• 자원리싸이클링
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• 제15권2호
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• pp.32-36
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• 2006

마그네슘은 자동차 엔진 경량화재료 및 휴대폰과 노트북 PC케이스 등 기능성 경량재료로서의 용도개발과 함께 수요가 증가하고 있다. 마그네슘 제련법은 원료광의 특성에 따라 달라지는데 크게 용융염전해법과 열환원법 두가지로 구분할 수 있다. 본 연구에서는 염화마그네슘을 사용하여 용융염전해법에 의해 전해 마그네슘을 얻고자 하였다. 흑연양극의 침지깊이를 일정하게 하고 전해전압 7V로 두가지 조성의 염욕을 비교 실험하였다. $760^{\circ}C$에서 전해 실험한 결과 $KCl/NaCl/MgCl_2$ 혼합염욕이 $KCl/NaCl/CaCl_2/CaF_2/MgCl_2$ 혼합염욕보다 전류효율 면에서 더 효과적이었다. 회수된 전해 마그네슘의 순도는 98% 이상이었다. 본 연구를 통하여 용융염 전해장치를 Scale-up 하거나 상용화시 장치설계 등에 필요한 기초자료들을 축적할 수 있었다.

• Bulletin of the Korean Chemical Society
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• 제35권1호
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• pp.51-56
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• 2014

The solvolysis rate constants of 2,4-dimethoxybenzenesulfonyl chloride (1) in 30 different solvents are well correlated with the extended Grunwald-Winstein equation, using the $N_T$ solvent nucleophilicity scale and $Y_{Cl}$ solvent ionizing scale, with sensitivity values of $0.93{\pm}0.14$ and $0.65{\pm}0.06$ for l and m, respectively. These l and m values can be considered to support a $S_N2$ reaction pathway. The activation enthalpies (${\Delta}H^{\neq}$) were 12.4 to $14.6kcal{\cdot}mol^{-1}$ and the activation entropies (${\Delta}S^{\neq}$) were -15.5 to -$32.3kcal{\cdot}mol^{-1}{\cdot}K^{-1}$, which is consistent with the proposed bimolecular reaction mechanism. The solvent kinetic isotope effects (SKIE) were 1.74 to 1.86, which is also in accord with the $S_N2$ mechanism and was possibly assisted using a general-base catalysis. The values of product selectivity (S) for solvolyses of 1 in alcohol/water mixtures was 0.57 to 6.5, which is also consistent with the proposed bimolecular reaction mechanism. Third-order rate constants, $k_{ww}$ and $k_{aa}$, were calculated from the rate constants ($k_{obs}$), together with $k_{aw}$ and $k_{wa}$ calculated from the intercept and slope of the plot of 1/S vs. [water]/[alcohol]. The calculated rate constants, $k_{calc}$ ($k_{ww}$, $k_{aw}$, $k_{wa}$ and $k_{aa}$), are in satisfactory agreement with the experimental values, supporting the stoichiometric solvation effect analysis.

• 대한화학회지
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• 제30권1호
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• pp.3-8
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• 1986

물-글리세롤, 물-에틸렌 글리콜, 물-이소프로필 알코올 및 물-t-부틸 알코올의 2성분 혼합용매 중에서 cis-$[Co(en)_2ClNO_2]^+$착이온의 가용매 분해반응을 분광광도법으로 연구하였다. 용매의 극성이 커짐에 따라 반응속도도 커지는 경향이 있었으며 반응속도의 대수값과 $\frac{D-1}{2D+1}$값을 도시한 결과 비직선적인 관계를 나타내는 것으로 보아서 용매의 수소결합이나 분산력등의 비정전기적인 상호작용이 지배적으로 작용함을 알 수 있었다. log k와 Grundwald-Winstein의 Y값을 도시한 직선의 기울기와 Kivinen식에서 구한 전이상태에 관여하는 물분자의 수 n값으로부터 실험에 사용한 착물의 가용매 분해반응은 Id메카니즘으로 진행됨을 알았다. 한편 자유에너지 사이클의 결과는 초기상태에서 보다 전이상태에서 용매구조의 효과가 더 큼을 알 수 있었다.

