• Proceedings of the KWS Conference
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• 2009.11a
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• pp.78-78
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• 2009

Glass sealing method is used glass bond as called frit in LCD, PDP process. but new sealing method is need to consider the endurance and economy. This paper present the new glass sealing method using high density gas torch in the furnace and process variable are defined by experiment. Taguchi Robust Experimental Design methods were applied for optimizing these four main processing parameters.

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
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• v.29 no.8
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• pp.489-493
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• 2016

In this study, the effect of vanadium oxide ($V_2O_5$) content and pre-sintering atmosphere on sealing property of glass frit that consisted of $V_2O_5-BaO-ZnO-P_2O_5-TeO_2-CuO-Fe_2O_3-SeO_2$ was investigated by XPS (X-ray photoelectron spectroscopy). The content of V2O5 was changed to 15, 30, and 45 mol%, and the pre-sintering was carried out in air and $N_2$ condition, respectively. XPS analysis conducted before and after laser irradiation with identical sample. Before laser treatment, glass frits that were pre-sintered at air condition showed both $V^{4+}$ and $V^{5+}$, but the valence state was changed to $V^{5+}$ after laser irradiation when the glass frits contained 30 and 45 mol% $V_2O_5$; this change led to non-adhesive property. On the other hand, glass frits that were pre-sintered at $N_2$ condition exhibited only $V^{4+}$ and it showed fine adhesion irrespective of the $V_2O_5$ content. As a result, the existence of $V^{4+}$ seems to be a major factor for controlling the adhesive property of glass frit for laser sealing.

• Transactions of the Korean Society of Mechanical Engineers A
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• v.25 no.12
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• pp.1988-1994
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• 2001

The CRT(Cathode-ray Tube) of salvage is a process of separating the panel and funnel to recycle a cathode-ray tube. In this paper, the thermal properties of glass for CRT were studied to improve its recycling ratio. In the salvage process, several patterns of breakage, as called 'comer pull', were easily generated on the sealing surface of panel or funnel glass due to the residual tensile stress, which had correlations with some parameters of the manufacturing process of CRT and the initial material properties of glass. Finite element analyses and experimental approaches on the flit sealing process were carried out to obtain the major characteristic of glass related to the residual stress. From this study, it was identified that the thermal expansion coefficient of glass had much influence on the residual stress of panel glass after frit sealing process. Therefore, the optimal conditions of thermal properties for CRT glass were proposed to achieve an effective salvage process. By using these optimal conditions, the size of comer pull on the panel and funnel glass was reduced to 10% level compared with the original size, and the recycling ratio of CRT was increased in the salvage process.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.13 no.3
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• pp.961-966
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• 2012

The concern about vacuum glass is enhanced as society gets greener and becomes more concerned about energy savings due to the rising cost of oil. The glass edge sealing process needs the high reliability among the main process for the vacuum glass development in order to maintain between the two glass by the vacuum. In this paper, the process of the edge sealing was performed by using the hydrogen mixture gas which is the high density heat source unlike the traditional method glass edge sealing by using the frit as the soldering process. The ambient temperature in the electric furnace was set in the edge sealing to prevents the thermal impact and transformation of the glasses and the temperature distribution uniformity was measured. The parameter of the edge sealing was set through the basic test and the mathematical relation with the area of the glass edge parts according to the parameter was drawn using the multiple regression analysis method.

• Korean Journal of Materials Research
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• v.26 no.10
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• pp.549-555
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• 2016

We have investigated a glass-forming region of $V_2O_5-P_2O_5-ZnO$ glass and the effects of the addition of modifier oxides ($B_2O_3$) to the glass systems as a sealing material to improve the adhesion between the glass frits and a soda lime substrate. Thermal properties and coefficient of thermal expansion were measured using a differential scanning calorimetry, a dilatometer and a hot stage microscopy. Structural changes and interfacial reactions between the glass substrate and the glass frit after sintering (at $400^{\circ}C$ for 1 h) were measured by Fourier transform infrared spectroscopy, X-ray photoelectron spectroscopy and scanning electron microscope. The results showed that the adhesion strength increases as the content of $B_2O_3$ at 5 mol% increases because of changes in the structural properties. It seems that the glass structures change with $B_2O_3$, and the $Si^{4+}$ ions from the substrate are diffused to the sealing glass. From these results, we could understand the mechanism of strengthening of the adhesion of soda lime silica substrate by ion-diffusion from the substrate to the glass.

