• 한국분말재료학회지
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• 제12권4호
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• pp.239-248
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• 2005

1990년도 초반에 개발되어 나노분말의 제조 공정으로 집중적으로 연구되어온 화학기상응축공정은 고강도용 나노분말 소재이외에 기능성 자성재료로의 응용에 주로 이용되어 왔다. 최근에는 이러한 응용이외에 나노분말의 표면을 다양한 이종 소재로 응용하고자하는 나노캡슐(혹은 core/shell)화 제조 공정으로 진보되어 다양한 합금 시스템으로 발전하게 되었다. 특히 최근 Particles 2005, Surface Modification in Particle Technology 학회에서는 나노금속 혹은 세라믹 분말에 PMMA, PE등 polymer의 유기화합물의 코팅하여, DNA나 RNA를 부착하거나 추출해내는 나노캡슐화 공정 연구가 매우 활발하게 진행됨을 보여주고 있으며, 이들 나노 캡슐의 개발은 약물전달계(Drug delivery system), 온열치료용 및 MRI 조영제 등의 바이오재료로의 응용가능성이 크게 기대되어 이에 대한 연구들이 활발하게 진행될 것으로 예상된다.

• Macromolecular Research
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• 제15권4호
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• pp.385-391
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• 2007

Block copolymer micelles are generally formed via the self-assembly of amphiphilic block copolymers in an aqueous medium. The hydrophilic and hydrophobic blocks form shell and core micelles, respectively. The block copolymers of methoxy poly(ethylene glycol) (MPEG)-b-poly(2-diisopropylamino)ethyl methacrylate (PDPA) were synthesized via atom transfer radical polymerization, with the macro initiator synthesized by the coupling of 2-bromoisobutyryl bromide with MPEG in the presence of a triethyl amine base catalyst. The atom transfer radical polymerization of 2-diisopropylamino)ethyl methacrylate was performed in conjunction with an N,N,N',N",N"-pentamethyl-diethylenetriamine/copper bromide catalyst system, in DMF, at $70^{\circ}C$. The pH induced micellization/demicellization was studied using fluorescence, with a pyrene probe. Furthermore, the pH dependent micellization was confirmed using the microviscosity method, with a dipyme fluorescence probe. The pH dependant micelle size distribution was studied using dynamic light scattering. The characterization of the synthesized polymers was established using gel permeation chromatography and from the $^1H-nuclear$ magnetic resonance spectroscopy.

• 건축역사연구
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• 제9권3호
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• pp.51-69
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• 2000

This study tries to analyze the development of architectural technologies appeared in several tall buildings and large spatial structures from 1955 to 1999 in Korea. We suppose that these buildings represent the development of technology in Korean modern architecture. By the detailed analysis of these buildings, we can arrive at a conclusion as such; During the years 1955-1999, there existed a great changement in the eighties. We can find this fact very well in the domain of structural system and curtain wall system. In large spatial structures, the structural-system of shell and steel truss dome was replaced by that of space frame, space truss and cable truss with membrane. In tall building, the structural system of rigid frame and shear wall was replaced by tubular system, core and outrigger system. Korean architects introduced the aluminum curtain wall in the sixties, but its low technological level caused many problems in reality. Therefore, precast concrete curtain wall appeared from seventies as the main method for an outer wall in tall building. With the augmentation of height after 1980, PC curtain wall was replaced by the aluminum curtain wall of unit type and structural glass wall system. These systems help to stress the transparency in a tall building.

• Bulletin of the Korean Chemical Society
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• 제31권8호
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• pp.2265-2271
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• 2010

In this study, wormorm-like polymeric micelles were construted from poly(L-lactic acid)-b-poly(ethyelen glycol) (PLLA-b-PEG) block copolymers via worm-like (or cylindrical) self- assembly that consisted of a relatively long PLLA block ($M_n$ 7K Daltons) at the core and a relatively short PEG block ($M_n$ 2K Daltons) as the shell. Several cancer-targeting moieties (such as folate, cobalamin, and cyclic arginine-glycine-aspartic (RGD) peptide) were chemically coupled with the succinylated or maleimided PEG block of PLLA-b-PEG to act as a cancer cell-specific targeting ligand for breast cancer. The worm-like micelles with muplite cancer cell-specific ligands proved to be successful in recognizing different breast cancer cells at once. This has the potential to aid in cancer-specific drug delivery and to be used as an effective treatment for breast cancer.

• 한국세라믹학회지
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• 제47권2호
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• pp.189-194
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• 2010

Compared with organic fluorophores, semiconductor quantum dots (QDs) have the better properties such as photostability, narrow emission spectra coupled to tunable photoluminescent emissions and exceptional resistance to both photo bleaching and chemical degradation. In this work, CdSe/ZnS QDs nanobeads were prepared by the incorporation of CdSe/ZnS QDs with mesoporous silica to use as the optical probe for detecting toxic and bio- materials with high sensitivity, CdSe/ZnS core/shell QDs were synthesized from the precursors such as CdO and zinc stearate with the lower toxicity than pyrotic precursors. The QD-nanobeads were characterized by transmission electron microscopy, FL microscopy, UV-Vis and PL spectroscopy, respectively.