• Geomechanics and Engineering
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• 제5권6호
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• pp.575-594
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• 2013

Organic soils exhibit problematic properties such as high compressibility and low shear strength; these properties may cause differential settlement or failure in structures built on such soils. Organic soil removal or stabilization are the most important methods to overcome geotechnical problems related to peat soils' engineering characteristics. This paper presents soil mechanical intervention for stabilization of peat with sand columns and focuses on a comparison between the mechanical characteristics of undisturbed peat and peat stabilized with 20%, 30% and 40% of sand on the laboratory scale. Cylindrical columns were extruded in different diameters through a nearly undisturbed peat sample in the laboratory and filled with sand. By adding sand columns to peat, higher permeability, higher shear strength and a faster consolidation was achieved. The sample with 70% peat and 30% sand displayed the most reliable compressibility properties. This can be attributed to proper drainage provided by sand columns for peat in this specific percentage. It was observed that the granular texture of sand also increased the friction angle of peat. The addition of 30% sand led to the highest shear strength among all mixtures considered. The peat samples with 40% sand were sampled with two and three sand columns and tested in direct shear and consolidation tests to evaluate the influence of the number and geometry of sand columns. Samples with three sand columns showed higher compressibility and shear strength. Following the results of this laboratory study it appears that the introduction of sand columns could be suitable for geotechnical peat stabilization in the field scale.

• Journal of Plant Biotechnology
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• 제49권2호
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• pp.124-130
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• 2022

The application of traditional taro propagation methods for large-scale cultivation would be insufficient to meet the high demand for quality planting materials. Therefore, this study aimed to develop an in vitro micro-propagation technique for two local taro cultivars (cv.), Wangi and Putih. Taro cormels were collected from the Malaysian Agricultural Research and Development Institute (MARDI) germplasm (Serdang, Malaysia). Explants were taken from the shoot tip of cormels and initially cultured on Murashige and Skoog (MS) basal media for four weeks. The explants were then transferred to different multiplication media supplemented with different types and concentrations of cytokinins such as 6-benzylaminopurine (BAP ) and Thidiazuron (TDZ). Shoot production was quantified after six weeks of culture. The highest mean number of new shoots was produced by the Wangi cultivar on MS medium supplemented with 2.0 mg/l BAP (2.10 shoots), MS medium supplemented with 0.5 mg/l TDZ (2.18 shoots), and Gamborg B5 medium supplemented with 6.0 mg/l BAP (2.43 shoots). The maximum average number of the Putih cultivar shoots was obtained on MS supplemented with 2.0 mg/l BAP (3.57 shoots). MS basal media was used for root initiation, as it produced an average of 25 roots with an 11-cm length. Various types of substrate mixtures were used during acclimatization. The best acclimatization substrate for the Wangi cultivar was 100% peat soil, whereas the Putih cultivar grew optimally in a combination of peat and perlites at a 1:1 ratio. Taro plantlets require approximately 4 to 6 weeks to acclimatize before they can be transferred to the field.

• 대한토목학회논문집
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• 제26권2D호
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• pp.285-292
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• 2006

본 연구에서는 국내에서 개발된 Full-Scale 포장가속시험기(HAPT; Hanyang Accelerated Pavement Tester)를 소개하고, 이 시험의 시험운영과 함께 개질아스팔트 혼합물과 일반 밀입도 아스팔트 혼합물의 소성변형 저항성 비교 연구를 수행하였다. 포장가속시험은 일반 밀입도와 3종의 개질아스팔트 각각에 대해 3가지 온도조건(25-30, 40, $50^{\circ}C$)에서 소성변형 저항성을 평가하였으며, 이 평가 결과들은 DSR실험등 바인더의 실내실험 결과들과도 비교하였다. 포장가속시험을 통한 소성변형 발생량을 분석한 결과, 시험 대상이 된 모든 개질아스팔트 구간에서 일반 밀입도에 비해 소성변형 저항성이 큰 것으로 나타났다. 특히 고온조건에서는 그 차이가 매우 크게 나타났다. 일반 밀입도 아스팔트포장을 대상으로 포장온도 증가에 따른 소성변형 저항성을 분석한 결과 온도가 어느 이상 되면 소성변형 저항성이 급격히 떨어짐을 알 수 있었다. 또한 소성변형에 관련한 중요한 인자로 제시되는 $G^*/sin{\delta}$는 소성변형 저항성을 잘 나타내고 있는 것으로 나타났다. 반면에 회복탄성계수는 소성변형 저항성을 나타내는 인자로 바람직하지 않음도 확인하였다.

• 한국막학회:학술대회논문집
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• 한국막학회 1996년도 춘계 총회 및 학술발표회
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• pp.62-64
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• 1996

Chitin, which is obtained mainly from the cuticle of a marine crustacean, has recently aroused great interest in its industrial and biomedical applications. Chitosan, deacetylated form of chitin, appears to be more useful for biomedical application and dehydration of aqueous solutions than chitin, since it has both hydroxyl and amino groups that can be modified easily. Amino groups on chitosan reacts with dialdehyde to form a Schiff base and then crosslinked, and can be easily neutralized with sulfuric acid and metal ions. Polyfunctional metal ions can form a metal-polyelectrolyte complexes with chitosan. Membranes used in modules so far working in industrial pervaporation plants are generally of composite type. This composite membrane was prepared by coating a porous polysulfone ultrafiltration membrane support of definite structure with a thin, dense layer of permselective chitosan. To apply industrial scale pervaporation process for dehydration of aqueous ethanol and isopropanol, chitosan composite membranes were prepared and tested at various conditions.

