• Applied Biological Chemistry
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• v.40 no.4
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• pp.294-300
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• 1997

As a part of basic investigation for utilizing by-products derived from marine food processing more effectively as a food source, refining of viscera oil of squid caught off Newzealand were investigated. In the process of refining, degumming with 3% of phosphoric acid at $60^{\circ}C$ for 30 min was effective in removing phosphatides, and optimal condition to neutralize was treating with 0.6% excess of 20% sodium hydroxide solution at $80^{\circ}C$ for 20 min. Bleaching was optimized by adding 10% activated clay and treating for $100^{\circ}C$ for 20 min under vacuum, and deodorizing was done by steam destillation at $180^{\circ}C$ for 60 min under 4 torr of vacuum. Acid value, peroxide value and chromaticity of refined squid viscera oil were 0.20, 0.8 meq/kg and 0.019, respectively. The ratio of polyenoic acid composition to saturated acid composition of refined squid viscera oil was 1.28 and its major fatty acids were 16 : 0, 18 : In-9, 20 : 5n-3 and 22 : 6n-3.

• Geotechnical Engineering
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• v.3 no.2
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• pp.29-40
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• 1987

This paper aims at investigating the characteristics of soil deformation by finite element method (FEM) coupling the cap model with the multi.purpose program developed by authors for the analysis of foundation displacement. The cap model as the constitutive equation has proved to be very useful to a partially saturated roils as well as rocks with high accuracy. As described in the Previous Paper (Park et al 1987) , there exist some difficulties in the determination of soil parameters in order to use the cap model at Present. However the authors have been studying to seek the method for the determination of the soil parameters from the laboratory results of conventional cylindrical triaxial test. Though the computer program advocated by foreign scholars has been kept secret, authors accomplished in performing the FEM analysis by the algorithm and program developed by authors for the cap model. Good results are obtained compared with those published already by Desai(1981) The main conclusions analyzed are as follows: 1. The cap model can be coupled with the multi.purpose computer program of authors bases on the Biot's consolidation theory without loss of generality. 2. Big difference appears in the settlement of center of the embankment between the cap modes and the modified Cam clay model in undrained conditions. The more study on which is more accurate should be performed in this respect.

• Journal of the Korean Geotechnical Society
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• v.15 no.5
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• pp.291-300
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• 1999

Surfactant flushing for enhancing the removal of BTEX from contaminated sand/clay mixtures was investigated. Eight soil columns packed with relatively undisturbed BTEX contaminated soils, were leached with water, methyl alcohol and then flushed with surfactant with or without several additives. Initial concentrations of BTEX mixture range from 278mg/kg to 1975mg/kg. Initial BTEX removal efficiency was 98% when the contaminated soil was flushed with water of 850 pore volumes. Because of tailing effect, water flushing could not remove below 8mg/kg concentrations during the experimental period. Eventually, the most effective surfactant for flushing was turned out to be 4% SOFTANOL(equation omitted)-90 with 3% ethyl alcohol and 3% SXS. In interrupted flow conditions, the removal efficiency was 99.5% with the flushed water of 95 pore volumes. The BTEX mixture removed from the soil columns during the surfactant flushing ranges from 84.5% to 99.5% of the initial amount for both water leaching(850 pore volumes) and surfactant flushing(95-165 pore volumes), respectively. Test results indicated that surfactant flushing could enhance the removal of BTEX mixture from contaminated soils and could reduce the aqueous phase BTEX mixture concentration in leachate.

• Korean Journal of Environmental Agriculture
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• v.10 no.2
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• pp.128-132
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• 1991

This study was carried out to find a method to remove cadmium from soil and/or attenuate in Cd saturated Soil The chemical form of Cd was influenced by the physico-chemical properties of soil and the adsorption of Cd by soil conformed to the Langmuir isotherm. The order of Cd contents in chemical fractions extracted by several reagents was EDTA > NaOH > $HNO_3$. Flooding, liming and the addition of chelating agents and clay minerals to the contaminated soil seems to desirable in alleviating the harmful effects of Cd on plant growth by reducing Cd content in the $KNO_3$ fraction.

