• Title/Summary/Keyword: separation of mixture

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The Comparison of Bunsen Reaction With Phase Separation in Sulfur-lodine Thermochemical Hydrogen Production Process (황-요오드 열화학 수소 제조 공정에서 분젠 반응과 상 분리 비고)

  • Lee, Kwang-Jin;Ahn, Sueng-Hyuk;Kim, Young-Ho;Park, Chu-Sik;Bae, Ki-Kwang
    • Journal of Hydrogen and New Energy
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    • v.19 no.2
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    • pp.111-117
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    • 2008
  • A Bunsen reaction section is a primary stage of Sulfur-iodine thermochemical hydrogen production cycle. This section is important, because it decides the efficiency of next stages. In order to produce hydrogen very efficiently, the characteristics of Bunsen reaction were investigated via two experimental methods. The one is a phase separation of $H_2SO_4-HI-H_2O-I_2$ mixture system, and the other is a direct Bunsen reaction. The characteristics of each method were investigated and compared. As the result of this study, the amount of HI and $I_2$ in $H_2SO_4$ phase via Bunsen reaction was more decreased than that via $H_2SO_4-HI-H_2O-I_2$ mixture system with increasing $I_2$ concentration. However, the amount of $H_2SO_4$ in $HI_x$ phase via Bunsen reaction was remarkably increased with increasing $I_2$ concentration, while that via $H_2SO_4-HI-H_2O-I_2$ mixture system was decreased. On the other hand, the range of initial composition which is able to separate into two liquid phases without $I_2$ solidification was almost alike.

Robust Non-negative Matrix Factorization with β-Divergence for Speech Separation

  • Li, Yinan;Zhang, Xiongwei;Sun, Meng
    • ETRI Journal
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    • v.39 no.1
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    • pp.21-29
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    • 2017
  • This paper addresses the problem of unsupervised speech separation based on robust non-negative matrix factorization (RNMF) with ${\beta}$-divergence, when neither speech nor noise training data is available beforehand. We propose a robust version of non-negative matrix factorization, inspired by the recently developed sparse and low-rank decomposition, in which the data matrix is decomposed into the sum of a low-rank matrix and a sparse matrix. Efficient multiplicative update rules to minimize the ${\beta}$-divergence-based cost function are derived. A convolutional extension of the proposed algorithm is also proposed, which considers the time dependency of the non-negative noise bases. Experimental speech separation results show that the proposed convolutional RNMF successfully separates the repeating time-varying spectral structures from the magnitude spectrum of the mixture, and does so without any prior training.

Feature Selection for Multi-Class Genre Classification using Gaussian Mixture Model (Gaussian Mixture Model을 이용한 다중 범주 분류를 위한 특징벡터 선택 알고리즘)

  • Moon, Sun-Kuk;Choi, Tack-Sung;Park, Young-Cheol;Youn, Dae-Hee
    • The Journal of Korean Institute of Communications and Information Sciences
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    • v.32 no.10C
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    • pp.965-974
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    • 2007
  • In this paper, we proposed the feature selection algorithm for multi-class genre classification. In our proposed algorithm, we developed GMM separation score based on Gaussian mixture model for measuring separability between two genres. Additionally, we improved feature subset selection algorithm based on sequential forward selection for multi-class genre classification. Instead of setting criterion as entire genre separability measures, we set criterion as worst genre separability measure for each sequential selection step. In order to assess the performance proposed algorithm, we extracted various features which represent characteristics such as timbre, rhythm, pitch and so on. Then, we investigate classification performance by GMM classifier and k-NN classifier for selected features using conventional algorithm and proposed algorithm. Proposed algorithm showed improved performance in classification accuracy up to 10 percent for classification experiments of low dimension feature vector especially.

Development of Adsorptive Permeation Membrane (APM) and Process for Separation of $CO_2$ from gas mixtures (이산화탄소 분리를 위한 흡착투과막 및 공정 개발)

  • Yeom, Choong Kyun;Ahn, Hyo Sung;Kang, Kyeong Rok;Kim, Joo Yul;Han, Jin-Soo;Kwon, Keun-Oh
    • Membrane Journal
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    • v.23 no.6
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    • pp.409-417
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    • 2013
  • Adsorptive permeation hollow fiber membrane (APM) has been developed for effectively separating $CO_2$ from gas mixture. Inside the APM, zeolite 13X particles were uniformly dispersed without covering their surfaces by a symmetric porous structure of polypropylene lattice. In this study, $CO_2/N_2$ mixture was used as a simulated gas mixture. Separation was achieved by adsorbing $CO_2$ on the zeolite particles in the APM and then permeating $N_2$ into permeate side in passing all the feed gas through the APM. Adsorptive permeation tests were carried out with a set of APM modules, and the adsorptive permeation performances of the modules were analyzed from the test results. After saturation of the adsorbent with $CO_2$, the APM was regenerated by desorption of $CO_2$ from it through vacuuming both inside of outside of the APM hollow fiber, and the regeneration process of the APM by vacuuming was discussed in terms of regeneration efficiency and energy consumption.

