S value.

• 한국염색가공학회지
• /
• 제18권6호
• /
• pp.25-30
• /
• 2006

Degumming is an essential process to improve the luster and smoothness of the silk filament. Silk varieties were degummed using different methods. A number of methods, from pad-steam to specific alkaline are being used for this propose. In this paper an attempt to compare the efficiencies of different degumming processes has been made. from the results, it may be observed that when silk fabrics were pad-steam, the degree of degumming, as assessed by weight loss. When the pad-steam degumming was carried out at different pHs, adjusted using alkalies, it was observed that at higher pH the weight loss is high. Pad-steam degumming as well as star degumming was found to be superior with minimum damage to the substrate. Among the alkalis used, the sodium carbonate gives the best results, since the weight loss is almost maximum with lower strength loss by over degumming. It is also efficient from the point of view of conservation of heat energy and time as against the comparable star degumming.

• 한국염색가공학회지
• /
• 제11권4호
• /
• pp.16-23
• /
• 1999

This study was made to investigate the effects of mimosa tannin and tannic acid on change of properties and photodegradation of silk fabrics according to tannin concentration and irradiation time. The results were as follows. 1. As concentration of tannin increased, thickness, fabric count and stiffness showed no difference. But tensile strength were increased, and elongation were decreased. 2. When concentration of tannin is high, tannin adhered to surface of fabrics. 3. fR absorption bands of untreated silk fabric appeared at $3400cm^{-1},\; 1640cm^{-1},\;1445cm^{-1},\;1235cm^{-1},\;and\;675cm^{-1}$, but those of silk fabric treated with tannic acid appeared at $1710cm^{-1}\;and\;3400cm^{-1}$ by treatment of mimosa tannin, respectively. IR absorption bands of photoirradiated silk fabrics appeared at $3400cm^{-1},\;3280cm^{-1},\;2960cm^{-1},\;2920cm^{-1},\; 1720cm^{ -1},\;1380cm^{-1},\;1280cm^{-1},\;1120cm^{-1},\;and\;1070cm^{-1}$. But those bands were decreased at the silk fabrics treated with mimosa tannin and tannic acid.

• 한국염색가공학회지
• /
• 제13권5호
• /
• pp.1-1
• /
• 2001

As the basic study to investigate the mechanism of improvement in the dyeing fastness of natural dyes on silk fabrics the optical behavior of tannin solution, the optimal condition of tannin treatment and the changes of the physical structure of silk fabrics were studied in the treatment of tannin. Results obtained were as follows ; 1.The K/S values of tannin-treated silk fabrics were not changed by tannin content on silk fabrics but yellowing of tannin in treatment condition. 2. As the concentration of tannin was increased in its treating condition, the tannin content and K/S vague of tannin-treated silk fabrics were increased. 3. Because tannin gave rise to yellowing by hydrolysis and oxidation at high temperature, the higher tannin-treating temperature was, the lower the tannin content and K/S values of silk fabrics 4. The tannin content of silk fabric was higher in acidic treating condition and the highest K/S value was showed at pH 5. 5. As the tannin content of silk fabric was increased, the value of ζ -potential of it became negative. 6. As the tannin content of silk fabric was increased, the crystallinity and crystallite size of it were decreased. This meant that the fraction of amorphous region in the fibers increased. And the degree of orientation of it was decreased with the tannin treatment.

• 한국염색가공학회지
• /
• 제13권5호
• /
• pp.289-297
• /
• 2001

As the basic study to investigate the mechanism of improvement in the dyeing fastness of natural dyes on silk fabrics the optical behavior of tannin solution, the optimal condition of tannin treatment and the changes of the physical structure of silk fabrics were studied in the treatment of tannin. Results obtained were as follows ; 1 The K/S values of tannin-treated silk fabrics were not changed by tannin content on silk fabrics but yellowing of tannin in treatment condition. 2. As the concentration of tannin was increased in its treating condition, the tannin content and K/S vague of tannin-treated silk fabrics were increased. 3. Because tannin gave rise to yellowing by hydrolysis and oxidation at high temperature, the higher tannin-treating temperature was, the lower the tannin content and K/S values of silk fabrics 4. The tannin content of silk fabric was higher in acidic treating condition and the highest K/S value was showed at pH 5. 5. As the tannin content of silk fabric was increased, the value of $\xi$ -potential of it became negative. 6. As the tannin content of silk fabric was increased, the crystallinity and crystallite size of it were decreased. This meant that the fraction of amorphous region in the fibers increased. And the degree of orientation of it was decreased with the tannin treatment.

• 한국잠사곤충학회지
• /
• 제43권1호
• /
• pp.41-48
• /
• 2001

The purification, dissolution and powdering of stained waste silk obtained from weaving and dyeing process were studied for the surface modification of textile fabric and plastic materials. The whiteness of stained waste silk could be improved through degumming and bleaching with sodium hydrosulfite. The water-soluble fibroin solution can be obtained by dissoving the degummed waste silk in a boiling solution of 50% calcium chloride for 60 minutes. The salts and heavy metals contained in fibroin solution were removed by electric dialysis, wool fiber filtration and gel filtration chromatography. The fibroin powder was prepared by using a fine grinder after the alkali treatment for weakening the silk fiber. The fine fibroin powder of particle size around 30 ㎛ was obtained with a ultra fine-mill, while it was finer below 10 ㎛ with a ball-mill. The dissolved or powdered silk was applied to the surface of fabric with addition of the binder (a urethane resin). The moisture content of polyester and nylon fabrics treated with the silk solution was improved due to hygroscopic property of silk. The fine fibroin powder mixed with the binder ws coated on the surface of synthetic film by use of the air pressed sprayer. It was revealed that the hygroscopicity as well as the softness of fibroin powder coated film was much improved. Therefore, it is thought that the fine silk fibroin powder is applicable as an coating agent for the surface modification of plastic and synthetic leather.

• 복식문화연구
• /
• 제19권1호
• /
• pp.19-30
• /
• 2011

The purpose of this study is to analyze the tendency of Korean traditional textile studies to review the studies critically and to suggest the new directions. To do this, this study included 164 articles of Korean traditional textile studies published in five Korean major journals from the first issue to the 2009. The identified 164 articles were categorized and analyzed by five areas : study subject, study content, study method, the tendency through times and journals publishing Korea traditional textile articles. The results were as follows. First, in the study subject, the ratio of traditional motifs study was the highest in any other study subject and an actual textile pattern study and society culture historic study were also favored. And, the ratio of foreign textile study was the lowest in any other study subject. Second, in the fiber type of study content, the ratio of silk fiber was the highest in any other fiber type. Hemp, ramie and cotton fiber were followed by silk fiber. Also, the ratio of wool fiber was lowest in any other fiber type. In the weaving type, ratio of plain weave was the highest in any other weaving type. In the times of study, the ratio of the Joseon Dynasty period was the highest in any other times of study. Third, in the study method, the ratio of an actual proof study method was higher than that of literature study method. In the tendency of times, there were society culture historic studies from the time publishing the first edition in each journal, the ratio of an actual textile pattern study, traditional motif study and preservation science study has increased since the 2000. Fourth, in the characteristics of journals, Journal of Korean Society of Costume has published the most articles in any other journal publishing Korea traditional textile study.

• 한국섬유공학회:학술대회논문집
• /
• 한국섬유공학회 1995년도 추계 학술발표회
• /
• pp.160-161
• /
• 1995