• International Journal of Concrete Structures and Materials
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• v.3 no.2
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• pp.97-101
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• 2009

It has been known that acid-resistant concretes on the liquid glass basis have high porosity (up to 18${\sim}$20%), low strength and insufficient water resistance. Therefore they can not be used as materials for load-bearing structural elements. Significant increasing of silicate matrix strength and density was carried out by incorporation of special liquid organic alkali-soluble silicate additives, which block of superficial pores and reduces concrete shrinkage deformation. It was demonstrated that introduction of tetrafurfuryloxisilane additive sharply increases strength, durability and shock resistance of silicate polymer concrete in aggressive media. This effect is attributable to hardening of contacts between silicate binder gel globes and modification of alkaline component owing to "inoculation" of the furan radical. The optimal concrete composition with the increased strength, chemical resistance in the aggressive environments, density and crack resistance was obtained.

• Proceedings of the Korean Institute of Building Construction Conference
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• 2020.06a
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• pp.81-82
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• 2020

In this study, after applying a silicate-based impregnation and polymer-based coating to fire damaged high strength concrete, carbonation resistance was evaluated to compare and evaluate the carbonation depth according to the type of surface repair materials. As a result of the experiment, it was confirmed that the carbonation resistance was increased in the case of the concrete with the surface repair materials compared to the control specimen without the surface repair materials. In particular, in the case of the polymer-based coating agent, it was confirmed that the carbonation hardly progressed.

• Advances in concrete construction
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• v.15 no.6
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• pp.419-430
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• 2023

In this study, the effect of two types of aggregates (fly ash aggregate and shale aggregate) on the density, strength, and durability of preplaced lightweight aggregate concrete (PLWAC) was studied. The results showed that the 7 - 28 days strength of concrete prepared with fly ash aggregates (high water absorption rate) significantly increased, which could attribute to the long-term water release of fly ash aggregates by the refined pore structure. In contrast, the strength increase of concrete prepared with shale aggregates (low water absorption rate) is not apparent. Although PLWAC prepared with fly ash aggregates has a lower density and higher strength (56.8 MPa @ 1600 kg/m³), the chloride diffusion coefficient is relatively high, which could attribute to the diffusion paths established by connected porous aggregates and the negative over-curing effect. Compared to the control group, the partial replacement of fly ash aggregates (30%) with asphalt emulsion (20% solid content) coated aggregates can reduce the chloride diffusion coefficient of concrete by 53.6% while increasing the peak load obtained in a three-point bending test by 107.3%, fracture energy by 30.3% and characteristic length by 103.5%. The improvement in concrete performance could be attributed to the reduction in the water absorption rate of aggregates and increased energy absorption by polymer during crack propagation.

• Proceedings of the Korea Concrete Institute Conference
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• 2005.11a
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• pp.563-566
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• 2005

Concrete structures have been damaged by salt, carbonization, freezing and thawing and the others. Therefore, it is needed to protect durability and performance according to the appropriate materials and methods in the concrete structures. In general, several types of polymer and silicate are used as protecting deterioration agents of concrete structures, but these agents have many problems because of low durability and properties. In this study, It developed the deterioration restraining agent using polycondensed silicate and monomer that can block a deterioration cause such as $CO_2$ gas, salt and water from the outside and enhance waterproofing ability by reinforcing the concrete surface when applying it to concrete structures. Also, it developed the systems for improving concrete performance using a deterioration restraining agent.

• Journal of the Korean Ceramic Society
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• v.47 no.4
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• pp.276-282
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• 2010

There are the impregnating layer formation by surface protective materials or impregnants and the adhesion method by polymer, FRP sheet or steel plate in the surface protective method of concrete structure. The surface impregnation method by impregnants improves the durability of concrete structure by modifying the structure of the concrete surface and also have a merit that can be shortly applied in place without the decrease of concrete surface appearance and is easily applied again. This study is interested in manufacturing the concrete surface impregnants including lithium and potassium silicate for the repair of the exposed concrete and the color concrete requiring the advanced function in view of the concrete appearance. The durability and porosity properties was tested for the review of application. The result of this study show that the effective content of silicate ranges 5 to 20% and the separate application of the first impregnant and the second impregnant is effective for the optimum performance. The adhesion in tension is slightly increased but the reinforcement of concrete substrate is slight. So, the concrete impregnant of this study is more desirable for the improvement of durability rather than the reinforcement.

• Proceedings of the Korea Concrete Institute Conference
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• 2006.05b
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• pp.313-316
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• 2006

The most serious cause of deterioration in the concrete structures is reinforcing corrosion due to the chloride attack and carbonation. Therefore, it is needed to protect durability and performance according to the appropriate materials and methods in the concrete structures. In general, several types of polymer and silicate are used as protecting deterioration agents of concrete structures, but these agents have many problems because of low durability and properties. The object of this study is to develop a preventing aging technology. The work involves the development of silicate type penetration reinforcing agent.