• Korean Journal of Environmental Agriculture
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• v.10 no.1
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• pp.27-31
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• 1991

This study was conducted to examine the adsorption capacity of $NH_4\;^+-N$ by natural zeolite for the purpose of investigating the possibility for $NH_4\;^+-N$ eliminator of Korean natural zeolite. The dominant clay minerals of zeolite were clinoptilolite and mordenite. The reaction of $NH_4\;^+-N$ adsorption by zeolite reached equilibrium after 4hrs. The amount of $NH_4\;^+-N$ adsoption by zeolite was not significantly affected by the particle size of zeolite. The order of $NH_4\;^+-N$ adsorption by zeolite according to exchangeable cations was Na-> Ca> K-saturated zeolite. The amount of $NH_4\;^+-N$ adsorption by zeolite was increased with increasing pH of solution and the ratio of zeolite to the volume of solution. The isothermal curvel of $NH_4\;^+-N$ adsorption by zeolite was conformed to Langmuir equation.

• Journal of the Korean Geotechnical Society
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• v.20 no.1
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• pp.21-27
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• 2004

In this test, there was two-dimensional model loading test implemented for analysis with respect to the problem of evaluating bearing capacity and the application range on the dredged and reclaimed ground, so it was possible to get the following result by comparing a result of loading test and an equation proposed previously. When the difference between average undrained shea. strength by (equation omitted)B of loading board width and the strength under. (equation omitted)B is mere than $\pm50%$, the applicability of Nc(coefficient of bearing capacity where $\phi=0$ analysis is considered in the single layer) was declined. As well, using Nc=5.7, 5.14(coeffcient of bearing capacity where $\phi=0$ analysis is applicable to saturated clay without special limit) for evaluating bearing capacity on the dredged and reclaimed ground causes poor applicability, therefore that seem to be applicable when water content is less than about 75% which makes the unconfined compression test possible.

• Journal of Forest and Environmental Science
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• v.37 no.2
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• pp.116-127
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• 2021

Predicting carbon distribution of soil aggregates is difficult due to complexity in organo-mineral formation. This limits global warming mitigation through soil carbon sequestration. Therefore, knowledge of land use effect on carbon stabilization requires quantification of soil mineral cations. The study was conducted to quantify carbon and base cations on soil mineral fractions in Natural Forest, Plantation Forest and Farm Land. Five 0.09 ha were demarcated alternately along 500 m long transect with an interval of 50 m in Natural Forest (NF), Plantation Forest (PF) and Farm Land (FL). Soil samples were collected with soil cores at 0-15, 15-30 and 30-45 cm depths in each plot. Soil core samples were oven-dried at 105℃ and soil bulk densities were computed. Sample (100 g) of each soil core was separated into >2.0, 2.0-1.0, 1.0-0.5, 0.5-0.05 and <0.05 mm aggregates using dry sieve procedure and proportion determined. Carbon concentration of soil aggregates was determined using Loss-on-ignition method. Mineral fractions of soil depths were obtained using dispersion, sequential extraction and sedimentation methods of composite soil samples and sieved into <0.05 and >0.05 mm fractions. Cation exchange capacity of two mineral fractions was measured using spectrophotometry method. Data collected were analysed using descriptive and ANOVA at α_0.05. Silt and sand particle size decreased while clay increased with increase in soil depth in NF and PF. Subsoil depth contained highest carbon stock in the PF. Carbon concentration increased with decrease in aggregate size in soil depths of NF and FL. Micro- (1-0.5, 0.5-0.05 and <0.05 mm) and macro-aggregates (>2.0 and 2-1.0 mm) were saturated with soil carbon in NF and FL, respectively. Cation exchange capacity of <0.05 mm was higher than >0.05 mm in soil depths of PF and FL. Fine silt (<0.05 mm) determine the cation exchange capacity in soil depths. Land use and mineral size influence the carbon and cation exchange capacity of Gambari Forest Reserve.