• Proceedings of the Materials Research Society of Korea Conference
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• 2011.10a
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• pp.33.2-33.2
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• 2011

고온형 SOFC의 개발에 있어 스택의 신뢰성을 확보하는데 가장 중요한 핵심기술은 스택 구성요소 사이를 접합하는데 필요한 고온형 밀봉재의 개발이다. SOFC 스택에서의 밀봉재는 고체전해질과 접속자 사이에서 음극에 공급되는 연료가스와 양극에 공급되는 공기가 서로 혼합되는 것을 방지하는 역할은 물론 기계적으로 취약한 단전지의 보호 및 스택전체 구조물의 구조적 일체성(Structural integrity)을 부여하는데 주목적이 있다. 현재 기체 기밀성을 유지하기 위한 밀봉재는 크게 유리 및 결정화 유리계, mica및 mica/유리복합재료, 유리/충전재 복합재료 등이 사용되고 있으나 다수의 단위전지로 구성되는 스택 구성에서 스택의 열기계적 안정성 및 장기수명을 보장하기 위해서는 본 연구에서 개발하고자 하는 복합밀봉재가 가장 적합할 것으로 예상되고 있다. 본 연구에서는 $SiO_2-B_2O_3-RO$계에 BaO, SrO를 일정비율로 첨가하여 제작된 유리 frit을 열처리하여 물리화학적 물성변화를 검토하였으며, $700^{\circ}C$ 이하의 연화점을 갖는 유리를 기지상으로 하고 세라믹 보강재를 첨가한 고온형 복합밀봉재를 개발하고 그 물리화학적 안정성, 열기계적 안정성 및 밀봉 특성을 평가하였다.

• Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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• v.23 no.5
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• pp.29-35
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• 2009

Field emission displays(FED) are currently being study as a potential flat technology. The purpose of this project shows the research result of vacuum packaging technology for the development of FED. For FED vacuum packaging, the bonding of glass/glass, the exhaust of vacuum and getter technology have been studied for vacuum packaging technology The simulation and vacuum sealing, and glass/glass bonding are also extensively studied. The glass/glass bonding is formed by using the frit glass and the Inside pressure of complete panel showed of $2{\times}10^{-5}$[Torr]. As a getter result, the increase of pressure has been showed the decrease of outgassing effect by using thin film getter.

• 한국정보디스플레이학회:학술대회논문집
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• 2007.08b
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• pp.1519-1521
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• 2007

In this work, a coplanar-type plasma flat fluorescent lamp having cross type of electrode was fabricated by screen printing and sealing technique. Cross type of electrode with a dielectric layer were screen-printed on a rear glass plate, and then fired at $550^{\circ}C$. Phosphor was printed on and fired at $450^{\circ}C$. Finally, the lamp was sealed by frit glass at $450^{\circ}C$. The lamp of cross electrode type was studied depending on the electrode gap and the thickness of dielectric layer.

• Journal of the Korean Ceramic Society
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• v.48 no.1
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• pp.63-68
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• 2011

The investigation is directed to lead free (Pb-free) frits that can be used for organic light emitting diode, plasma display screen devices and other sealing materials. $P_2O_5$-SnO system glasses have been prepared for Pb-free low temperature glass frit. Structure and properties of the glasses with the composition SnO-$xB_2O_3-(60-x)P_2O_5$ (x=0, 5, 10, 15, 20, 25, 30, 35, 40 mol%) were characterized by infrared spectra (IR), X-ray diffraction(XRD), Density, Molar volume, Thermo mechanical analysis(TMA) and weight loss after immersion test. Glass transition temperature($T_g$), dilatometric softening temperature($T_d$) and chemical durability increased, and coefficient of thermal expansion($\alpha$) decrease with the substitution of $B_2O_3$ for $P_2O_5$ in the range of 0~25 mol%.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2007.06a
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• pp.431-432
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• 2007

In this study, we used screen printing on the rear glass with silver electrodes, phosphor and a dielectric which is on the silver electrodes, and carried out firing in the temperature of $550^{\circ}C$, $570^{\circ}C$, $450^{\circ}C$ each. To seal the rear and top glass together, we used crystalline frit paste as a sealing material with dispenser and carried out firing up to $450^{\circ}C$. As using this panel, we focused on optimizing the condition which influences characteristics of discharging by the distance between electrodes, electrode structure, type and pressure of gases for FFL.