MODIFIED COMPOSITE MEMBRANES FOR NANOFINTRATION

  • Jegal, Jong-Geon;Oh, Nam-Wun;Park, Duk-Soon;Lee, Kew-Ho
    • Proceedings of the Membrane Society of Korea Conference
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    • 1999.07a
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    • pp.35-38
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    • 1999
  • Nanofiltration (NF) composite membranes based of poly (vinyl alcohol) (PVA) and sodium alginate (SA) were prepared by coating PVA/SA (95/5 in wt %) mixture solutions on the microporous polysulfone (PS) supports, followed by the crosslinking with glutaraldehyed. The composite membranes prepared were characterized with a scanning electron microscopy (SEM), a fourier transform infrared spectroscopy(FTIR), an elecrtokinetic analyzer (EKA) and permeation tests.

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Chromatographic Separation of Maltopentaose from Maltooligosaccharides

  • Lee, Jae-Wook;Kwon, Tae-Ouk;Moon, Il-Shik
    • Biotechnology and Bioprocess Engineering:BBE
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    • v.8 no.1
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    • pp.47-53
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    • 2003
  • An experimental study on the chromatographic separation of maltopentaose from a mixture, including glucose, maltose, maltotriose, and maltopentaose, was carried out in a nonionic polymeric sorbent column while varying the operating conditions, such as the solution pH, buffer contents, and isopropyl alcohol (1PA) concentration. Unlike the pH and buffer contents, the IPA concentration had a Significant impact on the single component chromatograms for maltopentaose. The retention times of the maltooligosaccharides with the nonionic polymeric sorbent Sp207 were in the following order: glucose < maltose < maltotriose < maltopentaose. From the experimental binary, ternary, and quaternary chromatograms, gradient chromatographic separation with a changing IPA concentration as a function of time was required to obtain high-purity maltopentaose and reduce the elution time.

Development of a Forced-Vortex Oil-Water Separator (강제와류 유수분리기의 걔발)

  • 박외철;이광진
    • Journal of the Korean Society of Safety
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    • v.12 no.2
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    • pp.22-26
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    • 1997
  • A small scale centrifugal oil separator consisted of two concentric tubes was fabricated for spilt oil recovery. With speed control of the inner tube, its performance of oil separation was investigated. Oil-water mixture is separated by forced vortex motion with the rotating inner tube. Velocity and pressure distributions in the tubes were calculated. Control of rotating speed, which is the most influencing parameter, showed an optimum value 946rpm corresponding to the acceleration of 20g at the inner tube surface. Separation performance was suddenly deteriorated at rotating speed higher than 1200rpm.

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Separative Power of an Optimised Concurrent Gas Centrifuge

  • Bogovalov, Sergey;Borman, Vladimir
    • Nuclear Engineering and Technology
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    • v.48 no.3
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    • pp.719-726
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    • 2016
  • The problem of separation of isotopes in a concurrent gas centrifuge is solved analytically for an arbitrary binary mixture of isotopes. The separative power of the optimised concurrent gas centrifuges for the uranium isotopes equals to ${\delta}U=12.7(V/700m/s)^2(300K/T)(L/1m)kg{\cdot}SWU/yr$, where L and V are the length and linear velocity of the rotor of the gas centrifuge and T is the temperature. This equation agrees well with the empirically determined separative power of optimised counter-current gas centrifuges.

A PRACTICAL METHOD FOR THE DISPOSAL OF RADIOACTIVE ORGANIC WASTE

  • Kim, Kil-Jeong;Shon, Jong-Sik;Ryu, Woo-Seog
    • Nuclear Engineering and Technology
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    • v.39 no.6
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    • pp.731-736
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    • 2007
  • Radioactive organic wastes containing acetone, alcohol, and particularly tributyl phosphate (TBP)/dodecane contaminated with uranium are extracted from the PUREX process and the decontamination of related equipment. An evaporation method that utilizes existing DU oxidation apparatuses and ventilation systems and a typical muffle furnace installed with an aspirating system are adopted. A separation method using phosphoric acid especially for the TBP/dodecane waste is also studied and evaluated. The results show that a simple evaporation process is utilizable for wastes containing acetone or alcohol with a lower boiling point. A modified muffle furnace is more appropriate to dispose directly of organic wastes having a higher boiling point, such as TBP/dodecane, without generating a condensed waste solution. It is recommended that, when the uranium concentration of TBP/dodecane waste is much higher than stipulated levels, separation technology should be applied to remove uranium from the mixture. Each type of solvent after separation can then be considered disposable below the regulatory limit in the modified furnace discussed in this study.

Chiral separation of $\beta$-blockers after derivatizalion wilh a new chiral derivalizalion agen1.GATC and Comparison wilh GITC on derivalizing conditions and chromalographic paramelers

  • Ko, Mi-Young;Shin, Dae-Hong;Seo, Sang-Hun;Kim, Kyeong-Ho
    • Proceedings of the PSK Conference
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    • 2002.10a
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    • pp.398.1-398.1
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    • 2002
  • A new chiral derivatization agent with sugar moiety. 2, 3.4, 6-tetra-O-acetyl-D-galactopyranosyl isothiocyanate (GATC) was synthesized. Several $\beta$-blockers were investigated for the possible separation of the enantiomers by reversed-phase HPLC after derivatization with this new chiral derivatization agent (GATC). GATC was reacted readily with $\beta$-blockers at room temperature and the reaction mixture could directly be injected into the HPLC system. (omitted)

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