• 제목/요약/키워드: scraps

검색결과 143건 처리시간 0.026초

MoO3 침출공정 폐액으로부터 동분말의 회수기술 (Recovery of Copper Powder from MoO3 Leaching Solution)

  • 홍현선;정항철;김건홍;공만식
    • 한국분말재료학회지
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    • 제16권5호
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    • pp.351-357
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    • 2009
  • A two-step recovery method was developed to produce copper powders from copper chloride waste solution as byproducts of MoO$_3$ leaching process. The first step consisted of replacing noble copper ions with external Fe$^{3+}$ ions which were formed by dissolving iron scraps in the copper chloride waste solution. The replaced copper ions were subsequently precipitated as copper powders. The second step was cementation of entire solution mixture to separate (pure) copper powders from aqueous solution of iron chloride. Cementation process variables of temperature, time, and added amount of iron scraps were optimized by using design of experiment method and individual effects on yield and efficiency of copper powder recovery were investigated. Copper powders thus obtained from cementation process were further characterized using various analytical tools such as XRD, SEM-EDS and laser diffraction and scattering methods.Cementation process necessitated further purification of recovered copper powders and centrifugal separation method was employed, which successfully yielded copper powders of more than 99% purity and average 1$\sim$2$\mu$m in size.

주철의 재질에 미치는 각종 Steel scrap의 영향 (Effect of Various Steel Scrap on the Microstructures and Mechanical Properties of Ductile Cast Iron)

  • 김홍범;;한용남;곽희환;이종문;김찬규
    • 자원리싸이클링
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    • 제9권1호
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    • pp.15-20
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    • 2000
  • Zn을 많이 함유하는 銅scrap(자동차용강판, Zn표면처리강판 등)을 이용하여 구상흑연주철을 제조한 경우 구상화가 제대로 이루어 지지 않았다. Sb을 많이 함유하는 銅scrap을 이용하여 구상흑연주칠을 제조한 경우에는 기지 층의 퍼얼라이트량이 증가하였다. 퍼얼라이트량이 증가하면 인장강도 및 경도는 증가하지만 연산율은 감소하였다. Mn, Cr을 많이 함유한 銅scrap(기계구조용강판, 가단주철)을 이용하여 구상흑연주출을 제조한 경우에는 피얼라이트량이 증가하였으며, 인장강도 및 경도도 증가하였다.

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광학용 사출성형품에 사용되는 고유동성 폴리카보네이트의 재사용에 따른 광학적, 기계적 물성 변화에 대한 연구 (A Study on the Change of Optical and Mechanical Properties by Reprocessing for High Melt-Indexed Polycarbonate Used in Injection Molded Optical Parts)

  • 이준한;강정진;윤경환;김종선
    • 소성∙가공
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    • 제27권4호
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    • pp.211-221
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    • 2018
  • To estimate the recycling feasibility of high melt-indexed polycarbonate, 3.5 inch LGP, tensile, flexural and impact specimens were injection-molded and the LGP was shredded into scraps. The scraps were injection-molded again and this process was repeated for 4 times. Properties of the sample, i.e., optical properties, mechanical properties and number average molecular weight were measured at each cycle. Based on the results, as the number of reprocessing increased, transmittance decreased at low wavelength and color coordinate was changed systematically to yellow. Yellow index increased more than twofold during 4 recycling processes. On the other hand, the number average molecular weight decreased during recycling processes. Flexural and impact strength showed no tendency according to the number of recycling, but tensile strength decreased sharply after the third recycling process. Based on these properties, it was concluded that the number of recycling for high melt-indexed polycarbonate allowed in this study was one.

알루미늄 호일 스크랩의 볼밀링 (Ball Milling of Aluminum Foil Scrap)