• 천문학회보
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• 제37권1호
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• pp.73.1-73.1
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• 2012

We present the results of dust scattering simulations carried out for the Orion Eridanus Superbubble region by comparing them with observations made in the far-ultraviolet. The albedo and the phase function asymmetry factor (g-factor) of interstellar grains were estimated as well as the distance and thickness of the dust layers. The results are: 0.39-0.45 for the albedo and 0.25-0.65 for the g-factor, in good agreement with previous determinations and theoretical predictions. The distance of the assumed single dust layer, modeled for the Orion Molecular Cloud Complex, was estimated to be -110 pc and the thickness ranged from -130 at the core to -50 pc at the boundary for the region of the present interest, implying that the dust cloud is located in front of the Superbubble. The simulation result also indicates that a thin (-10 pc) dust shell surrounds the inner X-ray cavities of hot gas at a distance of -70-90 pc.

• Journal of the Korean Wood Science and Technology
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• 제42권5호
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• pp.499-509
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• 2014

Wood filler is a porous and anisotropic material having different size, shape, and aspect ratio. The use of wood fillers such as wood particle, wood flour, and wood pulp in wood plastic composites (WPCs) are growing rapidly because these wood fillers give improved strength and stiffness to WPCs. However, the wood fillers have originally poor compatibility with plastic matrix affecting the mechanical properties of WPCs. Therefore, to improve compatibility between wood and plastic, numbers of physical and chemical treatments were investigated. While the various treatments led to improved performances in WPC industries using petroleum-based plastics, full biodegradation is still issues due to increased environmental concerns. Hence, bio-based plastics such as polylactide and polyhydroxybutyrate having biodegradable characteristics are being applied to WPCs, but relatively expensive prices of existing bio-based plastics prevent further uses. As conventional processing methods, extrusion, injection, and compression moldings have been used in WPC industries, but to apply WPCs to engineered or structural places, new processing methods should be developed. As one system, co-extrusion technique was introduced to WPCs and the co-extruded WPCs having core-shell structures make the extended applications of WPCs possible.

• 한국세라믹학회지
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• 제40권7호
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• pp.644-651
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• 2003

첨가물의 형태가 X7R용 MLCC 유전 원료의 전기적 특성 및 미세구조에 미치는 영향을 평가하였다. Glass frit 및 산화물 형태로 제조된 첨가물을 분말 공정 조건을 달리하여 동일한 주조성에 첨가하였다. 미세구조 및 유전특성을 측정한 결과, glass 층에 dopant의 농도 구배가 존재하는 조성이 유전 특성이 가장 우수하였다. 최적 조성을 MLCC로 제작하여 유전 특성을 측정하였으며, X7R 제반 조건을 만족하였다.

• 한국세라믹학회지
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• 제48권6호
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• pp.493-498
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• 2011

Optimal atomic configurations in a nanoparticle were predicted by genetic algorithm. A truncated octahedron with a fixed composition of 1 : 1 was investigated as a model system. A Python code for genetic algorithm linked with a molecular dynamics method was developed. Various operators were implemented to accelerate the optimization of atomic configuration for a given composition and a given morphology of a nanoparticle. The combination of random mix as a crossover operator and total_inversion as a mutation operator showed the most stable structure within the shortest calculation time. Pt-Ag core-shell structure was predicted as the most stable structure for a nanoparticle of approximately 4 nm in diameter. The calculation results in this study led to successful prediction of the atomic configuration of nanoparticle, the size of which is comparable to that of practical nanoparticls for the application to the nanocatalyst.

• Smart Structures and Systems
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• 제13권4호
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• pp.501-515
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• 2014

This paper presents a linear computational homogenization framework to evaluate the effective (or generalized) electromechanical coupling coefficient (EMCC) of adaptive structures with piezoelectric structural fiber (PSF) composite elements. The PSF consists of a silicon carbide (SiC) or carbon core fiber as reinforcement to a fragile piezo-ceramic shell. For the micro-scale analysis, a micromechanics model based on the variational asymptotic method for unit cell homogenization (VAMUCH) is used to evaluate the overall electromechanical properties of the PSF composites. At the macro-scale, a finite element (FE) analysis with the commercial FE code ABAQUS is performed to evaluate the effective EMCC for structures with the PSF composite patches. The EMCC is postprocessed from free-vibrations analysis under short-circuit (SC) and open-circuit (OC) electrodes of the patches. This linear two-scale computational framework may be useful for the optimal design of active structure multi-functional composites which can be used for multi-functional applications such as structural health monitoring, power harvest, vibration sensing and control, damping, and shape control through anisotropic actuation.