• Title/Summary/Keyword: self diffusions

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Self Diffusion Coefficients and Free Hole Volumes of Poly(acrylonitrile)-poly(vinyl chloride) Copolymers (Poly(acrylonitrile)-poly(vinyl chloride) 공중합체의 자체 확산 계수와 유동 자유 홀부피)

  • Kim, Nam-Jeong
    • Elastomers and Composites
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    • v.46 no.3
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    • pp.245-250
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    • 2011
  • The self diffusions and hole volumes of amorphous region of poly(acrylonitrile)-poly(vinyl chloride) fibers were investigated by experiments of stress relaxation. The experiments of stress relaxation were carried out using the tensile tester with the solvent chamber. The flow parameters of filament fibers were obtained by applying the experimental stress relaxation curves to the theoretical equation of stress relaxation. From the flow parameters, the hole volumes, self diffusions, viscosities and thermodynamic parameters of solid polymers were calculated. It was observed that the flow parameters of these samples are directly related to the hole volumes, self diffusions and flow activation energies of flow segments.

UNIQUENESS OF POSITIVE STEADY STATES FOR WEAK COMPETITION MODELS WITH SELF-CROSS DIFFUSIONS

  • Ko, Won-Lyul;Ahn, In-Kyung
    • Bulletin of the Korean Mathematical Society
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    • v.41 no.2
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    • pp.371-385
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    • 2004
  • In this paper, we investigate the uniqueness of positive solutions to weak competition models with self-cross diffusion rates under homogeneous Dirichlet boundary conditions. The methods employed are upper-lower solution technique and the variational characterization of eigenvalues.

[ W12 ]-ESTIMATES ON THE PREY-PREDATOR SYSTEMS WITH CROSS-DIFFUSIONS AND FUNCTIONAL RESPONSES

  • Shim, Seong-A
    • Communications of the Korean Mathematical Society
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    • v.23 no.2
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    • pp.211-227
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    • 2008
  • As a mathematical model proposed to understand the behaviors of interacting species, cross-diffusion systems with functional responses of prey-predator type are considered. In order to obtain $W^{1_2}$-estimates of the solutions, we make use of several forms of calculus inequalities and embedding theorems. We consider the quasilinear parabolic systems with the cross-diffusion terms, and without the self-diffusion terms because of the simplicity of computations. As the main result we derive the uniform $W^{1_2}$-bound of the solutions and obtain the global existence in time.

pH Effect on Relaxation Spectra of Poly(methyl acrylate)-Poly(acrylonitrile) Copolymers by REM Model (REM 모델에 의한 Poly(methyl acrylate)-Poly(acrylonitrile) 공중합체 완화스펙트럼의 pH 영향)

  • Kim, Nam Jeong
    • Polymer(Korea)
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    • v.37 no.2
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    • pp.135-140
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    • 2013
  • The stress relaxation of poly(methyl acrylate)-poly(acrylonitrile) copolymer samples was carried out in air, distilled water, pH 3, 7 and 11 solutions at various temperatures using a tensile tester equipped with a solvent chamber. The relaxation spectra of poly(methyl acrylate)-poly(acrylonitrile) copolymers were obtained by applying the experimental stress relaxation curves to the equation of relaxation spectrum derived from the Ree-Eyring and Maxwell model. The determination of relaxation spectra was performed from computer calculation using a Laplace transform method. It was observed that the relaxation spectra of these samples are directly related to the distribution of molecular weights and self-diffusions of flow segments.

Self-Diffusion of THO within Tactic Poly(2-hydroxyethyl methacrylate) Membranes

  • Kim, Hye-Kyeong;Jhon, Mu-Shik
    • Bulletin of the Korean Chemical Society
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    • v.4 no.3
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    • pp.128-132
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    • 1983
  • The self-diffusion experiment of water was performed across two series of tactic poly(2-hydroxyethyl methacrylate), P(HEMA) membranes prepared by crosslinking with various amount of hexamethylene diisocyanate (HMDIC). The tagging material was tritium hydroxide (THO) and the efflux of THO was counted on a Liquid Scintillation Counter. The transport data of THO show that the permeability decreases as the amount of HMDIC increased from 2.5 to 10 mole % and the self-diffusions coefficient shows a parallel trend with it. The diffusivity data was discussed in terms of the change of water structural orderliness within membranes. Using the relation between viscosities and diffusivities derived from Eyring's absolute rate theory, the corresponding viscosities of water within two series of tactic P(HEMA) membranes were obtained. From this, it is seen that the viscosity of water within tactic P(HEMA) membranes may have the same values with those of supercooling water whose temperature ranges from -28 to -$36^{\circ}C.$.

