• Title/Summary/Keyword: scattering particles

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Preparation of Fullerene/Polystyrene Nanoparticles by Emulsion Polymerizations

  • Kim, Kun-Ji;Park, Soo-Yeon;Lee, Myong-Hoon
    • 한국정보디스플레이학회:학술대회논문집
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    • 2009.10a
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    • pp.1573-1574
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    • 2009
  • Fullerene/polystyrene nanoparticles having the average size of 300 nm ~ 1 ${\mu}m$ were prepared by emulsion polymerization in aqueous medium. Poly(vinyl pyrrolidone) and potassium persulfate were used as a dispersant and an initiator, respectively. The contents of fullerene in the nanoparticle were controlled to be from 10 to 57 wt% by varying the feed ratio, which was confirmed by IR-spectroscopy, thermogravimetric analyses, and elemental analyses. Dynamic light scattering experiments revealed the particles have a broad size distribution. Further characterizations of the nanoparticles were performed by using SEM and TEM observation. The high content of fullerene in the particles will find applications in photovoltaic and organic semiconducting area.

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Simulation and Optimization of Nonperiodic Plasmonic Nano-Particles

  • Akhlaghi, Majid;Emami, Farzin;Sadeghi, Mokhtar Sha;Yazdanypoor, Mohammad
    • Journal of the Optical Society of Korea
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    • v.18 no.1
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    • pp.82-88
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    • 2014
  • A binary-coupled dipole approximation (BCDA) is described for designing metal nanoparticles with nonperiodic structures in one, two, and three dimensions. This method can be used to simulate the variation of near- and far-field properties through the interactions of metal nanoparticles. An advantage of this method is in its combination with the binary particle swarm optimization (BPSO) algorithm to find the best array of nanoparticles from all possible arrays. The BPSO algorithm has been used to design an array of plasmonic nanospheres to achieve maximum absorption, scattering, and extinction coefficient spectra. In BPSO, a swarm consists of a matrix with binary entries controlling the presence ('1') or the absence ('0') of nanospheres in the array. This approach is useful in optical applications such as solar cells, biosensors, and plasmonic nanoantennae, and optical cloaking.

Synthesis of Size Controlled Gold Nanoparticles and Surface Enhanced Raman Spectroscopy (SERS) Effect (크기가 조절된 골드 나노 입자의 합성과 표면 라만 증강의 효과)

  • Lee, Young Wook;Shin, Tae Ho
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.32 no.6
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    • pp.462-465
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    • 2019
  • Nanoscale gold particles have been intensively researched due to their potential applications in catalysis, electronics, plasmonics, and biological assays. In our study, we fabricated gold nanoparticles (NPs) that were synthesized in an aqueous environment via the reduction of $HAuCl_4$ by ascorbic acid (AC) with a sodium citrate (SC) surfactant. Highly monodispersed gold particles with sizes ranging from 123 to 184 nm were prepared in high-yield by a surfactant concentration. The structural and optical properties of the synthesized gold nanoparticles were characterized by transmission electron microscopy (TEM) and UV-vis spectroscopy. The prepared nanoparticles exhibited efficient surface-enhanced Raman scattering (SERS) properties that were dependent on their on size.

Characterization of Particle Losses in a Perma Pure Dryer

  • R. B. Xiang;Lee, K. W.;C. H. Jung;Kim, J. Y.;Park, B. C.
    • Proceedings of the Korea Air Pollution Research Association Conference
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    • 2002.04a
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    • pp.237-238
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    • 2002
  • Particle - bound water changes the physical and chemical properties of aerosol particles, such as size and light scattering properties. Consequently, it is necessary to remove water vapor from ambient aerosols before aerosol particles are sized and counted. Silicon gel diffusion dryer is commonly employed for this purpose. However, it can not be operated continuously While in operation, silicon gel becomes progressively more loaded with water and must periodically be regenerated by drying off the water. (omitted)

