• Bulletin of the Korean Chemical Society
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• 제32권8호
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• pp.2683-2688
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• 2011

Silica-manganese oxides with a core-shell structure were synthesized via precipitation of manganese oxides on the $SiO_2$ core while varying the concentration of a precipitation agent. Elemental analysis, crystalline property investigation, and morphology observations using low- and high-resolution electron microscopes were applied to the synthesized silica-manganese oxides with the core-shell structure. As the concentration of the precipitating agent increased, the manganese oxide shells around the $SiO_2$ core sequentially appeared as $Mn_3O_4$ particles, $Mn_2O_3+Mn_3O_4$ thin layers, and ${\alpha}-MnO_2$ urchin-like phases. The prepared samples were assembled as electrodes in a supercapacitor with 0.1 M $Na_2SO_4$ electrolyte, and their electrochemical properties were examined using cyclic voltammetry and charge-discharge cycling. The maximum specific capacitance obtained was 197 F $g^{-1}$ for the $SiO_2-MnO_2$ electrode due to the higher electronic conductivity of the $MnO_2$ shell compared to those of the $Mn_2O_3$ and $Mn_3O_4$ phases.

• 한국소음진동공학회:학술대회논문집
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• 한국소음진동공학회 2012년도 추계학술대회 논문집
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• pp.258-264
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• 2012

The overall aim of this paper is to determine coupling loss factor of welding point between shell and cylinder using loss factor and structural loss factor. For this purpose, two kinds of loss factor were adopted. One is loss factor of each sub structure, another is structural loss factor based on the complex welded or assembled structure. Using these two parameters, it is possible to derive the coupling loss factor which represents characteristic condition of SEA theory. Coupling loss factor of conjunction in complex structure was expressed as power balance equation. The derived equation for a coupling loss factor has been simplified on the assumption of one way (uni-directional) power flow between multi-sub structures. Using these conditions, it is possible to find the equation of coupling loss factor expressed as above two loss factors. To check the effectiveness of above equation, this paper used two-stage application. The first approach was application between simple cylinder and shell. The next was adopted rotary compressor. Rotary compressor has three main conjunctions between shell and internal vibration part. This equation was applied to find out the optimum welding point with respect to reduce the noise propagation. It shows the effective tool to evaluate the coupling loss factor in complex structure.

• 한국정밀공학회지
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• 제23권8호
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• pp.127-136
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• 2006

Metallic sandwich plates with inner dimpled shell subject to 3-point bending have been analyzed and then optimized for minimum weight. Inner dimpled shells can be easily fabricated by press or roll with high precision and bonded with same material skin sheets by resistance welding or adhesive bonding. Metallic sandwich plates with inner dimpled shell structure can be optimally designed for minimum weight subject to prescribed combination of bending and transverse shear loads. Fundamental findings for lightweight design are presented through constrained optimization. Failure responses of sandwich plates are predicted and formulated with an assumption of narrow sandwich beam theory. Failure is attributed to four kinds of mechanisms: face yielding, face buckling, dimple buckling and dimple collapse. Optimized shape of inner dimpled shell structure is a hemispherical shell to minimize weight without failure. It is demonstrated that bending stiffness of sandwich plate is 2 or 3 times larger than solid plates with the same strength. Failure mode boundaries and iso-strength lines dependent upon the geometry and yield strain of the material are plotted with respect to geometric parameters on the failure map. Because optimal parameters of maximum strength for given material weight can be selected from the map, analytic solutions for maximum strength are expressed as a function of only material property and proposed strength. These optimal parameters match well with numerical optimal parameters.

• 한국응용과학기술학회지
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• 제19권4호
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• pp.265-272
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• 2002

$CaCO_{3}$ absorbed sodium lauryl sulfate (SLS) surfactant was prepared, Core-shell polymers of inorganic/organic pair, which have both core and shell component, were synthesized by sequential emulsion polymerization using styrene(St) as a shell monomer and potasium persulfate (KPS) as an initiator, We found that when $CaCO_{3}$; core prepared by adding 2,0 wt% SLS, $CaCO_{3}$ core/PSt shell polymerization was carried out on the surface of $CaCO_{3}$ particle without forming the new PSt particle during St shell polymerization in the inorganic/organic core-shell polymer preparation, The structure of core-shell polymer were investigated by measuring the degree of decomposition of $CaCO_{3}$ using HCl solution, thermal decomposition of polymer composite using thermogravimetric analyzer and morphology by scanning electron microscope.

• 천문학회보
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• 제35권2호
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• pp.73.1-73.1
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• 2010

Using the spectroscopic data secured with the Hamilton Echelle Spectrograph attached to a 3-m telescope at the Lick Observatory, we derived the expansion velocities from various line profiles in the 3600 $\AA$ to 10,000 $\AA$ based on the full width at half maximum and double peak of the high dispersion line profiles. The symmetrical shapes of the permitted line profiles indicate that the permitted line zone is symmetrical e.g., a spherical shell or bipolar + torus structures, which might be evidence of relatively recent ejection from the central star. Most other stronger forbidden lines might be coming from a main shell which appears as a bilateral symmetrical morphology, seen in HST and other ground-based telescopic images. The overall expansion velocities of this main shell structure that are responsible for most lines, seem to show the Hubble type expansion, i.e., accelerating shell. The faster expansion velocities of the permitted OII, NII, NIII and perhaps CII lines that do not suit to the Hubble type expansion, imply the existence of a somewhat smaller inner shell inside the outer main shell. We conclude that the nebular shell consists of a swiftly expanding inner shell and an outer normal shell excited by a central star of about 55,000K. The former compact zone appears to be responsible for the permitted C, N, and O lines while the latter extended shell appears to be responsible for H, He, and forbidden lines. We present some evidence that NGC 6833 be a member of the Galactic halo.

