Macromolecular Research

The Polymer Society of Korea (한국고분자학회)
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Studies on Properties of Polyaniline-Dodecylbenzene Sulfonic Acid Composite Films Synthesized Using Different Oxidants

  • Basavaraja, C. (Department of Chemistry and Institute of Functional Materials, Inje University) ;
  • Pierson, R. (Department of Chemistry and Institute of Functional Materials, Inje University) ;
  • Huh, Do-Sung (Department of Chemistry and Institute of Functional Materials, Inje University) ;
  • Venkataraman, A. (Department of Materials Science, Gulbarga University) ;
  • Basavaraja, S. (Department of Materials Science, Gulbarga University)
  • Published : 2009.08.25
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Abstract

Two types of nano composite were obtained by in situ chemical method in polyaniline (PANI)/dodecyl-benzenesulfonic acid (DBSA) system depending on the use of either ammonium persulfate (APS) or ferric chloride ($FeCl_3$) as the oxidant. In order to study the difference of the two composites in the surface characteristics, thermal stability, and electric properties, the composite films were studied by transmission electron microscopy (TEM), X-ray diffraction (XRD), thermogravimetric analysis (TGA), and temperature dependent DC electrical conductivity. The results revealed a large difference in the surface morphology, thermal stability, and the microstructure properties between the two composites, and these differences were considered responsible for the molecular order and conductivity.

