• Advances in environmental research
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• 제4권2호
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• pp.69-81
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• 2015

A new magnetite-silica core/shell nanocomposite ($Fe_3O4@nSiO_2@mSiO_2$) was synthesized and functionalized with trimethylchlorosilane (TMCS). The prepared nanocomposite was used for the removal of diesel oil from aqueous media. The characterization of magnetite-silica nanocomposite was studied by X-ray diffraction (XRD), Fourier transform infrared (FTIR), transmission electron microscopy (TEM), surface area measurement, and vibrating sample magnetization (VSM). Results have shown that the desired structure was obtained and surface modification was successfully carried out. FTIR analysis has confirmed the presence of TMCS on the surface of magnetite silica nanocomposites. The low- angle XRD pattern of nanocomposites indicated the mesoscopic structure of silica shell. Furthermore, TEM results have shown the core/shell structure with porous silica shell. Adsorption kinetic studies indicated that the nanocomposite was able to remove 80% of the oil contaminant during 2 h and fit well with the pseudo-second order model. Equilibrium studies at room temperature showed that the experimental data fitted well with Freundlich isotherm. The magnetic property of nanocomposite facilitated the separation of solid phase from aqueous solution.

• 한국구조물진단유지관리공학회 논문집
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• 제6권3호
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• pp.97-102
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• 2002

Two dimensional Analysis has been applied to most of tunnel lining design in these days. Two dimensional analysis uses beam or curved beam element for finite element method. But because the behaviors of tunnel concrete lining structure is near to shell, it is required to model the tunnel lining as shell structure for safety design of tunnel lining structure. In this paper, two dimensional analysis by beam element and the three dimensional analysis by shell element of tunnel concrete lining are studied, in which 3 type of tunnel lining and lateral pressure factors are considered. As results of the study, three dimensional analyses of the behavior of tunnel concrete lining structure considering lateral pressure factor shows that the moment of three dimensional analysis is greater than those of two dimensional analysis. The results shows that three dimensional analysis is necessary for safety design of tunnel lining.

• 수산해양기술연구
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• 제32권2호
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• pp.164-176
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• 1996

The main intention of this paper is to develop and compare the algorithm based on finite element procedures for nonlinear transient dynamic analysis which has combined effects of material and geometric nonlinearities. Incremental equilibrium equations based on the principle of virtual work are derived by the finite element approach. For the elasto - plastic large deformation analysis of shells and the determination of the displacement-time configuration under time-varying loads, the explicit, implicit and combined explicit-implicit time integration algorithm is adopted. In the time structure is selected and the results are compared with each others. Isoparametric 8-noded quadrilateral curved elements are used for shell structure in the analysis and for geometrically nonlinear elastic behaviour, a total Lagrangian coordinate system was adopted. On the other hands, material nonlinearity is based on elasto-plastic models with Von-Mises yield criteria. Thus, the combined explicit-implicit time integration algorithm is benefit in general case of shell structure, which is the result of this paper.

• 천문학회보
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• 제39권1호
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• pp.60.2-60.2
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• 2014

The dust cloud around ${\lambda}$-Orionis is seen to be circular symmetric with the large angular extent (${\sim}8^{\circ}$). However, whether the three dimensional structure of the cloud is shell or torus ring is not yet fully resolved. We studied the structure of the dust cloud using a three-dimensional Monte-Carlo simulation code, MoCafe (Monte Carlo radiative transfer). The dust density structure of the cloud was inferred based on the star-count method. We assumed that the cloud is a spherical shell or a torus ring and calculated the radial profiles of scattered light originating from a central OB association. Comparison of the results with the S2/68 ultraviolet observations indicates that the cloud is a spherical shell. We also compared the Av map around ${\lambda}$-Orionis with the optical depth obtained based on the star-count.

• 한국응용과학기술학회지
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• 제26권2호
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• pp.199-204
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• 2009

Silicone dioxide absorbed polyoxyethylene alkylether sulfate (EU-S133D) surfactant was prepared. Core-shell polymers of inorganic/organic pair, which have both core and shell component, were synthesized by sequential emulsion polymerization using Acrylate as a shell monomer and potassium persulfate (KPS) as an initiator. We found that when Acrylate core prepared by adding 2.0 wt% EU-S133D, silicone dioxide/Acrylate core-shell polymerization was carried out on the surface of silicone dioxide particle without forming the new silicone dioxide particle during acrylate shell polymerization in the inorganic/organic core-shell polymer preparation. The structure of core-shell polymer were investigated by measuring to the thermal decomposition of polymer composite using thermogravimetric analyzer and morphology of latex by scanning electron microscope(SEM).

• 한국응용과학기술학회지
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• 제27권1호
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• pp.56-60
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• 2010

Titanium dioxide particles are used as photocatalysts, sensors, adsorbents and catalyst. Core-shell polymers of inorganic/organic pair, which have both core and shell component, were synthesized by sequential emulsion polymerization using Acrylate as a shell monomer and potassium persulfate (KPS) as an initiator. We found that when Acrylate core prepared by adding 0.5~2.0 wt% EU-S133D, Titanium dioxide / Acrylate core-shell polymerization was carried out on the surface of Titanium dioxide particle without forming the new Titanium dioxide particle during acrylate shell polymerized in the inorganic/organic core-shell polymer preparation. The structure of core-shell polymer were investigated by measuring to the thermal decomposition of polymer composite using thermogravimetric analyzer(TGA) and morphology of latex by scanning electron microscope(SEM).