• 한국정밀공학회:학술대회논문집
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• 한국정밀공학회 1997년도 추계학술대회 논문집
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• pp.286-289
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• 1997

In the design of structure the forces acting on the structure are important parameter for noise and vibration control. However, in the complex structure, the forces at the injection pomt on the structure cannot be measured directly. Thus it is necessary to find out indirect force evaluation method. In thls paper forces have been measured with in-situ vibration responses and system information. Three existing techniques of indirect force measurement, viz. direct inverse, principal component analysis and regularization have been compared. It has been shown that multi-vibration responses are essential for the precise estimation of the forces. To satisfy those cond~tions, Rotary compressor is adopted as test sample, because it is very difficult to measurc the injection forces from internal excitat~on to shell. It has also been obtained that relatively higher force IS transmitted through three welding paths to the compressor shell. It shows a good agreement between direct and indirect force evaluation wlth curvature shell and plate and is investigated the possibility of force evaluation of rotary compressor as a complex structure.

• 한국정밀공학회:학술대회논문집
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• 한국정밀공학회 1997년도 추계학술대회 논문집
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• pp.564-567
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• 1997

In the design of structure the forces acting on the structure are important parameter for noise and vibration control. However, in the complex structure, the forces at the injection point on the structure cannot be measured directly. Thus it is necessary to find out indirect force evaluation method. In this paper forces have been measured with in-situ vibration responses and system information. Three existing techniques of indirect force measurement, viz. direct inverse, principal component analysis and regularization have been compared. It has been shown that multi-vibration responses are essential for the precise estimation of the forces. To satisfy those conditions, Rotary compressor is adopted as test sample, because it is very difficult to measure the injection forces from internal excitation to shell. It has also been obtained that relatively higher force is transmitted though three welding paths to the compressor shell. It shows a good agreement between direct and indirect force evaluation with curvature shell and plate and is investigated the possibility of force evaluation of rotary compressor as a complex structure.

• Current Photovoltaic Research
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• 제4권4호
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• pp.140-144
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• 2016

In this paper, core-shell structure of nickel/gold (Ni/Au) conductive layer on poly-methyl-methacrylate (PMMA) micro-ball was fabricated and its conduction property was investigated. Firstly, PMMA micro-ball was synthesized by using dispersion polymerization method. Size of the ball was $2.8{\mu}m$ within ${\pm}7%$ deviation, and appropriate elastic deformation of the PMMA micro-ball ranging from 31 to 39% was achieved under 3 kg pressure. Also, 200 nm thick Ni/Au conductive layer was fabricated on the PMMA micro-ball by uniformly depositing with electroless-plating. Adhesion of the conductive layer was optimized with help of surface pre-treatment, and the layer adhered without peeling-off despite of thermal expansion by collision with accelerated electrons. Composite paste containing core-shell structured particles well cured at low temperature of $130^{\circ}C$ while pressing the test chip onto the substrate to make electrical contact, and electrical resistance of the conductive layer showed stable behavior of about $6.0{\Omega}$. Thus, it was known that core-shell structured particle of the Ni/Au conductive layer on PMMA micro-ball was feasible to flexible electronics.

• 한국전산구조공학회:학술대회논문집
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• 한국전산구조공학회 2004년도 봄 학술발표회 논문집
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• pp.317-324
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• 2004

Shape design optimization of shell structure is implemented on a basis of integrated framework of geometric modeling and finite element analysis which is constructed on the geometrically exact shell theory. This shell theory enables more accurate and robust analysis for complicated shell structures, and it fits for the nature of B-spline function which Is popular modeling scheme in CAD field. Shape of laminated composite shells is optimized through genetic algorithm and sequential linear programming, because there ire numerous optima for various configurations, constraints, and searching paths. Sequential adaptation of global and local optimization makes the process more efficient. Two different optimized results of laminated composite shell structures to minimize strain energy are shown for different layup sequence.

• 한국공간구조학회논문집
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• 제2권4호
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• pp.45-52
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• 2002

Research about spherical shells been applying most usually is achieved by many investigators already and generalized equation has been derived. But, existent research is limited in case that spherical shell's roof rigidity is isotropy or orthotropy, and research that consider periodicity of rigidity-distribution that can happen by doing spherical shell's roof system by lattice system is not gone entirely. The purpose of this paper is applying Galerkin method to spherical shell that model periodicity of roof rigidity distribution that appear by roof lattice form of large space structure and develop structural analysis program that formularize. Rigidity-model of this research selects that of spherical shell which has 2-way grid. In this paper, buckling-strength and deformation distribution of isotopic spherical shell and 2-way grid spherical shell obtained by developed program could confirm the reliability by comparison with result of existent research.