• Title/Summary/Keyword: shell powder

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Sintering Behavior of Ag-Ni Electrode Powder with Core-shell Structure

  • Kim, Kyung Ho;Koo, Jun-Mo;Ryu, Sung-Soo;Yoon, Sang Hun;Han, Yoon Soo
    • Journal of Surface Science and Engineering
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    • v.49 no.6
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    • pp.507-512
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    • 2016
  • Expensive silver powder is used to form electrodes in most IT equipment, and recently, many attempts have been made to lower manufacturing costs by developing powders with Ag-Ni or Ag-Cu core-shell structures. This study examined the sintering behavior of Ag-Ni electrode powder with a core-shell structure for silicon solar cell with high energy efficiency. The electrode powder was found to have a surface similar to pure Ag powder, and cross-sectional analysis revealed that Ag was uniformly coated on Ni powder. Each electrode was formed by sintering in the range of $500^{\circ}C$ to $800^{\circ}C$, and the specimen sintered at $600^{\circ}C$ had the lowest sheet resistance of $5.5m{\Omega}/{\Box}$, which is about two times greater than that of pure Ag. The microstructures of electrodes formed at varying sintering temperatures were examined to determine why sheet resistance showed a minimum value at $600^{\circ}C$. The electrode formed at $600^{\circ}C$ had the best Ag connectivity, and thus provided a better path for the flow of electrons.

Study on the Soil Improvement in the Grassland II. Effects of the dolomite particles and the shell powder application on soil characteristics, dry matter yield and nutritive value of forages in sandy loam soil (초지에서 토양 개량에서 관한 연구 II. 사양토에서 도로마이트 입자도와 패각분 시용이 토양 특성과 목초의 수량 및 사료가치에 미치는 영향)

  • Lee, J.K.;Choi, S.S.;Kim, M.J.;Yoon, S.H.;Park, G.J.;Choi, K.C.;Lee, S.C.
    • Journal of The Korean Society of Grassland and Forage Science
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    • v.19 no.4
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    • pp.373-378
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    • 1999
  • This study was conducted to investigate the effects of application of the dolomite particles and the shell powder on soil characteristics, dry matter yield and nutritive value of forage in sandy loam soil at the Experimental Field of National Livestock Research Institute, Suweon, from 1994 to 1996. This was compared with control, lime, dolomite 0.5mm, 2.0mm, 4.0mm, and shell powder in mixed pasture. Although there was no significant difference, average dry matter yield for 3 years was increased with the application of lime, dolomite 2.0mm, 0.5mm, control, 4.0mm and shell powder in order. Average crude protein yield of forages was increased with the application of dolomite 2.0mm, 0.5mm, control, lime, shell powder and 4.0mm in order. Lime requirement was slightly increased from 2,410 to 4,853kg per ha with the lapse of time. Although soil hardness was optimum level by second year, it was apt to become hard little by little. Solid phase of soil was lowered with dolomite 0.5mm treatment. The results demonstrated that dolomite and shell powder could be settled a dust problem in farms and a coast pollution as lime substitutes for soil improvement. Therefore, it is desirable for dry matter yield and crude protein yield to applicate the dolomite 2.0mm every 3 years and the shell powder more frequently in sandy loam soil.

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Characteristics of Heavy Metal Ion Adsorbent Extracted from Crab Shell (Crab Shell로부터 추출한 중금속 흡착제들의 특성)

