• 제목/요약/키워드: secondary ions

검색결과 225건 처리시간 0.027초

Flavobacterium odoratum의 TOL 플라스미드를 전달받은 광합성세균으로부터의 수소 생성 ($H_{2}$ production of photosynthetic bacteria transferred TOL plasmid from flavobacterium odoratum)

  • 오순옥;조인성;이희경;민경희
    • 미생물학회지
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    • 제29권6호
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    • pp.408-415
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    • 1991
  • TOL plsmid size of Flavobacterium odoratum SUB53 was estimated as 83 Md and the optimum concentration of m-toluate degradation by TOL plasmid was 5 mM. $H_{2}$ production by Rhodopseudomonas sphaeroides KCTC1425 was largely dependent on nitrogenase activity and showed the highest at 30 mM malate with 7 mM glutamate as nitrogen source. Nitrogenase activities were inhibited by 0.3 mM $NH_{4}^{+}$ions, to be appeared the decrease of $H_{2}$ production. Conjugation of TOL plasmids from F. odoratum SUB53 and Pseudomonas putida mt-2 to R. sphaeroides showed the optimum at the exponential stage of recipient cells in presence of helper plasmid pRK2013. According to the investigation of catechol-1,2-oxygenase (C-1, 2-O) and catechol-2,3-oxygenase (C-2,3-O) activities of R. sphaeroides C1 (TOL SUB53) and C2 (TOL mt-2), the gene for C-2,3-O is located on TOL plasmid and gene for C-1, 2-O on the chromosome of R. sphaeroides. m-Toluate was biodegraded by TOL plasmid in R. sphaeroides C1 and C2, presumably to be produced $H_{2}$ gas from the secondary metabolites of m-toluate.e.

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페놀수지로부터 유도된 Boron을 Doping한 polyacene계 부극의 특성 (Anode Properties of Boron Doped Polyacene Derived from Phenolic Resin)

  • 오원춘;박승혁;김범수
    • 분석과학
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    • 제13권6호
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    • pp.705-711
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    • 2000
  • 리튬 이차전지용 부극 재료로 페놀 수지로 부터 유도된 boron을 doping한 polyacene에 구조적 특성, 표면 특성 및 전기적 특성을 연구하였다. Polyacene탄소질에 boron의 함유량을 각각 5%, 10%, 15%, 20% 첨가하여 특성화하였다. X-선 회절 결과에 따르면, 이들 시료들은 대표적인 무정형 탄소의 회절형태를 나타내었다. 표면 상태는 반구형의 표면상태를 가지고 있음을 SEM 결과로부터 알 수 있었다. 전지의 이온과 전자전달효과를 알아보기 위한 전기 화학적 충전/방전 특성과 임피던스 측정의 결과에 의하면, 10%와 15% boron이 첨가된 시료는 다소 우수한 특성을 나타내고 있다.

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Electrochemical Performances of the Fluorine-Substituted on the 0.3Li2MnO3·0.7LiMn0.60Ni0.25Co0.15O2 Cathode Material

  • Kim, Seon-Min;Jin, Bong-Soo;Park, Gum-Jae;Kim, Hyun-Soo
    • Journal of Electrochemical Science and Technology
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    • 제5권3호
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    • pp.87-93
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    • 2014
  • The fluorine-substituted $0.3Li_2MnO_3{\cdot}0.7Li[Mn_{0.60}Ni_{0.25}Co_{0.15}]O_{2-x}F_x$ cathode materials were synthesized by using the transition metal precursor, $LiOH{\cdot}H_2O$ and LiF. This was to facilitate the movement of lithium ions by forming more compact SEI layer and to reduce the dissolution of transition metals. The $0.3Li_2MnO_3{\cdot}0.7Li[Mn_{0.60}Ni_{0.25}Co_{0.15}]O_{2-x}F_x$ cathode material was sphere-shaped and each secondary particle had $10{\sim}15{\mu}m$ in size. The fluorine-substituted cathodes initially delivered low discharge capacity, but it gradually increased until 50th charge-discharge cycles. These results indicated that fluorine substitution gave positive effects on the structural stabilization and resistance reduction in materials.