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Diameters Analyses of Fine Particles Emitted When Mackerels Cooked (고등어 조리 시 발생하는 미세먼지의 입경 분석)

  • Kim, Seong Mi;Lee, Im Hack;Lee, Kyoung Bin;Kim, Jin Sik;Kwon, Myung Hee
    • Journal of Korean Society for Atmospheric Environment
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    • v.33 no.4
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    • pp.361-369
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    • 2017
  • In this study, the characteristics of the dust emission according to the presence or absence of operation of the gas stove were analyzed by particle size analysis and density estimation while the mackerel was cooked while the fan was placed on the gas stove used in the home. The experiment was carried out using 20 mackerel of normal size at home. Commercially available canola oil was used as edible oil. In order to understand the characteristics such as particle size distribution of fine dust, light scattering measurement method which can be measured at intervals of several seconds was used. Particles generated by combustion of gas stove, particles formed by heating cooking oil, and particles generated by heating mackerel fish meat are judged to be nano size particles smaller than $1{\mu}m$. Therefore, it is necessary to use precise measurement method rather than the measurement method using the filter which is currently being measured in the measurement of the particles discharged from the fuel combustion or food cooking in the future. Analyzing the particle size and density of the dust emitted from the cooking stove is expected to contribute technically to the reduction of dust emissions from the cooking process of gas and fuel facilities at home and commercial facilities.

Dust-scattered FUV halo around Spica

  • Choi, Yeon-Ju;Min, Kyoung-Wook;Park, Jae-Woo;Lim, Tae-Ho;Seon, Kwang-Il
    • The Bulletin of The Korean Astronomical Society
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    • v.37 no.1
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    • pp.73.2-73.2
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    • 2012
  • The far ultraviolet (FUV) wavelength (900-1750A) range includes a wealth of important astrophysical information related to the cooling of hot gas, fluorescent emission from H2 molecules, and starlight scattered off dust particles. Among these, we would like to focus on the scattered emission of the central star by dust with the example of the FUV halo surrounding ${\alpha}$ Vir (Spica). While scattering properties of dust have been studied with the GALEX data, the improved dataset of STSAT-1 revealed many detailed structures of this interesting region. For example, the FUV continuum map obtained from the STSAT-1 observations shows enhanced emission in the southern part of the Spica halo region, where the dust level is also high. In fact, the FUV continuum intensity is seen to have a good correlation with the IRAS 100${\mu}m$ emission data. It is also seen that the scattered spectrum is softer than the original one emitted by the central star, which is attributed to the increase in the dust-scattering albedo with wavelength. We have developed a Monte Carlo code that simulates dust scattering of light including multiple encounters. The code is applied to the present Spica halo region to obtain the scattering properties such as the albedo and the phase function asymmetry factor.

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Measurement on the Methotrexate in L-${\alpha}$-Phosphatidylcholine Media by Light Sacttering (L-${\alpha}$-Phosphatidylcholine 매질에서 빔산란에 의한 Methotrexate의 측정)

  • Kim, Ki-Jun;Lee, Joo-Youb
    • Journal of the Korean Applied Science and Technology
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    • v.30 no.2
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    • pp.251-257
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    • 2013
  • The influences of Methotrexate as fluorophor, scatterer, absorber in turbid material by light scattering were interpreted for the scattered fluorescence intensity and wavelength, it has been studied the molecular properties by laser induced fluorescence spectroscopy. It has been found that the effects of optical properties in scattering media by the optical parameters((${\mu}_s$, ${\mu}_a$, ${\mu}_t$). The value of scattering coefficient ${\mu}_s$ is large by means of the increasing particles of L-${\alpha}$-Phosphatidylcholine, it has been found that the slope decays exponentially as a function of depth from laser source to detector. It may also aid in designing the best model for oil chemistry, laser medicine and application of medical engineering.

