• 한국재료학회지
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• 제13권5호
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• pp.285-291
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• 2003

The nanosized silver and gold particles are prepared by ERC method in which metal vapors with high temperature is rapidly quenched by coolants such as liquid nitrogen or liquid argon. In order to monitor the crystal structural changes on the internal and the surface of the nanosized noble metal particles, lattice parameter, internal strain and Debye-Waller factor are investigated, and the calculation of X-ray diffraction scattering intensity is performed. The lattice parameters of silver and gold particles agree with those of bulk materials, and crystal internal strain of the metal particles is not changed by rapid cooling. The Debye-Waller factor of gold particles is increased with decreasing particle size because of the surface softening phenomenon of nanosized particles, but the crystal structural change on the surface of the particles is not detected from the comparison the calculated X-ray diffraction profile with the experimental profile on gold particles with the particle size of 4 nm.

• 천문학회보
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• 제10권
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• pp.4.1-4.1
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• 1985

• 한국대기환경학회지
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• 제10권2호
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• pp.137-145
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• 1994

A visibility analysis model based on the Mie theory is applied to the measurements during the fall, 1993 in Seoul. Model estimations of the total extinction coefficient $b_{ext}$, and the particle scattering coefficient, $b_{sp}$ are in good agreement with the measured values by a transmissometer and a nephelometer, respectively. These values show strong dependency on the mass loading of fine particles( $D_{p}$ ＜3.0${\mu}{\textrm}{m}$) but show no apparent relation with that of coarse particles(3.0${\mu}{\textrm}{m}$＜ $D^{p}$ ＜10${\mu}{\textrm}{m}$). Relative humidity plays an important role in determining the size of particles which in turn, affects the optical efficiency of aerosol. Based on the composition analysis with cut size nitrate concentration is higher than the sulfate concentration in PM3-10 but they are comparable to each other in PM3. Considering in 1985, it demonstrates a drastic increase of nitrate concentration between 1985 and 1993. It is found that measured and estimated light extinction budget were in good agreement within 10% and that scattering by particles is responsible for about 50-55% and 70-80 % of total extinction during clear and smoggy periods respectively.y.

• 한국분말재료학회지
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• 제17권3호
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• pp.209-215
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• 2010

Mesoporous alumina particles were prepared by spray pyrolysis using cetyltrimethyl-ammonium bromide (CTAB) as a structure directing agent and the effect of Al precursor types on the texture properties was studied using $N_2$ adsorption isotherms, small-angle X-ray scattering (SAXS), scanning electron microscopy (SEM), and transmission electron microscopy (TEM). The surface area and the microstructure of alumina particles were significantly influenced by the Al precursor type. The largest BET surface area was obtained when Al chloride was used, whereas alumina particles prepared from Al acetate had the largest pore volume. According to small-angle X-ray scattering (SAXS) analysis, the alumina powders prepared using nitrate and acetate precursors had a clear single SAXS peak around $2{\theta}=1.0{\sim}1.5^{\circ}$, indicating that regular mesopores with sponge-like structure were produced. On the basis of TEM, SAXS, and $N_2$ isotherm results, the chloride precursor was most profitable to obtain the largest surface area ($265\;m^2/g$), whereas, the nitrate precursor is useful for the preparation of non-hollow mesoporous alumina with regular pore size, maintaining high surface area (${\sim}233\;m^2/g$).

• 한국화재소방학회논문지
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• 제28권5호
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• pp.64-70
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• 2014

신경망은 연기입자의 광학적 특징으로부터 화원을 분석할 수 있는 유용한 도구가 될 수 있다. UL268에서 연기감지기 시험에 사용되는 세 가지 화원(종이화원, 목재화원, 인화성 액체화원)들의 광학적 특징으로 신경망을 훈련시켰다. 또한, 소광과 산란을 동시에 측정할 수 있는 연기챔버를 제작하여 연기의 광학적 특징을 얻고 그 결과를 신경망에 입력하였다. 종이화원, 목재화원, 인화성 액체화원을 대상으로 한 실험에서 신경망은 화원을 정확하게 구별하였다. 또한, 종이-목재화원, 종이-인화성 액체화원, 목재-인화성 액체화원과 같은 복합화원을 대상으로 한 실험에서도 화원을 모두 구별하였다.

