• Transactions of the Korean Society of Mechanical Engineers A
• /
• v.23 no.11 s.170
• /
• pp.2014-2021
• /
• 1999

The present investigation is concerned with the degradation characteristics of cast stainless steel(CF8M), exposed to the $\sigma$-phase degradation at $700^{\circ}C$. In the present paper, the degradation of CF8 M at $700^{\circ}C$ is evaluated by a non-destructive test, DL-EPR(double loop electrochemical potentiokinetic reactivation). The surface of specimens is observed by using scanning electron microscopy after DL-EPR test. Also. chromium contents of matrix, grain boundary and ferrite phase are analyzed by electron probe X-ray micro analyzer. Through the experiments, the following results are obtained 1) The degree of sensitization(DOS) of CF8M aged up to 15hr at $700^{\circ}C$ is increased with acing time while that is decreased with aging time from 15hr to 150hr. 2) The impact energy decreases with increase of $\sigma$-phase while DOS increases with $\sigma$-phase until aging time reaches to 15hr. After the aging time. 15hr, the $\sigma$-phase and the rate of impact energy with respect to aging time decreases. Therefore the degradation behavior of the CF8M can be evaluated by comparing SEM micrographs and the value of DOS.

• Proceedings of the KWS Conference
• /
• 2003.11a
• /
• pp.216-218
• /
• 2003

Most of ferrous b.c.c weld materials may experience martensitic transformation during rapid cooling after welding. And it is well known that volume expansion due to phase transformation could influence in the case of welding of high tensile strength steels on the relaxation of welding residual stress. To apply this effect practically, it is a prerequisite to establish a numerical model which is able to estimate the effect of phase transformation on residual stress relaxation quantitatively. In this study, we investigated the effect of phase transformation on the relaxation of welding residual stress through experiment. And three-dimensional thermal elastic-plastic FEM analysis is conducted to compare the effect of phase transformation on the relaxation of welding residual stress in high strength steels(POSTEN60, POSTEN80) with analytical results which is not considering the effect of phase transformation on residual stress relaxation. According to the results, the extents of welding residual stress relaxation due to phase transformation in the case of welding of POSTEN60, POSTEN80 are 0.85 $\sigma$/$\sigma$$\sub$Y0/, 0.75$\sigma$/$\sigma$$\sub$Y0/, respectively.

• Proceedings of the Korean Society for Quality Management Conference
• /
• 2006.11a
• /
• pp.157-163
• /
• 2006

There are big differences in six sigma applications between manufacturing processes and transactional processes. This paper analyzes the differences between two areas by examining 18 six sigma case studies in Korean companies. To characterize six sigma cases, a step-by-step checklist is developed based on 12-step DMAIC methodology proposed by US six sigma academy. On the basis of those characterized data, the differences between two areas are analyzed. The most significant differences is that statistical tools are widely used in manufacturing processes, but qualitative tools are used in transactional processes during improvement phase.

• Journal of Ocean Engineering and Technology
• /
• v.23 no.3
• /
• pp.40-45
• /
• 2009

With the increase in the annealing temperature, the volume fraction of austenite phase increased and the volume fraction of ferrite phase decreased. In compliance with the addition of N, not only the volume fraction of austenite phase was increased but also the austenite structure was made larger. Volume fraction of ${\sigma}$ phase was increased by decreasing of the volume fraction of ferrite phase, with the increase in the aging time and in compliance with the addition of N. As increasing in volume fraction of ${\sigma}$ phase, tensile strength and hardness increased, while elongation and impact value decreased. Elongation slowly decreased and impact value rapidly decreased at the early stage of aging. By the added N, tensile strength, elongation, hardness and impact value was increased.

• Journal of Korean Ophthalmic Optics Society
• /
• v.6 no.2
• /
• pp.11-16
• /
• 2001

The polariscope to measure :he stress in lens was made up quarter-wave plate polarizer and we analyzed two components of light's wave $E_1$ and $E_2$ following the steps. It is clear that the principal-stress difference ${\sigma}_1-{\sigma}_2$ can be determined in 2-D model if fringe order N is measured each point in sample moreover. the optical axes of sample coincide with the principal-stress directions. The birefringence acted to a light wave and a phase retardation were in proportioned to the principal-stressed difference (${\sigma}_1-{\sigma}_2$) and the intensity of final light wave was proportioned to $sin^2({\Delta}/2)$, when ${\Delta}/2=n^{\pi}$ (n=0, 1, 2, ...) and the extinction occurs. As a experimental result, the extinction band shifted owing to a magnitude of lens' external stress.

• Journal of the Korean Society of Food Science and Nutrition
• /
• v.42 no.6
• /
• pp.933-940
• /
• 2013