Keywords

References

  1. E. M. Genies, A. Boyle, M. Lapkowski, and C. Tsintavis, Synth. Met., 36, 139 (1990) https://doi.org/10.1016/0379-6779(90)90050-U
  2. C. M. Finch, S. Srichantaropass, S. W. Bailey, I. M. Grace, V. M. García-Suárez, and C. J. Lambert, J. Phys.: Condens. Matter., 20, 22203 (2008) https://doi.org/10.1088/0953-8984/20/02/022203
  3. A. Skotheim, Handbook of Conducting Polymers, New York, Marcel Dekker, 1986, Vol. 1
  4. H. S. Nalwa, Handbook of Organic Conductive Molecules and Polymers, New York, Wiley, 1997, Vol. 4
  5. M. G. Guenza, J. Phys.: Condens. Matter., 20, 33101 (2008) https://doi.org/10.1088/0953-8984/20/03/033101
  6. C. R. Martin, Chem. Mater., 8, 1739 (1996) https://doi.org/10.1021/cm960166s
  7. I. D. Norris, M. M. Shaker, F. K. Ko, and A. G. MacDiarmid, Synth. Met., 114, 109 (2000) https://doi.org/10.1016/S0379-6779(00)00217-4
  8. X. Y. Zhang, W. J. Goux, and S. K. Manohar, J. Am. Chem. Soc., 126, 4502 (2004) https://doi.org/10.1021/ja031867a
  9. J. X. Huang, S. Virji, B. H. Weiller, and R. B. Kaner, J. Am. Chem. Soc., 125, 314 (2003) https://doi.org/10.1021/ja028371y
  10. Z. Wei, Z. Zhang, and M. Wan, Langmuir, 18, 917 (2002) https://doi.org/10.1021/la0155799
  11. Z. Wei and M. Wan, Adv. Mater., 14, 1314 (2002) https://doi.org/10.1002/1521-4095(20020916)14:18<1314::AID-ADMA1314>3.0.CO;2-9
  12. D. Wang and F. Caruso, Adv. Mater., 13, 350 (2001) https://doi.org/10.1002/1521-4095(200103)13:5<350::AID-ADMA350>3.0.CO;2-X
  13. W. L. Macknight, E. A. Ponomarenko, and D. A. Tirrell, Acc. Chem. Res., 31, 781 (1998) https://doi.org/10.1021/ar960309g
  14. T. Jana and A. K. Nandi, Langmuir, 17, 5768 (2001) https://doi.org/10.1021/la010253l
  15. T. Jana, J. Chatterjee, and A. K. Nandi, Langmuir, 18, 5720 (2002) https://doi.org/10.1021/la025724y
  16. J. Ruokolainen, R. Makinen, M. Torkkeli, T. Makela, R. Serimaa, G. ten Brinke, and O. Ikkala, Science, 280, 557 (1998) https://doi.org/10.1126/science.280.5363.557
  17. D. Tsotcheva, T. Tsanov, L. Terlmezyam, and S.Vassilev, J. Therm. Anal., 63, 133 (2001) https://doi.org/10.1023/A:1010140504579
  18. W. Jia, E. Segal, D. Kornemandel, Y. Lamhot, M. Narkis, and A. Siegmann, Synth. Met., 128, 115 (2002) https://doi.org/10.1016/S0379-6779(01)00672-5
  19. C. Basavaraja, Y. Veeranagouda, K. Lee, R. Pierson, S. H. Park, E. J. Jeon, and D. S. Huh, Eur. Polym. J. (submitted for publication) (2008)
  20. C. Basavaraja, R. Pierson, and D. S. Huh, J. Appl. Polym. Sci., 108, 1070 (2008) https://doi.org/10.1002/app.27582
  21. C. Basavaraja, R. Pierson, T. K. Vishnuvardhan, and D. S. Huh, Eur. Polym. J., 44, 1556 (2008) https://doi.org/10.1016/j.eurpolymj.2008.02.015
  22. M. Antonietti, D. Radloff, U. Niesner, and H. W. Spiess, Macromol. Chem. Phys., 197, 2713 (1996) https://doi.org/10.1002/macp.1996.021970910
  23. M. Antoniett, A. Wenzel, and A. Thunemann, Langmuir, 12, 2111 (1996) https://doi.org/10.1021/la950620r
  24. P. Chowdhury and B. Saha, J. Appl. Polym. Sci., 103, 1626 (2007) https://doi.org/10.1002/app.24609
  25. Y. Z. Wang, Y. C. Hsu, L. C. Chou, and K. H. Hsieh, J. Polym. Res., 11, 127 (2004)
  26. A. Gok, B. Sari, and M. Talu, Synth. Met., 142, 41 (2004) https://doi.org/10.1016/j.synthmet.2003.07.002
  27. A. Gok, M. Omastov, and A. Y. Gul, Synth. Met., 157, 23 (2007) https://doi.org/10.1016/j.synthmet.2006.11.012
  28. A. A. Athawale, M. V. Kulkarni, and V. V. Chabukswar, Mater. Chem. Phys., 73, 106 (2002) https://doi.org/10.1016/S0254-0584(01)00338-8
  29. S. A. Chen and H. T. Lee, Synth. Met., 47, 233 (1992) https://doi.org/10.1016/0379-6779(92)90390-5
  30. M. Wan, M. Li, J. Li, and Z. Liu, J. Appl. Polym. Sci., 53, 131 (1994) https://doi.org/10.1002/app.1994.070530201
  31. D. Das, S. Kar, S. Chakraborty, D. Chakraborty, and S. Gangopadhyay, J. Appl. Polym. Sci., 69, 841 (1998) https://doi.org/10.1002/(SICI)1097-4628(19980801)69:5<841::AID-APP1>3.0.CO;2-M
  32. P. R. Somani, R. Marimuthu, and A. B. Mandale, Polymer, 42, 2991 (2001) https://doi.org/10.1016/S0032-3861(00)00670-4
  33. C. H. Chen, J. Polym. Res., 9, 195 (2002) https://doi.org/10.1023/A:1021395726060
  34. M. Wan, M. Li, J. Li, and Z. Liu, J. Appl. Polym. Sci., 53, 131 (1994) https://doi.org/10.1002/app.1994.070530201
  35. M. Zilberman, G. I. Titelman, A. Siegmann, Y. Haba, M. Narkis, and D. Alperstein, J. Appl. Polym. Sci., 66, 243 (1998) https://doi.org/10.1002/(SICI)1097-4628(19971010)66:2<243::AID-APP5>3.0.CO;2-W
  36. M. E. Leyva, G. M. O. Barra, and B. G. Soares, Pol\acute{i}meros, 12, 197 (2002)
  37. J. K. Choi, Y. W. Kim, and J. H. Koh, Marcromol. Res., 15, 553 (2007) https://doi.org/10.1007/BF03218830
  38. H. Namgoong, D. J. Woo, and S. H. Lee, Marcromol. Res., 15, 633 (2007) https://doi.org/10.1007/BF03218943