• Title/Summary/Keyword: secondary structure of ITS

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Charge-discharge behaviour of $LiNi_{0.85}Co_{0.15}O_2>/MPCF$ cell ($LiNi_{0.85}Co_{0.15}O_2/MPCF$전지의 충방전 특성)

  • 김상필;조정수;박정후;윤문수
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1998.11a
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    • pp.25-28
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    • 1998
  • Lithiated cobalt and nickel oxides are becoming very attractive as active cathode materials for secondary lithium ion secondary battery. $LiCoO_2$ is easily synthesized from lithium cobalt salts, but has a relatively high oxidizing potential on charge. LiNiOz is synthesized by a more complex procedure and its nonstoichiometry significantly degraded the charge-discharge characteristics. But $LiNiO_2$ has a lower charge potential which increases the system stability. Lithiated cobalt and nickel oxides are iso-structure which make the preparation of solid solutions of $LiNi_{1-x}Co_xO_2$ for O$LiCoO_2 and LiNiO_2$ electrode. The aim of the presentb paper is to study the electrochemical behaviour, as weU as the possibilities for practical application of layered Iithiated nickel oxide stabilized by $Co^{3+}$ substitution as active cathode materials in lithium ion secondary battery.

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A Novel Switched Capacitor High Step-up dc/dc Converter Using a Coupled Inductor with its Generalized Structure

  • Hamkari, Sajjad;Moradzadeh, Majid;Zamiri, Elyas;Nasir, Mehdi;Hosseini, Seyed Hossein
    • Journal of Power Electronics
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    • v.17 no.3
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    • pp.579-589
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    • 2017
  • In this study a new high step-up dc-dc converter is presented. The operation of the proposed converter is based on the capacitor switching and coupled inductor with a single active power switch in its structure. A passive voltage clamp circuit with two capacitors and two diodes is used in the proposed converter for elevating the converter's voltage gain with the recovered energy of the leakage inductor, and for lowering the voltage stress on the power switch. A switch with a low $R_{DS}$ (on) can be adopted to reduce conduction losses. In the generalized mode of the proposed converter, to reach a desired voltage gain, capacitor stages with parallel charge and series discharge techniques are extended from both sides of secondary side of the coupled inductor. The proposed converter has the ability to alleviate the reverse recovery problem of diodes with circuit parameters. The operating principle and steady-states analyses are discussed in detail. A 40W prototype of the proposed converter is implemented in the laboratory to verify its operation.

Seven new species of two genera Scalarispongia and Smenospongia (Demospongiae: Dictyoceratida: Thorectidae) from Korea

  • Kim, Young A;Lee, Kyung Jin;Sim, Chung Ja
    • Journal of Species Research
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    • v.9 no.2
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    • pp.147-161
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    • 2020
  • Seven new species of two genera Scalarispongia and Smenospongia (Demospongiae: Dictyoceratida: Thorectidae) are described from Gageo Island and Jeju Island, Korea. Five new species of Scalarispongia are compared to nine reported species of the genus by the skeletal structure. Scalarispongia viridis n. sp. has regular ladder-like skeletal pattern arranged throughout the sponge body and has pseudo-tertiary fibres. Scalarispongia favus n. sp. is characterized by the honeycomb shape of the surface and is similar to Sc. flava in skeletal structure, but differs in sponge shape. Scalarispongia lenis n. sp. is similar to Sc. regularis in skeletal structure but has fibers that are smaller in size. Scalarispongia canus n. sp. has irregular skeletal structure in three dimensions and ladder-like which comes out of the surface and choanosome. Scalarispongia subjiensis n. sp. has pseudo-tertiary fibres and its regular ladder-like skeletal pattern occurs at the choanosome. Two new species of Smenospongia are distinguished from the other 19 reported species of the genus by the skeletal structure. Smenospongia aspera n. sp. is similar to Sm. coreana in sponge shape but new species has rarely secondary web and thin and thick bridged fibres at near surface. Smenospongia mureungensis n. sp. has very simple skeletal structure.