Synthesis of Amorphous Er3+-Yb3+ Co-doped TiO2 and Its Application as a Scattering Layer for Dye-sensitized Solar Cells

  • Han, Chi-Hwan;Lee, Hak-Soo;Lee, Kyung-Won;Han, Sang-Do;Singh, Ishwar
    • Bulletin of the Korean Chemical Society
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    • v.30 no.1
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    • pp.219-223
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    • 2009
  • $TiO_2$ doped with $Er^{3+\;and\;Yb^{3+}$ was used for fabricating a scattering layer and a nano-crystalline $TiO_2$ electrode layer to be used in dye-sensitized solar cells. The material was prepared using a new sol-gel combustion hybrid method with acetylene black as fuel. The $Er^{3+}$-$Yb^{3+}$ co-doped titanium oxide powder synthesized at 700oC had embossed structure morphology with a size between 27 to 54 nm that agglomerated to produce micron size particles, as observed by the scanning electron micrographs. The XRD patterns showed that the $Er^{3+}$-$Yb^{3+}$ co-doped titanium oxide had an amorphous structure, while using the same method without doping $Er^{3+}\;or\;Yb^{3+},\;TiO_2$ was obtained in the crystallite form with thea dominance of rutile phase. Fabricating a bilayer structure consisting of nano-crystalline $TiO_2$ and the synthesized $Er^{3+}$-$Yb^{3+}$ co-doped titanium oxide showed better scattering property, with an overall increase of 15.6% in efficiency of the solar cell with respect to a single nano-crystalline $TiO_2$ layer.

Fuel Concentration Measurements by Laser Rayleigh Scattering (레이저 Rayleigh 산란을 이용한 연료농도 계측시 잡음원인과 대책)

  • Kwon, Soon-Tae;Lee, Jae-Won;Park, Chan-Jun;Ohm, In-Young
    • Journal of Energy Engineering
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    • v.17 no.4
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    • pp.189-197
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    • 2008
  • In this study, a system to measure continuously the fuel concentration in a steady flow rig on the basis of Rayleigh scattering is presented. The system can be employed to measure both the temporal and the spatial distribution. Also, it is possible to calibrate the system for the measurement of accurate absolute concentration. Firstly, the system was tested at a calibration chamber for the determination of scattering cross section from propane, butane, acetylene, Freon-12 and Genetron 143a. After this, the system was adapted to a steady flow rig to measure the temporal and spatial fuel concentration. The rig is composed of cylinder head, intake manifold, injector, and transparent cylinder which can simulate internal combustion engine. To cope with the interference of Mie scattering, which is main obstacle of the measuring concentration with Rayleigh scattering, a hardware filter was installed for reducing the number density of particles. Furthermore a software filter was developed, which is based on the rise time and the time constant of the photomultiplier-amplifier system. In addition, background noisy was reduced by adjusting the optical array and applying the pin hall and beam trap. The results show that LRS can provide useful information about concentration field and the software filter is very effective method to remove Mie interference.

Thermal Plasma Synthesis of Nano Composite Particles (열플라즈마에 의한 복합 나노 입자 제조)

  • Jeong, Min-Hee;Kim, Heon-Chang
    • Applied Chemistry for Engineering
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    • v.21 no.6
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    • pp.676-679
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    • 2010
  • Nano composite particles were synthesized from a bulk ZrVFe alloy ingot by transferred DC thermal plasma. Effects of plasma gas flow rate on the characteristics of the produced nano composite particles were investigated. The characteristics of the synthesized powder were analyzed by field scanning electron microscopy (FE-SEM), light scattering particle size analyzer (PSA), energy dispersive X-ray spectroscopy (EDS), X-ray diffractometer (XRD), and Brunauer-Emmett-Teller (BET) surface area analyzer. As the flow rate of plasma gas increased from 20 L/min to 40 L/min, the average particle size decreased from 91 nm to 55 nm, the particle size distribution became narrower, the surface area increased from $200\;m^2/g$ to $255\;m^2/g$, the particle composition was nearly unaffected, and the particle crystallinity was improved.