  • 현근우;이찬기;이해승
    • Journal of environmental and Sanitary engineering
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    • v.14 no.2
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    • pp.46-55
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    • 1999
  • This study compared the adsorption characteristics of heavy metal ions by crab shell, treated crab shell with 2N-HCl, treated crab shell with 4%-NaOH, chitin and chitosan.Using crushed crab shell, the heavy metal ions removal rates of $Cd^{2+}$ and $Zn^{2+}$ were about 70-80% in 45minutes, but the removal rates of $Cu^{2+}$, $Cr^{6+}$ and $Pb^{2+}$ was less than 10%, 10% and 30%, respectively. For the by-products crab shell by 2N-HCl treatment, it was shown that the removal rates of $Cu^{2+}$ and $Pb^{2+}$ were about 70-80% in 45minutes reaction. But, some problems were observed, that the contained protein in crab shell was changed into gel in the mixing solution after a few hours. For the by-products of crab shell by 4%-NaOH treatment, the removal rates of Pb and Zn were about 90% in 45 minutes, and those of capacity of chitin and chitosan powder was better than those of the other by-products. The more adding to the adsorbent dosages increased the removal rates, and the adsorption reaction was rapidly occurred in a few minute. Using 1.0 wt% chitin powder, the heavy metal removal rates were ordered $Cu^{2+}$(94%) > $Zn^{2+}$(89%) > $Cd^{2+}$(88%) > $Pb^{2+}$(77%) > $Cr^{6+}$(58%) in 45 minutes. Using 1.0 wt% chitosan powder, the heavy metal removal rates were ordered $Cu^{2+}$(99%) > $Pb^{2+}$(96%) > $Cd^{2+}$(79%) > $Zn^{2+}$(71%) > $Cr${6+}$(46%) in 45minutes. The degree of degree of deacetylation by prepared chitosan was 91%.The Freundlich adsorption isotherm of $Cu^{2+}$, $Cd^{2+}$ and $Zn^{2+}$, when it was applied to 1.0 wt% chitosan powder in minutes, can be acceptable very strictly. The equation constant (1/n) for $Cu^{2+}$, $Cd^{2+}$ and $Zn^{2+}$ were 0.54 0.41 and 0.23 respectively.

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Effect of the Process Parameters on the Fe Nano Powder Formation in the Plasma Arc Discharge Process (플라즈마 아크 방전법에서 Fe 나노 분말 형성에 미치는 공정변수의 영향)

  • 이길근;김성규
    • Journal of Powder Materials
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    • v.10 no.1
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    • pp.51-56
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    • 2003
  • To investigate the effect of the parameters of the plasma arc discharge process on the particle formation and particle characteristics of the iron nano powder, the chamber pressure, input current and the hydrogen volume fraction in the powder synthesis atmosphere were changed. The particle size and phase structure of the synthesized iron powder were studied using the FE-SEM, FE-TEM and XRD. The synthesized iron powder particle had a core-shell structure composed of the crystalline $\alpha$-Fe in the core and the crystalline $Fe_3O_4$ in the shell. The powder generation rate and particle size mainly depended on the hydrogen volume fraction in the powder synthesis atmosphere. The particle size increased simultaneously with increasing the hydrogen volume fraction from 10% to 50%, and it ranged from about 45nm to 130 nm.

Effect of Dietary Pigment Sources on the Growth and Shell Color of Abalone (Haliotis discus hannai) (배합사료에 색소원료 첨가가 참전복 치패의 성장 및 패각 색깔에 미치는 영향)

  • LIM Tae-Jun;LEE Sang-Min
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.36 no.6
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    • pp.601-605
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    • 2003
  • This study investigated the effect of dietary pigment sources on growth and shell color of juvenile abalone(Haliotis discus hannai). Three replicate groups of the abalone (average weight 173 mg) were fed diets containing various pigment sources such as Porphyra powder, Spirulina, yeast astaxanthin, and paprika extract for 16 weeks. Survival and weight gain were not affected by dietary pigment sources (P>0.05). Shell color of abalone fed diets containing Porphyra powder and Spirulina approached the yellow-red and orange, colors similar to wild abalone. However, shell color of abalone fed the diets containing yeast astaxanthin and paprika extract were similar to the bright green control group. These results should be useful for changing the shell color of abalone in aquaculture.

Effect of Types of Egg Shell Calcium Salts and Egg Shell Membrane on Calcium Metabolism in Rats (난각 칼슘염의 종류와 난막의 존재유무가 흰쥐의 칼슘대사에 미치는 영향)