• 한국방사성폐기물학회:학술대회논문집
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• 한국방사성폐기물학회 2009년도 학술논문요약집
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• pp.84-85
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• 2009

New approaches for detecting, preventing and remedying environmental damage are important for protection of the environment. Procedures must be developed and implemented to reduce the amount of waste produced in chemical processes, to detect the presence and/or concentration of contaminants and decontaminate fouled environments. Contamination can be classified into three general types: airborne, surface and structural. The most dangerous type is airborne contamination, because of the opportunity for inhalation and ingestion. The second most dangerous type is surface contamination. Surface contamination can be transferred to workers by casual contact and if disturbed can easily be made airborne. The decontamination of the surface in the nuclear facilities has been widely studied with particular emphasis on small and large surfaces. The amount of wastes being produced during decommissioning of nuclear facilities is much higher than the total wastes cumulated during operation. And, the process of decommissioning has a strong possibility of personal's exposure and emission to environment of the radioactive contaminants, requiring through monitoring and estimation of radiation and radioactivity. So, it is important to monitor the radioactive contamination level of the nuclear facilities for the determination of the decontamination method, the establishment of the decommissioning planning, and the worker's safety. But it is very difficult to measure the surface contamination of the floor and wall in the highly contaminated facilities. In this study, the poly(styrene-ethyl acrylate) [poly(St-EA)] core-shell composite polymer for measurement of the radioactive contamination was synthesized by the method of emulsion polymerization. The morphology of the poly(St-EA) composite emulsion particle was core-shell structure, with polystyrene (PS)as the core and poly(ethyl acrylate) (PEA) as the shell. Core-shell polymers of styrene (St)/ethyl acrylate (EA) pair were prepared by sequential emulsion polymerization in the presence of sodium dodecyl sulfate (SOS) as an emulsifier using ammonium persulfate (APS) as an initiator. The polymer was made by impregnating organic scintillators, 2,5-diphenyloxazole (PPO) and 1,4-bis[5-phenyl-2-oxazol]benzene (POPOP). Related tests and analysis confirmed the success in synthesis of composite polymer. The products are characterized by IT-IR spectroscopy, TGA that were used, respectively, to show the structure, the thermal stability of the prepared polymer. Two-phase particles with a core-shell structure were obtained in experiments where the estimated glass transition temperature and the morphologies of emulsion particles. Radiation pollution level the detection about under using examined the beta rays. The morphology of the poly(St-EA) composite polymer synthesized by the method of emulsion polymerization was a core-shell structure, as shown in Fig. 1. Core-shell materials consist of a core structural domain covered by a shell domain. Clearly, the entire surface of PS core was covered by PEA. The inner region was a PS core and the outer region was a PEA shell. The particle size distribution showed similar in the range 350-360 nm.

• 한국공간구조학회논문집
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• 제8권2호
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• pp.105-113
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• 2008

쉘형 구조물은 외력에 대해 효과적으로 저항할 수 있어, 두께를 얇게하면서 대공간 구조물을 만들 수 있는 장점이 있다. 이러한 장점은 구조형태에 크게 의존한다. 그러므로 많은 설계자들은 최적 형태를 설계에 반영하고자 하지만, 이는 간단치 않다. 지금까지 보다 최적의 형태를 얻기 위한 많은 기법들이 발표되어 왔고, 이들은 각각 장단점을 나타낸다. 본 논문에서는 최적의 곡면을 얻기 위해 기하학적 비선형을 고려한 유한요소법을 이용한 비교적 간단한 방법을 제안한다. 이러한 방법을 이용하여 다양한 쉘형 곡면에 적용하여 최적곡면을 얻고, 이를 비교한다.

• Structural Engineering and Mechanics
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• 제68권6호
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• pp.721-733
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• 2018

The modal frequency responses of functionally graded (FG) sandwich doubly curved shell panels are investigated using a higher-order finite element formulation. The system of equations of the panel structure derived using Hamilton's principle for the evaluation of natural frequencies. The present shell panel model is discretised using the isoparametric Lagrangian element (nine nodes and nine degrees of freedom per node). An in-house MATLAB code is prepared using higher-order kinematics in association with the finite element scheme for the calculation of modal values. The stability of the opted numerical vibration frequency solutions for the various shell geometries i.e., single and doubly curved FG sandwich structure are proven via the convergence test. Further, close conformance of the finite element frequency solutions for the FG sandwich structures is found when compared with the published theoretical predictions (numerical, analytical and 3D elasticity solutions). Subsequently, appropriate numerical examples are solved pertaining to various design factors (curvature ratio, core-face thickness ratio, aspect ratio, support conditions, power-law index and sandwich symmetry type) those have the significant influence on the free vibration modal data of the FG sandwich curved structure.

• 대한기계학회:학술대회논문집
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• 대한기계학회 2005년도 창립60주년 기념 추계 학술대회
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• pp.177.2-177.2
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• 2005