• Journal of the Korea institute for structural maintenance and inspection
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• v.18 no.5
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• pp.51-58
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• 2014

This paper presents a fire exposure test result to evaluate fire resistance capacity of retrofit method using FRP (Fiber Reinforced Polymer) in reinforcement concrete structure. Especially, this paper focused on near-surface-mounted retrofit method; FRP is mounted into the groove after making a groove in concrete. In the test, main parameters are retrofit method and materials for fire proofing. Spray type of perlite and board type of calcium silicate were considered as external fire proof on surface while particle of calcium silicate and polymer mortar as internal one in groove. By increasing the temperature of inside heating furnace, the transfer of temperature from surface of fire proofing material to groove in specimen was measured. As a result, fire proofing using the board of calcium silicate was more effective to delay the heat transfer from outside than spraying with perlite. It was found that the fire proofing could resist outside temperature of $820^{\circ}C$ at maximum to keep the temperature of epoxy below glass transit temperature (GTT).

• Proceedings of the Korea Concrete Institute Conference
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• 2006.05b
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• pp.321-324
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• 2006

The latest concrete has showed that the deterioration of durability has been increased by the damage from salt, carbonation, freezing & thawing and the others. Therefore, it is needed to protect durability and performance according to the appropriate materials and methods in the concrete structures. In general, several types of polymer and silicate are used as protecting deterioration agents of concrete structures, but these agents have many problems because of low durability and properties. In this study, It developed the deterioration restraining agent using polycondensed silicate and monomer that can block a deterioration cause such as CO2 gas, salt and water from the outside and enhance waterproofing ability by reinforcing the concrete surface when applying it to concrete structures. Also, it evaluated improving concrete performance using a deterioration restraining agent.

• Advances in concrete construction
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• v.6 no.4
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• pp.345-362
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• 2018

In this paper, mechanical and short-term durability properties of fly ash and slag based geopolymer concretes (FAGPC-SGPC) were investigated. The alkaline solution was prepared with a mixture of sodium silicate solution ($Na_2SiO_3$) and sodium hydroxide solution (NaOH) for geopolymer concretes. Ordinary Portland Cement (OPC) concrete was also produced for comparison. Main objective of the study was to examine the usability of geopolymer concretes instead of the ordinary Portland cement concrete for structural use. In addition to this, this study was aimed to make a contribution to standardization process of the geopolymer concretes in the construction industry. For this purpose; SGPC, FAGPC and OPC specimens were exposed to sulfuric acid ($H_2SO_4$), magnesium sulfate ($MgSO_4$) and sea water (NaCl) solutions with concentrations of 5%, 5% and 3.5%, respectively. Visual inspection and weight change of the specimens were evaluated in terms of durability aspects. For the mechanical aspects; compression, splitting tensile and flexural strength tests were conducted before and after the chemical attacks to investigate the residual mechanical strengths of geopolymer concretes under chemical attacks. Results indicated that SGPC (100% slag) is stronger and durable than the FAGPC due to more stable and strong cross-linked alumina-silicate polymer structure. In addition, FAGPC specimens (100% fly ash) showed better durability resistance than the OPC specimens. However, FAGPC specimens (100% fly ash) demonstrated lower mechanical performance as compared to OPC specimens due to low reactivity of fly ash particles, low amount of calcium and more porous structure. Among the chemical environments, sulfuric acid ($H_2SO_4$) was most dangerous environment for all concrete types.

• Journal of the Architectural Institute of Korea Structure & Construction
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• v.35 no.11
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• pp.137-146
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• 2019

Recently, the Near-Surface-Mounting method using Fiber reinforced polymer (FRP) has been developed and applied to the reinforcement of many concrete structural members. However, as a part of the fire resistance design, there is a lack of research related to fire insulation for the areas reinforced with FRP. In case of NSM reinforcement, there is a difference in the transferred temperature from the external surface to the groove corresponding to the location of the groove where the FRP is embedded, and the effect of this should be reflected in the fireproof insulation design. Therefore, in this study, after forming grooves for surface embedding in concrete blocks, fireproof insulation reinforcement was performed using Calcium Silicate (CS) fireproof board and an experiment to evaluate the temperature transfer was performed. By observing the temperature at these groove positions, the reduction of temperature transfer according to fireproof insulation detail was studied. As a result, when the NSM-FRP is properly fire-insulated using the CS-based fireproof board, the epoxy inside the groove does not reach its glass transition temperature until the external temperature reaches $800^{\circ}C$.