• Bulletin of the Korean Chemical Society
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• v.11 no.3
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• pp.245-248
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• 1990

A series of compounds were synthesized that contain varying number of mesogenic units, 4-n-butylazobenzene moiety, attached to the central benzene ring through ester bond. These compounds were subjected to thermal analysis on a differential scanning calorimeter (DSC) and also on a polarizing microscope. It was found from this study that the presence of mesogenic units in a multi-mesogenic compound does not guarantee for the compound to become mesomorphic and that the linear molecular shape is conducive to form a liquid crystalline phase.

• Journal of the Korean Society for Precision Engineering
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• v.22 no.4
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• pp.52-59
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• 2005

When a micro hole is machined by EDM with a cylindrical electrode, the hole diameter is different at the inlet and the outlet of the micro hole. The taper shape of the micro hole is caused by not only wear of the electrode but the eroded particles. The eroded particles cause secondary discharge during machining the micro hole. As a result, the diameter of the inlet becomes larger than that of the outlet. In this paper, a new method is proposed to reduce the difference in diameter between the inlet and the outlet of the hole. Observed was that the feed depth and machining time affect the formation of taper shape On this experimental basis, ultrasonic vibration was applied to reduce machining time, and capacitance was changed during machining to use the difference in discharging energy of different capacitances. Using the proposed method, a straight micro-hole was fabricated.

• Proceedings of the KSME Conference
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• 2001.06c
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• pp.94-99
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• 2001

Theoretical analysis using finite element method are peformed in order to clarify the formation of the flare-shape defect for multi-step tube sinking process. The parameters of concern were the friction between the tube and the die, and geometrical parameters, such as the die inclination angle, the diameters of the die entrance and exit, and the curvature at the corner of the die exit. The effect of the curvature at the comer of the die exit is dominant for determining the flare-shape defect. In order to minimize the flare-shape defect the curvature at the corner of the die exit should be increased up to a certain level(120mm). Using three-step tube sinking die sets which have different curvatures at the comer of the die exit, several numbers of tests were performed and its results are compared with that of theoretical analysis.

• Journal of the Korean Society for Precision Engineering
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• v.21 no.12
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• pp.154-159
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• 2004

This study is aimed to diminish the errors which created during transforming from 3D shape created with CAD program to STL file formation. The length strain which created on X-Y axises at STL file transforming is diminished by using the relation between common shape error and shrinkage rate. As the result of study, we have confirmed the length strain in accordance with facetres value. Also, the shape error is compensated with shrinkage rate by error of length strain. so, we could diminish to shape error by several tens micrometer.

• Journal of the Korean Society for Precision Engineering
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• v.14 no.3
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• pp.28-34
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• 1997

The side burrs and shape distortion resulting from the micromachining of an array of V-shape microgrooves in fresnel lens mould were experimentally invesigated. The focus of this study is on the influence of depth of cut and prism angle on the burr growing rate. The main experiments were con- ducted on the single prism cutting for the convinient of measuring the burr shape and cutting force. From the observation of the burr shape and burr growing rate, it was found that there exits a critical depth of cut below which the burrs are more or less irregular and weak. But above that critical value, the burrs are re- latively clear and stiff.

• Applied Chemistry for Engineering
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• v.17 no.3
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• pp.235-242
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• 2006