  • 홍성현;김병기
    • 연구논문집
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    • 통권29호
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    • pp.131-139
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    • 1999
  • The effect of ball milling conditions in the milling of aluminium foil scraps was studied. Initial foil thickness, ball size. content of oleic acid. weight ratio of mineral spirits/foil. charged amount of foil were varied in wet ball milling process. It is impossible to make flake powders by milling of foil scraps with thickness $120 \mum$. As foil thickness decreases from $60\mum$ to $6.5\mum$, Mean size of powder milled for 30 h decreases from 107 µm to 17 µm. Bigger ball is slightly beneficial for milling of foils to the flake powders due to the larger impact energy produced by them. It is impossible to mill the foil without oleic acid to fabricate the flake powder. As content of oleic acid increases from 1.5 % to 5 %, mean size of flake powder milled for 30 h is drastically decreased. For the mineral spirits content below 50 %, foil scrap was not milled because sliding motion of balls by lubricant effect between balls and wall of container. As weight ratio of mineral spirits and foil increase over 100 %, foils were milled powders with mean powder size 15 - 20 때 irrespective of mineral spirits content due to reduced lubricant effect. As charged amount of foil decreases, mean powder size decreases due to increased collision frequency between ball and foil.

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알루미늄 캔 스크랩의 고품위 재활용을 위한 발포금속의 제조 (Fabrication of Aluminum Foams for High Profit Recycling of Aluminum Can Scraps)

  • 하원;김세광;김영직
    • 한국주조공학회지
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    • 제25권5호
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    • pp.203-208
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    • 2005
  • The main emphasis of this study is to optimize the process variables for manufacturing aluminum foam materials by direct foaming of remelted aluminum scraps. Aluminum foams were fabricated from two different raw materials, pure aluminum and used beverage cans. For both cases, $TiH_{2}$ was used as a foaming agent. Calcium was added as a thickener for the foaming of pure aluminum and no thickener was added for that of used beverage Cans because the pre-existing oxides of the used beverage cans are used as a thickener. Calcium and $TiH_{2}$ content varies from 0.5wt.% to 2.0wt.% and from 0.5wt.% to 1.5wt.%, respectively. The processing conditions, such as the effect of calcium on the melt viscosity, foaming temperature, and the optimum amount of the foaming agent with regard to the melt viscosity were discussed.

MOCVD 공정 중 발생한 GaN 분말 scrap에 대한 대기 산화가 결정조직과 미세조직에 미치는 영향 (Influence of Oxidation Temperatures on the Structure and the Microstructure of GaN MOCVD Scraps)

  • 홍현선;안중우
    • 한국분말재료학회지
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    • 제22권4호
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    • pp.278-282
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    • 2015
  • The GaN-powder scrap generated in the manufacturing process of LED contains significant amounts of gallium. This waste can be an important resource for gallium through recycling of scraps. In the present study, the influence of annealing temperatures on the structural properties of GaN powder was investigated when the waste was recycled through the mechanochemical oxidation process. The annealing temperature varied from $200^{\circ}C$ to $1100^{\circ}C$ and the changes in crystal structure and microstructure were studied. The annealed powder was characterized using various analytical tools such as TGA, XRD, SEM, and XRF. The results indicate that GaN structure was fully changed to $Ga_2O_3$ structure when annealed above $900^{\circ}C$ for 2 h. And, as the annealing temperature increased, crystallinity and particle size were enhanced. The increase in particle size of gallium oxide was possibly promoted by powder-sintering which merged particles to larger than 50 nm.

알루미늄 호일 스크랩 재활용에 의한 플레이크 분말 제조 (Preparation of Aluminum Flake Powder by Recycling of Foil Scrap)

  • 홍성현;김병기
    • 자원리싸이클링
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    • 제9권4호
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    • pp.50-55
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    • 2000
  • 알루미늄 호일 스크랩의 건식 및 습식 볼밀링에 의하여 알루미늄 플레이크 분말을 체조하는 재활용 기술에 대해 여 연구하였다. 볼밀링시 알루미늄 호일 스크랩들은 볼에 의한 미소 단조에 의하여 서로 층상으로 겹쳐지고 연산되면서 작은 호일로 쪼개진 후 플레이크 분말로 변하였다. 이러한 스크랩중에 $60\mu\textrm{m}$ 이하의 호일 스크랩은 볼밀링에 의하여 알루미늄 페이스트로 재활용이 가능하였고 초기 호일의 두께가 작을수록 쉽게 플레이크 분말화가 가능 하였다. 알루미늄 호일 스크랩의 봉밀링에 의하여 얻은 풀레이크 분말을 함유하는 알루미늄 페이스트와 가스 분사된 분말을 초기원료로 사용하여 불밀링한 플레이크 분말을 함유하는 페]이스트를 유리관위에 폐인팅한 후 외관 및 광택도를 비교한 결과, 그 특성은 유사하였다.

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