  • Noh, Kyung-Hee;Lee, Sang-Hyun;Ma, Jie;Zhou, Yusi;Kim, Jae-Cherl;Kim, Myo-Jeong;Song, Young-Sun
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.35 no.7
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    • pp.853-859
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    • 2006
  • This study was carried out to investigate the effect of egg shell calcium salt types and egg shell membrane on calcium metabolism in rats. Sprague-Dawley male rats, 4 weeks of age, were fed on free-calcium diets for 2 weeks after adjustment period. Rats weighing approximately $247{\pm}2.3g$ were divided into 6 groups and were fed on the experimental diets containing 0.2% calcium for 4 weeks. Experimental groups were as follows; {ES(M+)} (egg shell powder diet with egg shell membrane), {ES(M-)} (egg shell powder diet without egg shell membrane), {AC(M+)} (egg shell calcium acetate diet with egg shell membrance), {AC(M-)} (egg shell calcium acetate diet without eg shell membrane), {GC(M+)} (egg shell calcium glucuronate diet with egg shell membrane) and {GC(M-)} (egg shell calcium glucuronate diet without egg shell membrane). Bone length of femur was significantly different by the types (p<0.05) of egg shell calcium salts. Bone mineral density of femur showed the highest level in AC(M-) group. Calcium content of femur and calcium absorption rate were higher in egg shell calcium salt groups than in eg shell powder groups. Calcium absorption rate and retention were significantly different (p<0.05) among the types of eg shell calcium salts and were higher in the AC(M-) group than in the other groups. Alkaline phosphatase activity, parathyroid hormone and osteocalcin levels of serum showed no significant difference among the experimental groups. From the above results, it is concluded that bioavailability of calcium is higher in groups of egg shell calcium salts compared to those in egg shell powder, even though egg shell membrane has no effect on calcium metabolism. Thus, these findings suggest the possibility of using egg shell calcium salts as a functional food material related to calcium metabolism.

Synthesis of Ultrafine Zr Based Alloy Powder by Plasma Arc Discharge Process

  • Lee, Gil-Geun;Park, Je-Shin;Kim, Won-Baek
    • Proceedings of the Korean Powder Metallurgy Institute Conference
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    • 2006.09a
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    • pp.420-421
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    • 2006
  • In the present study, ultrafined Zr-V-Fe based alloy powder prepared by a plasma arc discharge process with changing process parameters. The chemical composition of synthesized powder was strongly influenced by the process parameters, especially the hydrogen volume fraction in the powder synthesis atmosphere. The synthesized powder had an average particle size of 50 nm. The synthesized Zr-V-Fe based particles had a shell-core structure composed of metal in the core and oxidse in the shell.

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Fabrication of Molybdenum Silicide-based Composites with Uniformly Dispersed Silicon Carbide (탄화 규소가 균일 분산된 규화 몰리브데넘계 복합재의 제조)

  • Choi, Won June;Park, Chun Woong;Kim, Young Do;Byun, Jong Min
    • Journal of Powder Materials
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    • v.25 no.5
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    • pp.402-407
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    • 2018
  • Molybdenum silicide has gained interest for high temperature structural applications. However, poor fracture toughness at room temperatures and low creep resistance at elevated temperatures have hindered its practical applications. This study uses a novel powder metallurgical approach applied to uniformly mixed molybdenum silicide-based composites with silicon carbide. The degree of powder mixing with different ball milling time is also demonstrated by Voronoi diagrams. Core-shell composite powder with Mo nanoparticles as the shell and ${\beta}-SiC$ as the core is prepared via chemical vapor transport. Using this prepared core-shell composite powder, the molybdenum silicide-based composites with uniformly dispersed ${\beta}-SiC$ are fabricated using pressureless sintering. The relative density of the specimens sintered at $1500^{\circ}C$ for 10 h is 97.1%, which is similar to pressure sintering owing to improved sinterability using Mo nanoparticles.

Removal Efficiency of Residual Pesticides in Mini-Tomatoes by Using CaO(scallop-shell powder) (CaO(scallop-shell powder)를 이용한 방울토마토 중 잔류농약 제거)

  • Lee Beom Gil;Sin Dong Bin;Ha Sang-Do
    • Journal of Food Hygiene and Safety
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    • v.20 no.2
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    • pp.114-117
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    • 2005
  • Although the removal efficiency of residual pesticides using tap water were ranged from -1.25 to $13.27\%$, the removal efficiencies of residual pesticides using both powder CaO and liquid CaO were $5.16\~l7.61,\;8.7\~41.59\%$, respectively. And those results showed much higher residual effect of the CaO washing than tap water washing. Natural CaO made by burning of scallop-shell considered to be a good reducing agent for pesticides. Furthermore, liquid CaO showed much higher removal efficiency than powder CaO. However, powder CaO also can be used as a good natural eliminator of pesticides in Mini-Tomato.