• 제목/요약/키워드: silicate

검색결과 1,848건 처리시간 0.027초

Chemical characteristics of mineral trioxide aggregate and its hydration reaction

  • Chang, Seok-Woo
    • Restorative Dentistry and Endodontics
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    • 제37권4호
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    • pp.188-193
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    • 2012
  • Mineral trioxide aggregate (MTA) was developed in early 1990s and has been successfully used for root perforation repair, root end filling, and one-visit apexification. MTA is composed mainly of tricalcium silicate and dicalcium silicate. When MTA is hydrated, calcium silicate hydrate (CSH) and calcium hydroxide is formed. Formed calcium hydroxide interacts with the phosphate ion in body fluid and form amorphous calcium phosphate (ACP) which finally transforms into calcium deficient hydroxyapatite (CDHA). These mineral precipitate were reported to form the MTA-dentin interfacial layer which enhances the sealing ability of MTA. Clinically, the use of zinc oxide euginol (ZOE) based materials may retard the setting of MTA. Also, the use of acids or contact with excessive blood should be avoided before complete set of MTA, because these conditions could adversely affect the hydration reaction of MTA. Further studies on the chemical nature of MTA hydration reaction are needed.

무기계난연제 첨가형 상용화블렌드/층상실리케이트 나노복합재료의 제조 및 난연특성에 관한 연구 (A Study on the Preparation and Flame Retardancy of Compatibilized Blend/Layered Silicate Nanocomposites with Inorganic Flame Retardant)

  • 강영구;송종혁
    • 한국안전학회지
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    • 제21권1호
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    • pp.79-85
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    • 2006
  • Olefinic compatibilized blend(R-PP/R-PE)/layered silicate composites have been prepared by melt intercalation technique directed from $Na^{+}$ montmorillonite(MMT) or organophilic montmorillonites while using magnesium hydroxide as flame retardant. Morphology and flammability properties were characterized by X-ray diffraction(XRD), transmission electron microscopy(TEM), scanning electron microscopy(SEM), thermogravimetry analysis(TGA), limiting oxygen index(LOI), UL94 test. It is found that the compatibilized blend/layered silicate(Cloisite 20A) nanocomposites have a mixed immiscible-intercalated structure and there is better intercalation when a compatibilizer is combined with the polymer and layered silicate to be melt blended. A very large increase in the LOI value was observed with hybrid filler addition and further enhancement in thermal stability and compatibility of blend was obtained for the compatibilized blend containing small amount of layered silicate.

Synthesis of Ga-silicate and Its Catalytic Performance for NO Removal under the Presence of Water

  • Misook Kang;Yoon, Yong-Soo;Um, Myeong-Heon
    • Journal of Korean Society for Atmospheric Environment
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    • 제15권E호
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    • pp.1-8
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    • 1999
  • Catalytic performance for NOx removal by Ga-incorporated silicates(Ga-silicate; Gallosilicate) with MFI type synthesized by the rapid crystallization method was reported in this study. NOx removal was investigated under the condition of O2 excess(10%), with various hydrocarbons of low concentrations. Effect of H2O(2%) addition was also considered. The result showd that the conversion from NOx to N2 was enhanced on the Ga-silicate compared with the Al-silicate. Furthermore, the performance for NOx conversion on the Ga-silicate increased with addition of water.

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침투성 함침제에 따른 콘크리트 표층부의 개질특성 (Surface Layer Change of Concrete with Concrete Impregnant)

  • 송훈;신현욱;추용식;이종규
    • 한국건축시공학회:학술대회논문집
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    • 한국건축시공학회 2013년도 추계 학술논문 발표대회
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    • pp.200-201
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    • 2013
  • This study is interested in manufacturing the concrete surface impregnants including tetra ethyl ortho silicate, alkali silicate for the repair of the exposed concrete and the color concrete requiring the advanced function in view of the concrete appearance. The surface layer change and porosity properties was tested for the review of application. The result of this study show that the effective silicate are tetra ethyl ortho silicate and alkali silicate t. The adhesion in tension is slightly increased but the reinforcement of concrete substrate is slight. So, the concrete impregnant of this study is more desirable for the improvement of durability rather than the reinforcement.