• Macromolecular Research
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• 제17권10호
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• pp.757-762
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• 2009

The micro domain structures and crystallization behavior of the binary blends of poly(methyl methacrylate)-b-poly(pentafluorostyrene)-b-poly(methyl methacrylate) (PMMA-PPFS-PMMA) triblock copolymer with a low molecular weight poly(vinylidene fluoride) (PVDF) were investigated by small-angle X-ray scattering (SAXS), small-angle light scattering (SALS), transmission electron microscopy (TEM), optical microscopy, and differential scanning calorimetry (DSC). A symmetric, PMMA-PPFS-PMMA triblock copolymer with a PPFS weight fraction of 33% was blended with PVDF in N,N-dimethylacetamide (DMAc). In the wide range of PVDF concentration between 10.0 and 30.0 wt%, PVDF was completely incorporated within the PMMA micro domains of PMMA-PPFS-PMMA without further phase separation on a micrometer scale. The addition of PVDF altered the phase morphology of PMMA-PPFS-PMMA from well-defined lamellar to disordered. The crystallization of PVDF significantly disturbed the domain structure of PMMA-PPFS-PMMA in the blends, resulting in a poorly-ordered morphology. PVDF displayed unique crystallization behavior as a result of the space constraints imposed by the domain structure of PMMA-PPFS-PMMA. The pre-existing microdomain structures restricted the lamellar orientation and favored a random arrangement of lamellar crystallites.

• 대한기계학회논문집B
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• 제30권2호
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• pp.153-160
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• 2006

A technique for measuring surface temperature field in micro scale is newly proposed, which uses temperature-sensitive fluorescent (TSF) dye coated on the surface and is easily implemented with a fluorescence microscope and a CCD camera. The TSF dye is chosen among mixtures of various chemical compositions including rhodamine B as the fluorescent dye to be most sensitive to temperature change. In order to examine the effectiveness of this temperature measurement technique, numerical analysis and experiment on transient conduction heat transfer for two different substrate materials, i. e., silicon and glass, are performed. In the experiment, to accurately measure the temperature with high resolution temperature calibration curves were obtained with very fine spatial units. The experimental results agree qualitatively well with the numerical data in the silicon and glass substrate cases so that the present temperature measurement method proves to be quite reliable. In addition, it is noteworthy that the glass substrate is more appropriate to be used as thermally-insulating locally-heating heater in micro thermal devices. This fact is identified in the temperature measuring experiment on the locally-heating heaters made on the wafer of silicon and glass substrates. Accordingly, this technique is capable of accurate and non-intrusive high-resolution measurement of temperature field in microscale.

• 한국지하수토양환경학회지:지하수토양환경
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• 제19권5호
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• pp.9-17
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• 2014

This paper reported the use of real-time polymerase chain reaction (PCR), denaturing gradient gel electrophoresis (DGGE), and the culture-based method in the intrinsic bioremediation study at a petroleum contaminated site. The study showed that phenol hydroxylase gene was detected in groundwater contaminated with benzene, toluene, ethylbenzene, xylene isomers (BTEX) and methyl tert-butyl ether (MTBE). This indicated that intrinsic bioremediation occurred at the site. DGGE analyses revealed that the petroleum-hydrocarbon plume caused the variation in microbial communities. MTBE degraders including Pseudomonas sp. NKNU01, Bacillus sp. NKNU01, Klebsiella sp. NKNU01, Enterobacter sp. NKNU01, and Enterobacter sp. NKNU02 were isolated from the contaminated groundwater using the cultured-based method. Among these five strains, Enterobacter sp. NKNU02 is the most effective stain at degrading MTBE without the addition of pentane. The MTBE biodegradation experiment indicated that the isolated bacteria were affected by propane. Biodegradation of MTBE was decreased but not totally inhibited in the mixtures of BTEX. Enterobacter sp. NKNU02 degraded about 60% of MTBE in the bioreactor study. Tert-butyl alcohol (TBA), acetic acid, 2-propanol, and propenoic acid were detected using gas chromatography/mass spectrometry during MTBE degraded by the rest cells of Enterobacter sp. NKNU02. The effectiveness of bioremediation of MTBE was assessed for potential field-scale application.