냉음극형 대면적 전자빔의 공간적 분포 특성 (Characteristics of spatial distribution of cold cathode type large aperture electron beam)

  • 우성훈;;조주현;김광훈;이홍식;임근희;이광식
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 1999년도 하계학술대회 논문집 E
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    • pp.2170-2172
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    • 1999
  • A low energy large aperture(LELA) pulsed electron beam generator of a cold cathode type has been developed for environmental applications, for example, waste water cleaning, flue gas cleaning, and pasteurization etc. The operational principle is based on the emission of secondary electrons from cold cathode when ions in the plasma hit the cathode, which are accelerated toward exit window by the gradient of an electric potential. We have fabricated the LELA electron beam generator with the peak energy of 200keV and beam diameter of 200mm and obtained the large aperture electron beam in air. The electron beam current density has been investigated as a function of glow discharge current, accelerating voltage and radial distribution in front of the exit window foil. The plasma density and electron temperature have been measured in order to confirm the relation with the electron beam current density. We are going to upgrade the LELA electron beam generator in the electron energy, electron beam current and stability of operation for various applications.

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저에너지 대면적 전자빔 발생장치 개발(II) (A Development of the Low Energy Large Aperture Electron Beam Generator)

  • 우성훈;이광식;이동인;조주현;최영욱;이홍식
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 1998년도 하계학술대회 논문집 E
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    • pp.1767-1769
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    • 1998
  • We have established a pulsed electron beam generation system with an energy of 200[keV], pulse repetition rate of 200[Hz], and several tens of [${\mu}s$] pulse width. The system is characterized by a cold cathode that is simpler than the hot cathode. Target object does not need to be scanned because of large aperture electron beam of 300[$cm^2$]. Electron source is secondary electrons that are generated when the ions from the glow discharge collide on the cathode surface. In this paper, the discharge current characteristics are investigated experimentally as a function of He gas pressure in order to obtain stable glow discharge. And computer simulations are carried out as a preliminary study for the development of low energy large aperture electron beam generator. The variation of electon beam current is investigated as a function of rising time of high voltage when 20[kV] potential is applied in 20[mTorr] pressure.

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실리카겔에 담지된 4급암모늄염 유도체의 합성 및 이온교환 특성 (Preparation of Quaternary Ammonium Salt Derivatives Supported on Silica gel and Its Ion Exchange Characteristics)

  • 안범수
    • 한국응용과학기술학회지
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    • 제25권1호
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    • pp.65-72
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    • 2008
  • The ion exchangers supported on silica gel containing primary, secondary, or tertiary amine groups show a behaviour that is weakly acidic, while the quaternary salts are strongly acidic. These properties change according to the hydrophilicities of the modifier functional groups. Ammonium salt derivatives supported on silica gel were prepared from silica modified with 3-Aminopropyltriethoxysiliane and N-3-(Trimethoxysilyl)propylehtylene diamine. The preparation and the ion exchange properties of two systems were discussed. Two systems have different hydrophilicities and contain ammonium chloride derivatives of 3-amminopropyltriethoxysilane and N-3-(triehtoxysilyl)propyl ethylene diamine supported on silica gel, $SA^+/Cl^-$ and $SA^+/Cl^-$, respectively. The high affinity to perchlorate ion presented by the $SA^+/Cl^-$ through the equilibrium studies of ion exchange led us to its application as an ion selective electrode for the perchlorate ion. The determination of the perchlorate ion in the presence of other anions and in complexes is very difficult. Few analytical methods are available and most of them are indirect. Both materials showed potential use as an ion exchanger; they are thermically stable, achieve equilibrium rapidly in the presence of suitable exchanger ions, and are easily recovered.