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Effect of Amino Silane Coupling Agent on the AC Electrical Breakdown Phenomena of Epoxy/Layered Silicate Nanocomposite in Needle-plate Electrodes

  • Park, Jae-Jun
    • Transactions on Electrical and Electronic Materials
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    • 제13권3호
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    • pp.149-152
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    • 2012
  • The effects of amino silane coupling agent on the AC electrical treeing and breakdown behaviors in an epoxy/layered silicate (1 wt%) were examined in needle-plate electrode geometry. A layered silicate was exfoliated in an epoxy base resin by using our AC electric field apparatus. To measure the tree initiation and propagation and the breakdown rate, an alternating current (AC) of 10 kV (60 Hz) was applied to the specimen in needle-plate electrode arrangement with a $30^{\circ}C$ insulating oil bath. In the epoxy/amino silane system, the tree initiation time was 11.5 times higher and the breakdown time was 17.9 times higher than those of the neat epoxy resin. The tree initiation time in the epoxy/layered silicate (1 wt%) system with the amino silane was 2.0 times higher, and the breakdown time was 1.5 times higher than those of the epoxy/layered silicate (1 wt%) system.

방화피복재 개발을 위한 용해성 규산염의 수화특성에 관한 연구 (A Study of Hydration Characteristics on Soluble Silicate to Develop Fire Protective Coating)

  • 김정훈;이내우
    • 한국안전학회지
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    • 제11권1호
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    • pp.90-98
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    • 1996
  • In order to investigate the effects on intumescence to fire protective coatings, the characteristics of solubility, hygroscopic nature and X-ray diffration results on soluble silicate were determined. Solubility is depended on the mutual action of each silicate. In the result of hygroscopic characteristics by water absorption under several kinds of relative humidity, lithium silicate is more stable than sodium and potassium silicate over moistures. Eventhough free water is evaporated over $100^{\circ}C$ , physically adsorption water and ionic water are eliminated about $200^{\circ}C$, but evolution of structural water is expected to be emitted between 400~$600^{\circ}C$ range. Those are considered to be contributed intumescence on soluble silicate.

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ALD 방법으로 증착된 Hf-silicate 박막의 열처리온도에 따른 전기적 특성 (Electrical properties of hafnium silicate deposited by atomic layer deposition as a function of annealing temperature)

  • 서영선;김남훈;노용한
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2007년도 추계학술대회 논문집
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    • pp.107-108
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    • 2007
  • In order to investigate the electrical properties of Hf-silicate as a function of annealing temperature, Hf-silicate deposited by atomic layer deposition (ALD) was studied. After Hf-silicate film deposition, annealing was proceeded at $500^{\circ}C\;and\;700^{\circ}C$. The hysteresis of C-V curves and trapping charge densities were decreased after annealing process. As annealing temperature became higher from $500^{\circ}C\;to\;700^{\circ}C$, the capacitance equivalent thickness (CET) was increased from 1.66 nm to 1.76 nm and the leakage current at -1 V was decreased from $1.70{\times}10^{-4}\;to\;5.68{\times}10^{-5}\;A/cm^2$.

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합성규산 알루미늄의 최적합성조건 (Optimal Synthesis Conditions of Synthetic Aluminum Silicate)

  • 신화우;서민재;정동훈
    • 약학회지
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    • 제47권1호
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    • pp.5-9
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    • 2003
  • Synthetic aluminum silicate was prepared by reacting aluminum sulfate solution with Sodium silicate solution in this study. The optimum synthesis conditions based on the yield of the product were established by applying Box-Wilson experimental design. The results were found to be as follows; Reactant temperature : 50∼72$^{\circ}C$, Concentration of two reactants : 10∼17.6%, Mole ratio of two reactants, [Sod. silicate]/[Al. sulfate) : 4.6∼5.0, Temperature of washing water : 25∼4$0^{\circ}C$, and Drying temperature of product : 50∼$65^{\circ}C$. The physical and chemical properties of synthetic aluminum silicate as medicine were investigated by means of chemical analysis, adsorption test and acid consuming capacity measurements.

