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Preparation of Nanoflake Bi2MoO6 Photocatalyst Using CO(NH2)2 as Structure Orientation and Its Visible Light Degradation of Tetracycline Hydrochloride

  • Hu, Pengwei;Zheng, Dewen;Xian, Yuxi;Hu, Xianhai;Zhang, Qian;Wang, Shanyu;Li, Mingjun;Cheng, Congliang;Liu, Jin;Wang, Ping
    • Korean Journal of Materials Research
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    • v.31 no.6
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    • pp.325-330
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    • 2021
  • Bi2MoO6 (BMO) via the structure-directing role of CO(NH2)2 is successfully prepared via a facile solvothermal route. The structure, morphology, and photocatalytic performance of the nanoflake BMO are characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), fluorescence spectrum analysis (PL), UV-vis spectroscopy (UV-vis) and electrochemical test. SEM images show that the size of nanoflake BMO is about 50 ~ 200 nm. PL and electrochemical analysis show that the nanoflake BMO has a lower recombination rate of photogenerated carriers than particle BMO. The photocatalytic degradation of tetracycline hydrochloride (TC) by nanoflake BMO under visible light is investigated. The results show that the nanoflake BMO-3 has the highest degradation efficiency under visible light, and the degradation efficiency reached 75 % within 120 min, attributed to the unique hierarchical structure, efficient carrier separation and sufficient free radicals to generate active center synergies. The photocatalytic reaction mechanism of TC degradation on the nanoflake BMO is proposed.

Development of Novel Materials for Reduction of Greenhouse Gases and Environmental Monitoring Through Interface Engineering

  • Hirano, Shin-Ichi;Gang, Seok-Jung L.;Nowotny, Janusz-Nowotny;Smart, Roger-St.C.Smart;Scrrell, Charles-C.Sorrell;Sugihara, Sunao;Taniguchi, Tomihiroi;Yamawaki, Michio;Yoo
    • Korean Journal of Materials Research
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    • v.9 no.6
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    • pp.635-653
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    • 1999
  • The present work considers work considers research strategies to address global warming. Specifically, this work considers the development of technologies of importance for the reduction of greenhouse gas emission and, especially, the materials that are critical to these technologies. It is argued that novel materials that are essential for the production of environmentally friendly energy may be developed through a special kind of engineering: interface engineering, rather than through classical bulk chemistry. Progress on the interface engineering requires to increase the present state of understanding on the local properties of materials interfaces and interfaces processes. This, consequently, requires coordinated international efforts in order to establish a strong background in the science of materials interfaces. This paper considers the impact of interfaces, such as surfaces and grain boundaries, on the functional properties of materials. This work provides evidence that interfaces exhibit outstanding properties that are not displayed by the bulk phase. It is shown that the local interface chemistry and structure and entirely different than those of the bulk phase. In consequence the transport of both charge and matter along and across interfaces, that is so important for energy conversion, is different than that in the bulk. Despite that the thickness of interfaces is of an order to a nanometer, their impact on materials properties is substantial and, in many cases, controlling. This leads to the conclusion that the development of novel materials with desired properties for specific industrial applications will be possible through controlled interface chemistry. Specifically, this will concern materials of importance for energy conversion and environmental monitoring. Therefore, there is a need to increase the present state of understanding of the local properties of materials interfaces and the relationship between interfaces and the functional properties of materials. In order to accomplish this task coordinated international efforts of specialized research centres are required. These efforts are specifically urgent regarding the development of materials of importance for the reduction of greenhouse gases. Success of research in this area depends critically on financial support that can be provided for projects on materials of importance for a sustainable environment, and these must be considered priorities for all of the global economies. The authors of the present work represent an international research group economies. The authors of the present work represent an international research group that has entered into a collaboration on the development of the materials that are critical for the reduction of greenhouse gas emissions.

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NuDE 2.0: A Formal Method-based Software Development, Verification and Safety Analysis Environment for Digital I&Cs in NPPs

  • Kim, Eui-Sub;Lee, Dong-Ah;Jung, Sejin;Yoo, Junbeom;Choi, Jong-Gyun;Lee, Jang-Soo
    • Journal of Computing Science and Engineering
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    • v.11 no.1
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    • pp.9-23
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    • 2017
  • NuDE 2.0 (Nuclear Development Environment 2.0) is a formal-method-based software development, verification and safety analysis environment for safety-critical digital I&Cs implemented with programmable logic controller (PLC) and field-programmable gate array (FPGA). It simultaneously develops PLC/FPGA software implementations from one requirement/design specification and also helps most of the development, verification, and safety analysis to be performed mechanically and in sequence. The NuDE 2.0 now consists of 25 CASE tools and also includes an in-depth solution for indirect commercial off-the-shelf (COTS) software dedication of new FPGA-based digital I&Cs. We expect that the NuDE 2.0 will be widely used as a means of diversifying software design/implementation and model-based software development methodology.