두 번째 Ag 층을 적용한 Ag/$Ge_1Se_1Te_2$ 물질의 광학적 특성 연구 (Optical properties of Ag/$Ge_1Se_1Te_2$ material with secondary Ag layer adoption)

  • 김현구;한송이;김재훈;구상모;정홍배
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2008년도 하계학술대회 논문집 Vol.9
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    • pp.191-192
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    • 2008
  • For phase transition method, good record sensitivity, low heat radiation, fast crystallization and hi-resolution are essential. Also, a retention time is very important part for phase-transition. In our past papers, we chose composition of $Ge_1Se_1Te_2$ material to use a Se factor which has good optical sensitivity than conventional Sb. Ge-Se-Te and Ag/$Ge_1Se_1Te_2$ samples are fabricated and irradiated with He-Ne laser and DPSS laser to investigate a reversible phase change by light. Because of Ag ions, the Ag layer inserted sample showed better performance than conventional one. We should note that this novel one showed another possibility for phase-change random access memory.

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Floating Zone법에 의한 YIG단결정 성장 (YIG(Yttrium Iron Garnet) SingLe Crystal Growth by Floating Zone Method)

  • 신재혁;김범석;오근호
    • 한국결정성장학회지
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    • 제2권2호
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    • pp.1-1
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    • 1992
  • YIG는 분해용융을 하므로 FZ법을 개량한 TSFZ법을 적용하여 YIG단결정을 성장시켰다. 최적성장조건은 성장속도 1mm/hr, 상호역방향 회전속도 30rpm이었으며 소결 및 결정성장시 산화분위기를 필요로 하였고 성장된 결정의 질은 소결정도에 의해 많은 영향을 받았다. Melt내 기포의 생성은 철이온과 산소와의 반응에 의해 발생되었으며 기포의 밀도는 성장속도가 빨라질수록 증가하였다. 성장속도는 1mm/hr 이상일 경우에는 Cell Growth가 발생하였으며 결정의 가장자리에서 전위밀도가 증가하였다. 또한 성장된 결정에서는 제2상으로 Orthoferrite가 관찰되었다.

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가공제품에 대한 생활주변방사선 실태조사 자료를 활용한 통계분석 (Statistical Analysis Using Living Radiation Survey Data on Processed Products)

  • 최경호;조정근
    • 대한방사선기술학회지:방사선기술과학
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    • 제43권2호
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    • pp.123-128
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    • 2020
  • Radiation Following the 2011 Fukushima nuclear accident in Japan, public interest and anxiety about radiation safety increased, and vague anxiety about commonly exposed living radiation was generated. The Atomic Energy Safety Commission has been conducting a survey of processed products that advertise "negative ions" and "far-infrared" emissions under the Living Radiation Safety Management Act. In this study, in-depth analysis was performed from a statistical point of view using the measurement data presented in the Nuclear Safety Committee's actual survey analysis report as secondary data. As a result, there was a statistically significant difference (p<0.005) between latex and civil affairs products. There were also statistically significant differences (p<0.05) in the results of testing whether there were significant differences in the annual exposure dose between groups after categorizing 71 civil products, including radon beds, into bed, bedding, and living and other categories. The correlation analysis results also confirm that, as is commonly known, the annual doses received from processed products are associated with radon derived from U-238 and Th-232.

제주시 지역 미세먼지의 변동과 화학적 구성 특성 (Chemical Mass Composition of Ambient Aerosol over Jeju City)

  • 이기호;김수미;김길성;허철구
    • 한국환경과학회지
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    • 제29권5호
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    • pp.495-506
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    • 2020
  • This study investigated the nitrate formation process, and mass closure of Particulate Matter (PM) were calculated over the urbanized area of Jeju Island. The data for eight water-soluble inorganic ions and nineteen elements in PM2.5 and PM10 were used. The results show that the nitrate concentration increased as excess ammonium increased in ammonium-rich samples. Furthermore, nitrate formation was not as important in ammonium-poor samples as it was in previous studies. According to the sum of the measured species, approximately 45~53% of gravimetric mass of PM remained unidentified. To calculate the mass closure for both PM2.5 and PM10, PM chemical components were categorized into secondary inorganic aerosol, crustal matter, sea salt, trace matter and unidentified matter. The results by the mass reconstruction of PM components show that the portion of unidentified matter was decreased from 52.7% to 44.0% in PM2.5 and from 45.1% to 29.1% in PM10, despite the exclusion of organic matter and elemental carbon.