• Title/Summary/Keyword: self-assembly method

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Local Photoswitching Effects of Cytochrome c/Viologen/GFP Hetero-Thin Film

  • Yu, Chang-Jun;Choe, Jeong-U;Park, Se-Jeong;Nam, Yun-Seok;O, Byeong-Geun;Lee, Won-Hong
    • 한국생물공학회:학술대회논문집
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    • 2001.11a
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    • pp.823-826
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    • 2001
  • In the initial process of photosynthesis, a biological electron transfer system, photoelectric conversion occurs and then long-range electron transfer takes place very efficiently in one direction through the biomolecules. The metal/insulator/metal structured device consisting of GFP, viologen, cytochrome c hetero-thin film was presented based on the biomimesis. GFP, viologen, and cytochrome c was used as an electron sensitizer, a mediator, and an electron acceptor. Cytochrome c molecules and viologen molecules were deposited by Langmuir-Blodgett (LB) technique, and GFP molecules were adsorbed by self-assembly method (SAM). Surface morphology of hetero-thin film was analyzed by scanning tunneling microscopy (STM). Local photoswitching effects of a proposed photodiode were verified by current-voltage measurements using hybrid STM/I-V measurement system.

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Electrochemical Detection of Hydrogen Peroxide based on Viologen Monolayers (Viologen 박막을 이용한 과산화수소의 전기화학적 검출 특성)

  • Choi, Won-Suk;Lee, Dong-Yun;Park, Sang-Hyun;Park, Jae-Chul;Kwon, Young-Soo
    • The Transactions of The Korean Institute of Electrical Engineers
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    • v.57 no.11
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    • pp.2006-2010
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    • 2008
  • In this paper, we fabricated a biosensor for detecting hydrogen peroxide and investigated the sensing property. We prepared a viologen and hemoglobin modified gold electrode using self-assembly and layer by layer method. The electrochemical property of the viologen derivative was characterized in 0.1 M $NaClO_4$ electrolyte solution by cyclic voltammetry. The modified electrode showed reversible electrochemical properties and high stability. From the results, the viologen can act as a charge transfer mediator for access to the electrode surface. The catalytic characteristics of the designed sensor proved that hemoglobin has been kept in its natural structure and can retain its biological activity. The designed biosensor showed a fast amperometric response, excellent linearity and low detection limit. In addition, it had high sensitivity, good reproducibility and stability.

Fabrication of Wafer-scale Polystyrene (2+1) Dimensional Photonic Crystal Multilayers Via the Layer-by-layer Scooping Transfer Technique

  • Do, Yeong-Rak;O, Jeong-Rok;Lee, Gyeong-Nam
    • Proceedings of the Materials Research Society of Korea Conference
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    • 2011.05a
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    • pp.11.1-11.1
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    • 2011
  • We have developed a simple synthetic method for fabricating a wafer-scale colloidal crystal film of 2D crystals in a 1D stack based on a combination of two simple processes : the self-assembly of polystyrene (PS) nanospheres at the water-air interface and the layer-by-layer (LbL) scooping transfer technique. The main advantage of this approach is that it allows excellent control of the thickness (at a layer level) of the crystals and the formation of a vertical crack-free layer over a wafer-scale (4 inch). We investigate the optical and morphological properties of the PhC multilayers fabricated using various mono-sized colloidal crystals (250, 300, 350, 420, 580, 720, and 850 nm), and mixed binary colloidal crystals (300/350 and 250/350 nm).

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SAMSUNG FARA SCARA robot system (삼성 파라 스카라 로봇시스템)

  • 김성권;신기범;김동일;전재욱;김영철;오인환;황찬영;임상권;김호규
    • 제어로봇시스템학회:학술대회논문집
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    • 1991.10a
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    • pp.504-510
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    • 1991
  • SAMSUNG Electronics has developed a SCAR.A robot system, SM3, which is applicable to several assembly, inspection, and adjustment tasks. This robot system drives by AC servo motors has attained a .theta.1 and .theta.2 axis maximum composite speed of 5.4 m/sec, a repeatability of .+-.05 mm, and a cycle time of 1.2 sea. The robot controller based on three 8086 and one 8087 processors consists of the main controller, the joint position controller, and the motor controller. The robot controller has plentiful self-diagnosis and control capabilities, and can be interfaced to other external device. The robot language FARAL Is designed such that every task is easily programmed. In this paper, the main features of the body, controller, and FARAL of SM3 will be described. In particular, the control method designed for a stable and fast robot motion will be explained. Finally, the future development will be addressed.

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Derivation of Cubic and Hexagonal Mesoporous Silica Films by Spin-coating

  • Pan, Jia-Hong;Lee, Wan-In
    • Bulletin of the Korean Chemical Society
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    • v.26 no.3
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    • pp.418-422
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    • 2005
  • By introducing spin-coating method to the evaporation induced self-assembly (EISA) process, a simple and reproducible route in controlling the mesophase of silica thin films has been developed for the first time in this work. When a comparatively solvent-rich Si-sol (The atomic ratio of TEOS : F127 : HCl : $H_2O$ : EtOH = 1 : 0.006 : 0.2 : 9.2 : 30) was used as coating solution, the mesophase of resultant silica films was selectively controlled by adjusting the spin-on speed. The cubic mesophase has been obtained from the coating at a low rpm, such as 600 rpm, while the 2-D hexagonal mesophase is formed at a high rpm, such as 2,500 rpm. At a medium coating speed, a mixture of cubic and hexagonal mesophase has been found in the fabricated films. The present results confirm that the evaporation rate of volatile components at initial step is critical for the determination of mesopore structures during the EISA process.