논토양에서 규산질비료 시용이 토양 환경에 미치는 영향 (Assessment of Silicate Fetilizers Application Affecting Soil Properties in Paddy Field)

  • 주진호;이승빈
    • 한국토양비료학회지
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    • 제44권6호
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    • pp.1016-1022
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    • 2011
  • 본 연구는 논 토양에서 규산질 비료의 성상이 다른 두 종의 규산질 비료의 토양 시비를 통한 토양의 화학적 특성 변화와 벼의 화학적 영양 성분을 평가하고자 수행하였다. 강원도 춘천시 소재 논 토양에서 두 종 (슬래그를 이용한 입상 규산질 비료와 수용성 입상 규산질 비료)의 규산 처리 수준에 따른 토양환경 변화를 보기 위해 무처리와 관행시비, 처리 기준의 0, 1, 2, 4배 처리 후 토양 화학적 변화를 고찰하였다. 슬래그를 이용한 규산질 비료의 처리 시 토양 pH는 시험 전 토양 pH에 비하여 상승하였으나 수용성 규산염을 원료로 한 규산질 비료의 처리 시에는 pH의 변화가 나타나지 않았는데 이는 수용성 규산염의 처리 양이 적고 가수분해율이 적기 때문인 것으로 판단된다. 슬래그를 이용한 규산질 비료를 처리한 구의 토양 유효규산 함량은 15일과 35일까지는 슬래그를 이용한 모든 규산질 비료 처리 구에서 증가하였다. 하지만 처리 60일 후부터는 유효규산 함량이 감소하는 것으로 나타났으나 수용성 규산염을 원료로 한 규산질 비료의 경우에는 토양 유효규산 함량의 증가가 대조구와 비교하여 볼 때 매우 적게 증가한 것으로 나타났다. 슬래그를 이용한 규산질 비료 처리구에서는 처리량에 관계없이 무처리 구에 비해 치환성 칼슘과 유효 인산 함량이 증가하는 것으로 나타났으나 최고 수준 (4배)의 처리구에서의 유효 인산 함량은 비례적으로 증가하지는 않았다. 슬래그를 이용한 규산질 비료 처리구에서의 볏짚의 규산 함량은 무처리구와 관행 처리구에 비해 모두 증가하는 것으로 나타났다. 즉, 규산질 비료를 처리함에 따라 규질비 ($SiO_2$/N)가 증가하였다. 관행 처리구와 슬래그를 이용한 규산질 비료 100% 처리시의 규질비는 각각 8.4와 11.5로 나타났다. 본 실험의 연구 결과를 통하여 슬래그를 이용한 규산질 비료의 토양시비는 토양의 화학적 성질 개선 및 수도 생육을 위해 바람직하나 수용성 규산질 비료의 경우에는 엽면 시비를 통한 액상 분무 등을 통하여 시비를 하는 것이 바람직하다고 판단된다.

한국잔디 재배에 규산질 비료 시비가 생육과 질소이용효율에 미치는 영향 (Effect of Growth and Nitrogen Use Efficiency by Application of Mixed Silicate and Nitrogen Fertilizer on Zoysiagrass Cultivation)

  • 한정지;이광수;박용배;배은지
    • Weed & Turfgrass Science
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    • 제3권2호
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    • pp.137-142
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    • 2014
  • 본 연구는 규산질 비료와 질소 비료 혼용이 한국잔디의 생육과 질소비료 효율에 미치는 영향을 알아보기 위해 수행하였다. 한국잔디의 초장, 지상부, 포복경과 지하부의 생체중과 건물중, 지상부 개체수, 포복경 길이는 규산질 비료 400 kg/10a와 질소비료 24 kg/10a을 혼합시비 하였을 때 질소비료의 24 kg/10a 단용처리구보다 증가하였고, 규산질 비료와 질소비료 18 kg/10a은 질소비료의 24 kg/10a 단용 처리구와 유의성이 없었다. 규산질 비료와 질소비료를 혼합하여 시비했을 경우 질소비료 약 25-30% 절감효과가 있는 것으로 판단되었으며, 토양 내 유효 규산과 유기물의 함량은 규산질 비료 시비를 하지 않은 것보다 시비를 하였을 때 더 높게 나타나 규산질 비료가 한국잔디의 생장과 밀도를 높였으며 토양의 화학적 특성에 중요한 요소로 작용하였다.