Liquid phase alkylation of biphenyl (BP) was studied over large pore zeolites. Selective formation of the least bulky products, 4,4'-diisopropylbiphenyl (4,4'-DIPB) occurred only in the isopropylation of BP over some large pore molecular sieves. H-mordenites (MOR) gave the highest selectivity among them. The dealumination of MOR enhanced catalytic activity and the selectivity of 4,4'-DIPB because of the decrease of coke-deposition. Non-selective catalysis occurs on external acid sites over MOR with the low $SiO_2/Al_2O_3$ ratio because severe coke-deposition deactivates the acid sites inside the pores by blocking pore openings. The selectivity of DIPB isomers was changed with reaction temperature. Selective formation of 4,4'-DIPB was observed at moderate temperatures such as $250^{\circ}C$, whereas the decrease of the selectivity of 4,4'-DIPB occurred at higher temperatures as $300^{\circ}C$. However, 4,4'-DIPB was almost exclusive isomer in the encapsulated DIPB isomers inside the pores even at high temperatures. These decreases of the selectivity of 4,4'-DIPB are due to the isomerization of 4,4'-DIPB on the external acid sites. Some 12-membered molecular sieves, such as SSZ-24, MAPO-5 (M:Mg, Zn, Si), SSZ-31, and ZSM-12, which have straight channels, gave 4,4'-DIPB with moderate to high selectivity; however; SSZ-55, SSZ-42, and MAPO-36 (M: Mg, Zn) gave lower selectivity because of cages in 12-membered one dimensional channels. Three dimensional H-Y and Beta zeolites also yield 4,4'-DIPB in low yield because of their wide circumstances for the isopropylation of BP. The increasing the size of alkylating agent enhanced the shape-selective alkylaiton even for the zeolites, such as UTD-1. The ethylation of BP to ethylbiphenyls (EBPs) and diethylbiphenyls (DEBPs) over MOR was non-selective. The ethylation of BP to EBPs was controlled kinetically. However, there was difference in reactivity of EBPs and DEBPs for their further ethylation. 4-EBP was ethylated preferentially among the isomers, although the formation of 4,4'-DEBP was less selective. The least bulky 4-EBP and 4,4'-DEBP have the highest reactivity among EBPs and DEBPs for the ethylation to polyethylbiphenyls (PEBPs). These results show that the environments of MOR pores are too loose for shape selective formation of the least bulky isomers, 4-EBP and 4,4'-DEBP in the ethylation of BP, and that MOR pores have enough space for the further ethylation of 4,4'-DEBP.

• Proceedings of the Korean Society of Machine Tool Engineers Conference
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• 2001.04a
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• pp.78-82
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• 2001

This paper presents the numerical analysis and experimental verification to know the metal cutting burr formation mechanism in face milling operation. Finite element method are applied to predict the 2-D burr formation process prediction. Face milling process are adjusted to analyze the characteristics of burr shapes according to various cutting conditions. The cutting parameters were investigated with cutting speed, feed rate, depth of cut. Through a few experiments, various burr types are classified according to its shape and properties.

• Proceedings of the Korean Society of Precision Engineering Conference
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• 2001.04a
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• pp.1000-1003
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• 2001

This paper presents the numerical analysis and experimental verification to know the metal cutting burr formation mechanism in face milling operation. Finite element method are applied to predict the 2-D burr formation process prediction. Face milling process are adjusted to analyze the characteristics of burr shapes according to various cutting conditions. The cutting parameters were investigated with cutting speed, feed rate, depth of cut. Through the experiments various burr types are classified according to its shape and properties.

• Korean Journal of Metals and Materials
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• v.48 no.6
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• pp.557-564
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• 2010

Formation of Sn through-silicon-via (TSV) and its interconnection processes were studied in order to form a three-dimensional interconnection structure of chip-stack packages. Different from the conventional formation of Cu TSVs, which require a complicated Cu electroplating process, Sn TSVs can be formed easily by Sn electroplating and reflow. Sn via-filling behavior did not depend on the shape of the Sn electroplated layer, allowing a much wider process window for the formation of Sn TSVs compared to the conventional Cu TSV process. Interlocking joints were processed by intercalation of Cu bumps into Sn vias to form interconnections between chips with Sn TSVs, and the mechanical integrity of the interlocking joints was evaluated with a die shear test.

• Biomolecules & Therapeutics
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• v.25 no.3
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• pp.223-230
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• 2017

Platelets play an essential role in hemostasis through aggregation and adhesion to vascular injury sites but their unnecessary activation can often lead to thrombotic diseases. Upon exposure to physical or biochemical stimuli, remarkable platelet shape changes precede aggregation or adhesion. Platelets shape changes facilitate the formation and adhesion of platelet aggregates, but are readily reversible in contrast to the irrevocable characteristics of aggregation and adhesion. In this dynamic phenomenon, complex molecular signaling pathways and a host of diverse cytoskeleton proteins are involved. Platelet shape change is easily primed by diverse pro-thrombotic xenobiotics and stimuli, and its inhibition can modulate thrombosis, which can ultimately contribute to the development or prevention of thrombotic diseases. In this review, we discussed the current knowledge on the mechanisms of platelet shape change and also pathological implications and therapeutic opportunities for regulating the related cytoskeleton dynamics.