In this study, methyl esters with different saturated fatty acids (SFA) were prepared by urea fractionation to make an oil-in-water emulsion. Emulsion characteristics (emulsion stability and oxidative stability) of the methyl ester emulsion were then studied at different percentages of methyl ester saturation (5, 28, 39, 50, and 72%, termed ${\Sigma}$SFA5, ${\Sigma}$SFA28, ${\Sigma}$SFA39, ${\Sigma}$SFA50, and ${\Sigma}$SFA72, respectively). The stability of emulsions (ES) with different SFA content was 46.0 (${\Sigma}$SFA5), 39.5 (${\Sigma}$SFA28), 32.7 (${\Sigma}$SFA39), 32.6 (${\Sigma}$SFA50), and 27.3 (${\Sigma}$SFA72). Results from Turbiscan showed that creaming or clarification, based on the backscattering intensity, was more pronounced with increases in the saturation degree of the emulsion. These results implied that the emulsions with lower saturation were more stable. During 30 days of storage, the lipid peroxide value increased for all emulsions, with the increase less pronounced with the increasing saturation of the emulsion; 1.880 (${\Sigma}$ SFA5), 1.267 (${\Sigma}$SFA28), 1.062 (${\Sigma}$SFA39), 0.342 (${\Sigma}$SFA50) and 0.153 (${\Sigma}$SFA72) mg $H_2O_2/mL$ emulsion. In addition, thiobarbituric acid reactive substances (TBARS) values were significantly lower in emulsions with high saturation (4.419 mg for ${\Sigma}$SFA50 and 4.226 mg for ${\Sigma}$SFA72) than emulsions with low saturation (6.229 mg for ${\Sigma}$SFA5, 6.801 mg for ${\Sigma}$SFA28 and 6.246 mg for ${\Sigma}$SFA39). In conclusion, the emulsions with a higher saturation degree of methyl esters showed lower emulsion stability but better oxidation stability.

• Journal of the Korean Society for Heat Treatment
• /
• v.26 no.6
• /
• pp.293-299
• /
• 2013

A specimen of weld metal was prepared by GTA welding with weld wire of super duplex stainless steel. Aging treatment was conducted for the sample at the temperature range of 700 to $900^{\circ}C$ for 5 to 300 minutes. The effect of volume fraction of ${\sigma}$-phase to intergranular corrosion of weld metal has been investigated and the results were derived as follows. The volume fraction of ${\sigma}$ phase tends to increase with an increase of aging temperature and time and intergranular corrosion of weld metal was increased by an increase of ${\sigma}$ phase. Degree of sensitization representing intergranular corrosion was found to tend to increase with an increase of aging time at 700 to $800^{\circ}C$, while it decreased by an increase of aging time at $900^{\circ}C$.

• Korean Journal of Materials Research
• /
• v.4 no.8
• /
• pp.847-854
• /
• 1994

An amorphous single phase and coexistent amorphous and hcp-Mg phases in Mg-Zn-Ce system were found to form in the composition ranges of 20 to 40% Zn, 0 to 10% Ce and 5 to 20% Zn, 0 to 5% Ce, respectively. A $Mg_{85}Zn_{12}Ce_{3}$ amorphous alloy containing nanoscale hcp-Mg particles was found to form either by melt spinning or by heat treatment of melt -spun ribbon. The particle size of the hcp-Mg phase can be controlled in the range of 4 to 20 nm. The mixed phase alloy prepared thus has a good bending ductility and exhibits high ultimate tensile strength($\sigma_{B}$) ranging from 670 to 930 MPa and fracture elongation($\varepsilon_{f}$) of 5.2 to 2.0%. The highest specific strength($\sigma_{B}$/density =$\sigma_{s}$)$3.6 \times 10^5N \cdot m/kg$. It should be noted that the highest values of flB, US and ？1 are considerably higher than those (690MPa,$2.5 \times 10^5N \cdot m/kg$and 2.5%) for amorphous Mg-Zn-Ce alloys. The increase of the mechanical strengths by the formation of the mixed phase structure is presumably due to a dispersion hardening of the hcp supersaturated solution which has the hardness higher than that of the amorphous phase with the same composition.

• Corrosion Science and Technology
• /
• v.5 no.6
• /
• pp.189-195
• /
• 2006

Effects of tungsten (W) on the precipitation kinetics of secondary phases and the associated resistance to pitting corrosion of 25%Cr duplex stainless steels were investigated through microstructural and electrochemical noise analyses. With the partial substitution of W for Mo in duplex stainless steel, the potential and current noises of the alloy were significantly decreased in chloride solution due to retardation of the ${\sigma}$ phase precipitation. The preferential precipitation of the $\chi$ phase in the W-containing alloy during the early period of aging contributed to retarding the precipitation of the $\sigma$ phase by depleting W and Mo along grain boundaries. In addition, the retardation of the nucleation and growth of the $\sigma$ phase in the W-containing alloy appears to be attributed to the inherently low diffusivity of W compared with that of Mo.

• Corrosion Science and Technology
• /
• v.20 no.6
• /
• pp.426-434
• /
• 2021

The effect of two different annealing temperatures on the level of the second phase precipitated in the microstructure and the corrosion behaviors of super austenitic stainless steel were examined. The sample annealed at a higher temperature had a significantly lower fraction of the sigma phase enriched with Cr and Mo elements, showing more stable passivity behavior during the potentiodynamic polarization measurement. However, after the welding process with Inconel-type welding material, severe corrosion damage along the interface between the base metal and the weld metal was observed regardless of the annealing temperature. This was closely associated with the precipitation of the fine sigma phase with a high Mo concentration in the unmixed zone (UMZ) during the welding process, leading to the local depletion of Mo concentrations around the sigma phase. On the other hand, the fraction of the newly precipitated fine sigma phase in the UMZ was greatly reduced by post-weld heat treatment (PWHT), and the corrosion resistance was greatly improved. Based on the results, it is proposed that the alloy composition of welding materials and PWHT conditions should be further optimized to ensure the superior corrosion resistance of welded super austenitic stainless steel.