Electro-optic Behavior of Photonic Crystals with Nematic Liquid-Crystal (액정을 이용한 광자결정의 형성과 전기광학 효과)

  • Kwon, Jang-Un;Han, Soon-Ku;Kang, Dae-Seung
    • Proceedings of the KIEE Conference
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    • 2002.07c
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    • pp.1933-1935
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    • 2002
  • In this paper, we present a study of the structure and electro-optic behavior of hybrid liquid-crystal-silica sphere composite photonic crystals, formed by filling the (26% by volume) void space of fee (face centered cubic) silica opals infiltrated with a nematic liquid crystal. Three dimensional photonic crystals of visible range were fabricated via a self assembly method of silica spheres of submicron diameter. The expected fee structure was confirmed by scanning electron microscopy (SEM) of the dehydrated crystal with glass removed. The photonic crystal exhibited significant electric-field-induced shift of the optical Bragg reflection peak when the liquid crystal has the long molecular axis oriented parallel to the sphere surfaces.

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Alumina Templates on Silicon Wafers with Hexagonally or Tetragonally Ordered Nanopore Arrays via Soft Lithography

  • Park, Man-Shik;Yu, Gui-Duk;Shin, Kyu-Soon
    • Bulletin of the Korean Chemical Society
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    • v.33 no.1
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    • pp.83-89
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    • 2012
  • Due to the potential importance and usefulness, usage of highly ordered nanoporous anodized aluminum oxide can be broadened in industry, when highly ordered anodized aluminum oxide can be placed on a substrate with controlled thickness. Here we report a facile route to highly ordered nanoporous alumina with the thickness of hundreds-of-nanometer on a silicon wafer substrate. Hexagonally or tetragonally ordered nanoporous alumina could be prepared by way of thermal imprinting, dry etching, and anodization. Adoption of reusable polymer soft molds enabled the control of the thickness of the highly ordered porous alumina. It also increased reproducibility of imprinting process and reduced the expense for mold production and pattern generation. As nanoporous alumina templates are mechanically and thermally stable, we expect that the simple and costeffective fabrication through our method would be highly applicable in electronics industry.

Selective Band Engineering of an Isolated Subnanometer Wire

  • Song, In-Gyeong;Park, Jong-Yun;An, Jong-Ryeol
    • Proceedings of the Korean Vacuum Society Conference
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    • 2013.02a
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    • pp.267-267
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    • 2013
  • Band engineering of a nanowire is related to the question what is the minimum size of a nanowire-based device. At the subnanometer scale, there has been a long standing problem whether it is possible to both control an energy band of an isolated nanowire by a dopant and measure it using angle-resolved photoemission spectroscopy (ARPES). This is because an extra atom in the subnanometer wire plays as a defect rather than a dopant and it is challenging to assemble isolated subnanometer wires into an array for an ARPES measurement. We demonstrate that only one of multiple metallic subnanometer wires canbe controlled electronically by a dopant maintaining the whole metallic bands of other wires, which was observed directly by ARPES. Here,the multiple metallic subnanometer wires were produced on a stepped Si(111) surface by a self-assembly method. The selective band engineering proves that the selectively-controlled metallic wire is nearly isolated electronically from other metallic wires and an electronic structure controlcan be realized down to subnanometer scale.

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Studies on Properties of Polyaniline-Dodecylbenzene Sulfonic Acid Composite Films Synthesized Using Different Oxidants

  • Basavaraja, C.;Pierson, R.;Huh, Do-Sung;Venkataraman, A.;Basavaraja, S.
    • Macromolecular Research
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    • v.17 no.8
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    • pp.609-615
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    • 2009
  • Two types of nano composite were obtained by in situ chemical method in polyaniline (PANI)/dodecyl-benzenesulfonic acid (DBSA) system depending on the use of either ammonium persulfate (APS) or ferric chloride ($FeCl_3$) as the oxidant. In order to study the difference of the two composites in the surface characteristics, thermal stability, and electric properties, the composite films were studied by transmission electron microscopy (TEM), X-ray diffraction (XRD), thermogravimetric analysis (TGA), and temperature dependent DC electrical conductivity. The results revealed a large difference in the surface morphology, thermal stability, and the microstructure properties between the two composites, and these differences were considered responsible for the molecular order and conductivity.

Investigations on the Pu-to-244Cm ratio method for Pu accountancy in pyroprocessing

  • Sunil S. Chirayath;Heukjin Boo;Seung Min Woo
    • Nuclear Engineering and Technology
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    • v.55 no.10
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    • pp.3525-3534
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    • 2023
  • Non-uniformity of Pu and Cm composition in used nuclear fuel was analyzed to determine its effect on Pu accountancy in pyroprocessing, while employing the Pu-to-244Cm ratio method. Burnup simulation of a typical pressurized water reactor fuel assembly, required for the analysis, was carried out using MCNP code. Used fuel nuclide composition, as a function of nine axial and two radial meshes, were evaluated. The axial variation of neutron flux and self-shielding effects were found to affect the uniformity of Pu and Cm compositions and in turn the Pu-to-244Cm ratio. However, the results of the study showed that these non-uniformities do not affect the use of Pu-to-244Cm ratio method for Pu accountancy, if the measurement samples are drawn from the voloxidized powder at the feed step of pyroprocessing. 'Material Unaccounted For' and its uncertainty estimates are also presented for a pyrprocessing facility to verify safeguards monitoring requirements of the IAEA.