Amazonocrinis thailandica sp. nov. (Nostocales, Cyanobacteria), a novel species of the previously monotypic Amazonocrinis genus from Thailand

  • Tawong, Wittaya;Pongcharoen, Pongsanat;Pongpadung, Piyawat;Ponza, Supat;Saijuntha, Weerachai
    • ALGAE
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    • v.37 no.1
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    • pp.1-14
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    • 2022
  • Cyanobacteria are distributed worldwide, and many new cyanobacterial species are discovered in tropical region. The Nostoc-like genus Amazonocrinis has been separated from the genus Nostoc based on polyphasic methods. However, species diversity within this genus remains poorly understood systematically because only one species (Amazonocrinis nigriterrae) has been described. In this study, two novel strains (NUACC02 and NUACC03) were isolated from moist rice field soil in Thailand. These two strains were characterized using a polyphasic approach, based on morphology, 16S rRNA phylogenetic analysis, internal transcribed spacer secondary structure and ecology. Phylogenetic analyses based on 16S rRNA gene sequences confirmed that the two novel strains formed a monophyletic clade related to the genus Amazonocrinis and were distant from the type species A. nigriterrae. The 16S rRNA gene sequence similarity (<98.1%) between novel strains and all other closely related taxa including the Amazonocrinis members exceeded the cutoff for species delimitation in bacteriology, reinforcing the presence of a new Amazonocrinis species. Furthermore, the novel strains possessed unique phenotypic characteristics such as the presence of the sheath, necridia-like cells, larger cell dimension and akinete cell arrangement in long-chains and the singularity of D1-D1', Box-B, V2, and V3 secondary structures that distinguished them from other Amazonocrinis members. Considering all the results, we described our two strains as Amazonocrinis thailandica sp. nov. in accordance with the International Code of Nomenclature for Algae, Fungi and Plants.

Secalonic acid D; A Cytotoxic Constituent from Marine Lichen-derived Fungus Gliocladium sp. T31

  • Ren, Hong;Tian, Li;Gu, Qianqun;Zhu, Weiming
    • Archives of Pharmacal Research
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    • v.29 no.1
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    • pp.59-63
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    • 2006
  • Secalonic acid D(SAD) was isolated as the major secondary metabolite of the marine lichen-derived fungus Gliocladium sp. T31. Its structure was established on the basic of physicochemical and spectroscopic data. This is the first report on the isolation of SAD from this fungus, as well as its inhibitory effect on K562 cell cycle and its cytotoxicity against several tumor cell lines in vitro.

A highly efficient computational discrimination among Streptococcal species of periodontitis patients using 16S rRNA amplicons

  • Al-Dabbagh, Nebras N.;Hashim, Hayder O.;Al-Shuhaib, Mohammed Baqur S.
    • Korean Journal of Microbiology
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    • v.55 no.1
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    • pp.1-8
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    • 2019
  • Due to the major role played by several species of Streptococcus in the etiology of periodontitis, it is important to assess the pattern of Streptococcus pathogenic pathways within the infected subgingival pockets using a bacterial specific 16S rRNA fragment. From the total of 50 patients with periodontitis included in the study, only 23 Streptococcal isolates were considered for further analyses, in which their 16S rRNA fragments were amplified and sequenced. Then, a comprehensive phylogenetic tree was constructed and in silico prediction was performed for the observed Streptococcal species. The phylogenetic analysis of the subgingival Streptococcal species revealed a high discrimination power of the 16S rRNA fragment to accurately identify three groups of Streptococcus on the species level, including S. salivarius (14 isolates), S. anginosus (5 isolates), and S. gordonii (4 isolates). The employment of state-of-art in silico tools indicated that each Streptococcal species group was characterized with particular transcription factors that bound exclusively with a different 16S rRNA-based secondary structure. In conclusion, the observed data of the present study provided in-depth insights into the mechanism of each Streptococcal species in its pathogenesis, which differ in each observed group, according to the differences in the 16S rRNA secondary structure it takes, and the consequent binding with its corresponding transcription factors. This study paves the way for further interventions of the in silico prediction, with the main conventional in vitro microbiota identification to present an interesting insight in terms of the gene expression pattern and the signaling pathway that each pathogenic species follows in the infected subgingival site.

A Study on Teaching of the Elements of Geometry in Secondary School (중학교 기하 교재의 '원론' 교육적 고찰)

  • Woo Jeong-Ho;Kwon Seok-Il
    • Journal of Educational Research in Mathematics
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    • v.16 no.1
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    • pp.1-23
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    • 2006
  • It is regarded as critical to analyse and re-appreciate Euclidean geometry for the sake of improving school geometry This study, a critical analysis of demonstrative plane geometry in current secondary school mathematics with an eye to the viewpoints of 'Elements of Geometry', is conducted with this purpose in mind. Firstly, the 'Elements' is analysed in terms of its educational purpose, concrete contents and approaching method, with a review of the history of its teaching. Secondly, the 'Elemens de Geometrie' by Clairaut and the 'histo-genetic approach' in teaching geometry, mainly the one proposed by Branford, are analysed. Thirdly, the basic assumption, contents and structure of the current textbooks taught in secondary schools are analysed according to the hypothetical construction, ordering and grouping of theorems, presentations of proofs, statements of definitions and exercises. The change of the development of contents over time is also reviewed, with a focus on the proportional relations of geometric figures. Lastly, tile complementary way of integrating the two 'Elements' is explored.