• 한국대기환경학회지
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• 제4권2호
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• pp.28-37
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• 1988

Light scattering coefficient of visible light by atmospheric aerosol over the size range 0.01-10$\mu$m is determined from scattering efficiency and aerosol size distribution. Aerosol number distribution as a function of particle diameter dN/dlog D decreases rapidly as increasing particle size. Distribution of scattering coefficient d$\sigma_s/dlog$ D is mostly accumulated in diameter 0.1-2.0 $\mu$m showing its maximum in the vicinity of 0.6$\mu$m. This means that the visible light in the atmosphere is mainly scattered by these particles. Diurnal variation of scattering coefficient $\sigma_s$ appears its maximum in the morning, while minimum in the afternoon which agrees with the aerosol number distribution in the size range 0.1-2.0 $\mu$m.

• 한국진공학회:학술대회논문집
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• 한국진공학회 2013년도 제44회 동계 정기학술대회 초록집
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• pp.521-521
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• 2013

Collective Thomson scattering (CTS) system is being developed in KAERI based on high power gyrotrons. CTS is a promising diagnostic method to measure fast ion distributions and potentially the fusion product alpha particles in magnetically confined plasmas. By utilizing millimeter-waves from high power gyrotrons as a probing beam, spatially and temporally resolved 1-D ion velocity distributions can be obtained from the scattered radiation with less scattering geometrical constraints. The pulse modulation of gyrotrons enables to separate scattering signal from ECE background noises. The feasibility was assessed with the calculation of spectral density functions under the condition of KSTAR plasmas. Further CTS system requirements are also discussed.

• 분석과학
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• 제32권3호
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• pp.77-87
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• 2019

High viscosity carbon black dispersions are used in various industrial fields such as color cosmetics, rubber, tire, plastic and color filter ink. However, carbon black particles are unstable to heat due to inherent characteristics, and it is very difficult to keep the quality of the product constant due to agglomeration of particles. In general, particle size analysis is performed by dynamic light scattering (DLS) during the dispersion process in order to select the optimum dispersant in the carbon black dispersion process. However, the existing low viscosity analysis provides reproducible particle distribution analysis results, but it is difficult to select the optimum dispersant because it is difficult to analyze the reproducible particle distribution at high viscosity. In this study, dynamic light scattering (DLS) and asymmetrical flow field-flow fractionation (AsFlFFF) analysis methods were compared for reproducible particle size analysis of high viscosity carbon black. First, the stability of carbon black dispersion was investigated by particle size analysis by DLS and AsFlFFF according to milling time, and the validity of analytical method for the selection of the optimum dispersant useful for carbon black dispersion was confirmed. The correlation between color and particle size of particles in high viscosity carbon black dispersion was investigated by using colorimeter. The particle size distribution from AsFlFFF was consistent with the colorimetric results. As a result, the correlation between AsFlFFF and colorimetric results confirmed the possibility of a strong analytical method for determining the appropriate dispersant and milling time in high viscosity carbon black dispersions. In addition, for nanoparticles with relatively broad particle size distributions such as carbon black, AsFlFFF has been found to provide a more accurate particle size distribution than DLS. This is because AsFlFFF, unlike DLS, can analyze each fraction by separating particles by size.

• 한국대기환경학회:학술대회논문집
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• 한국대기환경학회 2003년도 춘계학술대회 논문집
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• pp.355-356
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• 2003

Coagulation is a process whereby particles collide with one another due to their relative motion, and adhere to form large particles. Coagulation caused by the random Brownian motion of particles is called Brownian coagulation. Many properties, such as light scattering, electrostatic charges, toxicity, as well as physical processes, including diffusion, condensation and thermophoresis depend strongly on their size distribution. Therefore, Brownian coagulation is substantially important in atmospheric science, combustion technology, inhalation toxicology and nuclear safety analysis. (omitted)

• Bulletin of the Korean Chemical Society
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• 제33권9호
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• pp.3043-3047
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• 2012

To investigate the scattering layer effect of a $TiO_2$ multilayer in dye-sensitized solar cells (DSSCs), we designed a new DSSC system, assembled with a CdS-$TiO_2$ scattering layer electrode. A high-magnification SEM image exhibited hollyhock-like particles with a width of 1.5-2.0 ${\mu}m$ that were aggregated into 10-nm clumps in a hexagonal petal shape. The efficiency was higher in the DSSC assembled with a CdS-$TiO_2$ scattering layer than in the DSSC assembled with $TiO_2$-only layers, due to the decreased resistance in electrochemical impedance spectroscopy (EIS). The short-circuit current density ($J_{sc}$) was increased by approximately 7.26% and the open-circuit voltage ($V_{oc}$) by 2.44% over the 1.0 wt % CdS-$TiO_2$ composite scattering layer and the incident photon-to-current conversion efficiency (IPCE) in the maximum peak was also enhanced by about 5.0%, compared to the DSSC assembled without the CdS-$TiO_2$scattering layer.