• Geomechanics and Engineering
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• v.27 no.6
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• pp.583-594
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• 2021

The gas permeability behavior of unsaturated bentonite-based materials is of major importance for ensuring effective sealing of high-level radwaste repositories. This study investigated this by taking a sample of Granular Bentonite Material (GBM) at the end of the Engineered Barrier Emplacement (EB) experiment in the Opalinus Clay, placing it under different humidity conditions until it achieved equilibration, and testing the change in the gas permeability under loading and unloading. Environmental humidity is shown to have a significant effect on the water content, saturation, porosity and dry density of GBM and to affect its gas permeability. Higher sensitivity to confining pressure is exhibited by samples equilibrated at higher relative humidity (RH). It should be noted that for the sample at RH=98%, when the confining pressure is raised from 1 MPa to 6 MPa, gas permeability can be reduced from 10^-16 m² to 10^-19 m², which is close to the requirements of gas tightness. Due to higher water content and easier compressibility, samples equilibrated under higher RH show greater irreversibility during the loading and unloading process. The effective gas permeability of highly saturated samples can be increased by 2-3 orders of magnitude after 105℃ drying. In addition, cracks possibly occurred during the dehydration and drying process will become the main channel for gas migration, which will greatly affect the sealing performance of GBM.

• Journal of the Korean Geotechnical Society
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• v.24 no.11
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• pp.133-141
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• 2008

In this study, a new method for estimating the undrained shear strength $s_u$ of saturated clays using piezocone penetration test (CPTu) result is proposed. This is to develop more effective CPTu-based $s_u$ estimation method at lower cost with less uncertainty. For this purpose, a marine clay deposit is selected and tested through extensive experimental testing program including both in-situ and fundamental laboratory tests. The proposed method is based on a correlation between the undrained shear strength $s_u$ and the cone resistance $q_t$, without introduction of the total overburden stress into the $s_u-q_t$ correlation. As a result, no additional testing procedure for collecting undisturbed soils samples is required, which can reduce overall testing cost. To verify the proposed method, 4 test sites, which consist of a variety of soil conditions, are selected and used for comparison between measured and predicted undrained shear strength. From comparison, it is seen that predicted values of $s_u$ using the proposed method match well those from measured results.

• KSCE Journal of Civil and Environmental Engineering Research
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• v.1 no.1
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• pp.53-68
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• 1981

Most clays under sustained load exhibit time-dependent deformation because of creep movement of soil particles and many investigators have attempted to relate their findings to the creep behavior of natural ground and to the long-term stability of slopes. Since the creep behavior of clays may assume a variety of forms depending on such factors as soil plasticity, activity and water content, it is difficult and complicated to analyse the creep behavior of clays. Rheological models composed of linear springs in combination with linear or nonlinear dashpots and sliders, are generally used for the mathematical description of the time-dependent behavior of soils. Most rheological models, however, have been proposed to simulate the behavior of secondary compression for saturated clays and few definitive data exist that can evaluate the behavior of non-saturated clays under the action of sustained stress. The clays change gradually from a solid state through plastic state to a liquid state with increasing water content, therefore, the rheological models also change. On the other hand, creep is time-dependent, and also the effect of thixotropy is time-function. Consequently, there may be certain correlations between creep behavior and the effects of thixotropy in compacted clays. In addition, the states of clay depend on water content and hence the height of the specimen under drained conditions. Futhermore, based on present and past studies, because immediate elastic deformation occurs instantly after the pressure increment without time-delayed behavior, the factor representing immediate elastic deformations in the rheological model is necessary. The investigation described in this paper, based on rheological model, is designed to identify the immediate elastic deformations and the effects of thixotropy and height of clay specimens with varing water content and stress level on creep deformations. For these purposes, the uniaxial drain-type creep tests were performed. Test results and data for three compacted clays have shown that a linear top spring is needed to account for immediate elastic deformations in the rheological model, and at lower water content below the visco-plastic limit, the effects of thixotropy and height of clay specimens can be represented by the proposed rheological model not considering the effects. Therefore, the rheological model does not necessitate the other factors representing these effects. On the other hand, at water content higher than the visco-plastic limit, although the state behavior of clays is visco-plastic or viscous flow at the beginning of the test, the state behavior, in the case of the lower height sample, does not represent the same behavior during the process of the test, because of rapid drainage. In these cases, the rheological model does not coincide with the model in the case of the higher specimens.