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The Effect of Current and Preheat Temperature on Structure and Hardness of Stellite 12 Alloy Overlayer by PTA Process (PTA법에 의한 스텔라이트 12 합금 육성층의 조직과 경도에 미치는 전류와 예열온도의 영향)

  • Jung, B.H.;Kim, M.G.;Kim, G.D.;Kim, M.Y.;Lee, S.Y.
    • Journal of the Korean Society for Heat Treatment
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    • v.13 no.4
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    • pp.246-252
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    • 2000
  • Stellite 12 alloy-powder was overlaid on 410 stainless steel valve seat using plasma transferred arc(PTA) process. Variation of characteristic of microstructure and hardness of deposit with current(90~150 A) and preheat temperature(R.T.~$400^{\circ}C$) was investigated. Important conclusion obtained are as follows; All welding conditions used produced a sound deposit layer with no defect in single pass welding. The maximum deposit had 4.0~4.8 mm in thickness and its bead width was increased with increase of current and preheat temperature. The deposit showed hypoeutectic microstruture, which was consisting of primary cobalt dendrite and networked $M_7C_3$ type eutectic carbides. The amount of eutectic carbides was decreased and its dendritic secondary arm spacing was increased with increase of current. Hardness of the deposit was decreased with increase of current. Preheat temperature up to $400^{\circ}C$, however, showed little influence on the hardness and microstructure. The hardness was also influenced by diluted Fe content near the interface in addition to microstructure and dendritic secondary arm spacing. Hot hardness at $500^{\circ}C$ showed higher than 300 HV.

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Homology Modeling and Molecular Docking Study of Translationally Controlled Tumor Protein and Artemisinin

  • Chae, Jin-Sun;Choi, In-Hee;Kim, Choon-Mi
    • Archives of Pharmacal Research
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    • v.29 no.1
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    • pp.50-58
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    • 2006
  • Translationally controlled tumor protein (TCTP), also known as histamine releasing factor (HRF), is found abundantly in different eukaryotic cell types. The sequence homology of TCTP between different species is very high, belonging to the MSS4/DSS4 superfamily of proteins. TCTP is involved in both cell growth and human late allergy reaction, as well as having a calcium binding property; however, its primary biological functions remain to be clearly elucidated. In regard to many possible functions, the TCTP of Plasmodium falciparum (Pf) is known to bind with an antimalarial agent, artemisinin, which is activated by heme. It is assumed that the endoperoxide-bridge of artemisinin is opened up by heme to form a free radical, which then eventually alkylates, probably to the Cys14 of PfTCTP. Study of the docking of artemisinin with heme, and subsequently with PfTCTP, was carried out to verify the above hypothesis on the basis of structural interactions. The three dimensional (3D) structure of PfTCTP was built by homology modeling, using the NMR structure of the TCTP of Schizosaccharomyces pombe as a template. The quality of the model was examined based on its secondary structure and biological function, as well as with the use of structure evaluating programs. The interactions between artemisinin, heme and PfTCTP were then studied using the docking program, FlexiDock. The center of the peroxide bond of artemisinin and the Fe of heme were docked within a short distance of $2.6{\AA}$, implying the strong possibility of an interaction between the two molecules, as proposed. When the activated form of artemisinin was docked on the PfTCTP, the C4-radical of the drug faced towards the sulfur of Cys14 within a distance of $2.48{\AA}$, again suggesting the possibility of alkylation having occurred. These results confirm the proposed mechanism of the antimalarial effect of artemisinin, which will provide a reliable method for establishing the mechanism of its biological activity using a molecular modeling study.

An Overview of Chemically/Surface Modified Cubic Spinel LiMn2O4 Electrode for Rechargeable Lithium Batteries

  • Jung, Kyu-Nam;Pyun, Su-Il
    • Journal of the Korean Electrochemical Society
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    • v.9 no.4
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    • pp.158-169
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    • 2006
  • The present article is concerned with the overview of the chemically/surface modified cubic spinel $LiMn_2O_4$ as a cathode electrode far lithium ion secondary batteries. Firstly, this article presented a comprehensive survey of the cubic spinel structure and its correlated electrochemical behaviour of $LiMn_2O_4$. Subsequently, the various kinds of the chemically/surface modified $LiMn_2O_4$ and their electrochemical characteristics were discussed in detail. Finally, this article reviewed our recent research works published on the mechanism of lithium transport through the chemically/surface modified $Li_{1-\delta}Mn_2O_4$ electrode from the kinetic view point by the analyses of the experimental potentiostatic current transients and ac-impedance spectra.