Thermodynamic Properties and Self Diffusions from Rheological Parameters of Eyring-Halsey Model (Eyring-Halsey 모델의 유동파라메타로부터 열역학 성질과 자체 확산)

  • Kim, Nam Jeong
    • Journal of the Korean Chemical Society
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    • v.58 no.3
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    • pp.251-257
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    • 2014
  • The stress relaxation of poly(methyl acrylate)-poly(acrylonitrile) copolymer samples were carried out in air and distilled water at various temperatures using the tensile tester with the solvent chamber. The rheological parameters were obtained by applying the experimental stress relaxation curves to the theoretical equation of the Eyring-Halsey non-Newtonian model. The self diffusion, hole volume, viscosities, and thermodynamic parameters of copolymer samples were calculated from rheological parameters and crystallite size in order to study of flow segments in amorphous region. It was observed that the rheological parameters of these copolymer samples are directly related to the self diffusion, hole volume, viscosities, and thermodynamic parameters of flow segments.

Self Diffusions and Rheological Properties of Polyamide Polymer Materials in Various Solvents (용매 환경에서의 폴리아미드 고분자 재료의 자체확산과 유변학적인 특성)

  • Kim, Nam Jeong
    • Journal of the Korean Applied Science and Technology
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    • v.36 no.4
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    • pp.1050-1059
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    • 2019
  • The self diffusion, hole volume, and flow thermodynamic parameters of polyamide fibers were calculated from rheological parameters and crystallite size in order to study of flow segments in amorphous region. The stress relaxation of polyamide filament fibers were carried out in air and various solvents at various temperatures using the tensile tester with the solvent chamber. The rheological parameters were obtained by applying the experimental stress relaxation curves to the theoretical equation of the Ree-Eyring and Maxwell non-Newtonian model. It was observed that the rheological parameters of these polyamide filament fibers are directly related to the relaxation spectra, self diffusion, viscosities, and activation energies of flow segments.

Motivations and Characteristics of Hashtag Users

  • Kim, Gwon-Il;Jung, Ga Yeon;Song, Ye Ji;Park, Jee-Sun
    • Journal of Fashion Business
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    • v.19 no.6
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    • pp.112-126
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    • 2015
  • In social environments, hashtags have been widely adopted and have become a new form of language for users. The current study attempts to enhance our understanding of users and their motivations to use hashtags when posting fashion-related information. Specifically, this study examines whether user characteristics (fashion leadership, conspicuousness) influence their motivations to use hashtags (curation, self-presentation, information diffusion), which then leads to behavioral intentions to continue to use hashtags and recommend the same to others. An online survey was administered to test our research questions. A total of 136 consumers in their 20s, 30s, and 40s living in Korea were used for data analysis. Structural equation modeling was conducted, which revealed that fashion leadership and conspicuousness had a positive impact on users' motivations of curation, self-presentation, and information diffusion. Motivations of self-presentation and information diffusions were found to affect users' behavioral intentions while curation had no significant impact. Practical implications are presented.

Determination of Self Diffusion Distributions of Molten Polyurethanes by Relaxation Spectra (용융 폴리우레탄의 완화 스펙트럼에 의한 자체확산분포 결정)

  • Kim, Nam-Jeong
    • Journal of the Korean Chemical Society
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    • v.50 no.3
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    • pp.196-202
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    • 2006
  • The self diffusion distributions of viscoelastic molten polyurethanes were determined from the relationship between the relaxation spectra and the distribution of self diffusion. The relaxation spectra of ester, PCL and PCL dyed type molten polyurethanes were obtained by applying the experimental stress relaxation curves to the theoretical equation of the Ree-Eyring and Maxwell non-Newtonian model(REM model) from computer calculation. The experiments were carried out at various temperatures using the physica rheometer with the temperature controller. The self diffusion and hole distance of amorphous region of polyurethane samples were investigated by experiments of stress relaxation. The diffusion coefficients and hole volumes were calculated from rheological parameters and crystallite size in order to study the diffusion of flow segments in amorphous region. It was observed that the relaxation spectra and self diffusions of these polymer samples are directly related to the distribution of molecular weights, viscosities, hole volumes and activation energies of flow segments.