A Research on Development of Transfer Case for Military Special Trucks based the Reverse Engineering (역설계 기반의 군용 특수 트럭용 중간변속기 개발에 관한 연구)

  • Kim, Won-Jae;Moon, Tae-Sang;Yi, Il-Lang;Lee, Jae-Woo;Na, Kyeong-Woon
    • Journal of the Korea Institute of Military Science and Technology
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    • v.22 no.6
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    • pp.754-762
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    • 2019
  • The transfer case for special truck are usually produced by only a few specialized companies. The special technical data are not unveiled. In order to complete the development successfully, it is necessary to carry out the compatibility tests such as the running test on the vehicle, which is the test condition of the military vehicle. In this research, transfer case the core-component of the '230 mm K-MLRS' has been developed with the reverse engineering and the prototype is developed through structural analysis. The transfer case developed through this research is currently used in the '230 mm K-MLRS'. The development process In this research are useful in the development of similar products.

The Development and Application of a External Coating for Buried Pipeline Rehabilitation

  • Zhang, Liping;Lin, Zhu;Zhang, Qibin;Qin, Yanlong;Wang, Xueying
    • Corrosion Science and Technology
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    • v.2 no.3
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    • pp.161-163
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    • 2003
  • With the development of Chinese petroleum and gas industry, about 20,000 km long-distance pipeline and 250,000 km gathering pipeline have been constructed in China. After operating for many years, most of the coatings on buried pipelines have aged so severe that the steel pipes are subject to corrosion environment underground. Focusing on the need of external coating for buried pipeline rehabilitation, a new type of coating has been developed. The development and application of the coatings has been introduced in this paper.

Effect of pulverizing method on the particle size of matured silkworm powder

  • Kim, Su-Bae;Kim, Kee-Young;Ji, Sang-Deok;Kim, Seong-Wan;Kim, Nam-Suk;Jo, You-Young;Kim, Jong-Gil;Kim, Young-Guk;Koo, Hui-Yeon;Moon, Hyung-Chul;Seok, Young-Seek;Lee, Hyun-Tai
    • International Journal of Industrial Entomology and Biomaterials
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    • v.37 no.2
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    • pp.105-108
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    • 2018
  • Recently matured silkworm powder was developed by RDA. In this study, the effect of pulverizing method on the particle size of matured silkworm powder was examined. FESEM was performed to observe the morphology and to measure the particle size of silkworm powder. Particle morphology of air-jet mill pulverized powder was round and smooth, however, those of roller-mill and hammer-mill pulverized mature silkworm was more harsh and square. Particle size was varied with pulverizing technique as follows; $1.1{\mu}m$ (air-jet mill), $10{\mu}m$ (roller mill), and $120{\mu}m$ (hammer mill), respectively. A proximate analysis results of air-jet mill powder showed that crude protein, crude lipid, crude fiber, and ash was 73%, 12%, 1.95%, and 3.4%, respectively. According to our results, air-jet mell technique might be used to make a tiny matured silkworm powder.

A Study on Engineering Education Model for Citizen - Focusing on the Connection Program Between Colleges of Science and Engineering and Science Museums - (시민을 위한 공학교육 모델 개발에 대한 연구 - 이공계 대학과 과학관의 연계 프로그램을 중심으로 -)

  • Han, Hyeontaek;Kim, Seunggyu;Park, Jongrae
    • Journal of Engineering Education Research
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    • v.25 no.3
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    • pp.11-25
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    • 2022
  • The purpose of this study is to propose a strategy model for engineering education for citizen through the connection between colleges of science and engineering and science museums as a way to achieve citizen science. For this model, the role of universities was redefined as social contributions through engineering education from the perspective of knowledge triangle and university entrepreneurship. In addition, the science museum was re-examined as an engineering education platform and selected as an institution that supports the contribution of colleges to society. For practical model development, the connection types of these two institutions were analyzed as case studies and interview to collect opinions from experts in the science museum. In this process, convergence education content development, reinforcement of college-science museum linkage, infrastructure construction, development of college resource utilization plans, and maintenance and expansion of educational programs diversification were derived as components for model development. Based on this, engineering education model for citizen was presented that matches educational programs according to the type of participation of colleges including key factors and considerations.