• Economic and Environmental Geology
• /
• v.45 no.6
• /
• pp.661-672
• /
• 2012

Lab scale experiments to investigate the dissolution reaction among supercritical $CO_2$-sandstone-groundwater by using sandstones from Gyeongsang basin were performed. High pressurized cell system (100 bar and $50^{\circ}C$) was designed to create supercritical $CO_2$ in the cell, simulating the sub-surface $CO_2$ storage site. The first-order dissolution coefficient ($k_d$) of the sandstone was calculated by measuring the change of the weight of thin section or the concentration of ions dissolved in groundwater at the reaction time intervals. For 30 days of the supercritical $CO_2$-sandstone-groundwater reaction, physical properties of sandstone cores in Gyeongsang basin were measured to investigate the effect of supercritical $CO_2$ on the sandstone. The weight change of sandstone cores was also measured to calculate the dissolution coefficient and the dissolution time of 1 g per unit area (1 $cm^2$) of each sandstone was quantitatively predicted. For the experiment using thin sections, mass of $Ca^{2+}$ and $Na^+$ dissolved in groundwater increased, suggesting that plagioclase and calcite of the sandstone would be significantly dissolved when it contacts with supercritical $CO_2$ and groundwater at $CO_2$ sequestration sites. 0.66% of the original thin sec-tion mass for the sandstone were dissolved after 30 days reaction. The average porosity for C sandstones was 8.183% and it increased to 8.789% after 30 days of the reaction. The average dry density, seismic velocity, and 1-D compression strength of sandstones decreased and these results were dependent on the porosity increase by the dissolution during the reaction. By using the first-order dissolution coefficient, the average time to dissolve 1 g of B and C sandstones per unit area (1 $cm^2$) was calculated as 1,532 years and 329 years, respectively. From results, it was investigated that the physical property change of sandstones at Gyeongsang basin would rapidly occur when the supercritical $CO_2$ was injected into $CO_2$ sequestration sites.

• Nuclear Engineering and Technology
• /
• v.54 no.4
• /
• pp.1175-1184
• /
• 2022

The pore structure of uranium-bearing sandstone is one of the critical factors that affect the uranium leaching performance. In this article, uranium-bearing sandstone from the Yili Basin, Xinjiang, China, was taken as the research object. The fractal characteristics of the pore structure of the uranium-bearing sandstone were studied using mercury intrusion experiments and fractal theory, and the fractal dimension of the uranium-bearing sandstone was calculated. In addition, the effect of the fractal characteristics of the pore structure of the uranium-bearing sandstone on the uranium leaching kinetics was studied. Then, the kinetics was analyzed using a shrinking nuclear model, and it was determined that the rate of uranium leaching is mainly controlled by the diffusion reaction, and the dissolution rate constant (K) is linearly related to the pore specific surface fractal dimension (D_S) and the pore volume fractal dimension (D_V). Eventually, fractal kinetic models for predicting the in-situ leaching kinetics were established using the unreacted shrinking core model, and the linear relationship between the fractal dimension of the sample's pore structure and the dissolution rate during the leaching was fitted.

• Journal of the Speleological Society of Korea
• /
• v.34 no.35
• /
• pp.78-104
• /
• 1993

Analysis of one sinkhole, the Dodgeville sinkhole, developed in Ordovician dolostones in the Driftless Area of Wisconsin in the Upper Midwest'd Driftless Area reveals homogenous clayey sediment fills reflecting a range of dissolutional processes during the Quaternary or Pre-Quaternary. Granulometric analysis, graphical moments statistics, carbonate minerals, ana sand grain lithology were used to differentiate sinkhole sediment sources and modes of accumulation. Sediments in the dolostone sinkholes developed by dissolution. Sediments contain two major types of sediments : residual redish clay( autogenic sediments) and aeolian silt (allogenic sediments). The massive clay is generated from the weathered dolostone bedrocks as a in situ materials. The loessial silt is mostly derived from transportation of the surrounding surface materials, with some evidences of penetrated deposition. Unlike the collapsed sandstone sinkholes (Oh et al., 1993), dolostone sinkholes reveal homogenous, autogenic clay materials, and a geochemical composition indicative of in situ autogenic karstification. Dolostone sinkhole si1ts (26.9%) and sands (34.9%) are derived from weathered Plattevi1le-Galena dolostones, and contain high carbonate(37.5%), chert (57.2%) and lead ore (3%). Graphical moments statistics for sorting, skewness, and kurtosis indicate that sand grains from dolostones were derived entirely from local bedrock by in situ dissolution. Upper sinkhole sediments are pedagogically very young as carbonate is unleashed. Materials of the sinkhole sediment are definitely inherited from internal dolostones by dissolution and weathering, because not only a granulomatric comparison of dolostone and sandstone sediments demonstrates that they have heterogeneous paticle size distributions, but also 1ithologic analyses displays they differ completely.

• Proceedings of the Korea Water Resources Association Conference
• /
• 2005.05b
• /
• pp.29-38
• /
• 2005

It is important to understand groundwater conditions such as recharge, flow and hydrochemical process occurred within an aquifer for groundwater protection and groundwater resource management. Groundwater from the Triassic Sherwood Sandstone aquifer of North Yorkshire has been used for industrial purposes and domestic water supply. Tn order to understand the processes affecting groundwater chemistry and identify the sources of high chloride, sulphate and nitrate concentrations hydrochemical and isotopic measurements were carried out. Hydrochemical and isotopic measurements indicated that five groundwater types exist within the Sherwood Sandstone aquifer of study area. The results of hydrochemical and isotopic measurements showed that older groundwaters have different hydrochemical and isotopic characteristics from recent recharge water. It was also found that water-rock interactions are the dominant mechanism controlling the ${\delta}^{13}C$ composition of dissolved inorganic carbon, the ${\delta}^{34}S\;and\;{\delta}^{18}O$ composition of dissolved sulphate and the strontium isotope ratios ($^{87}Sr/^{86}Sr$) in recent recharge water and old groundwater. Several abstraction boreholes within the Selby wellfield have been contaminated by saline water. The isotopic data of saline groundwater samples taken from these abstraction boreholes indicate that saline waters are derived from the dissolution of the Triassic evaporites within the Mercia Mudstone.

• The Korean Journal of Petroleum Geology
• /
• v.3 no.1 s.4
• /
• pp.16-27
• /
• 1995

The Early Miocene Temblor Formation forms an important sandstone reservoir at Kettleman North Dome oil field, California. Sandstones are mostly arkosic in composition except deepest sandstones containing much volcanic rock fragments. Arranged in paragenetic sequence prior to feldspar alteration, the Temblor sandstones contain cements of early calcite, dolomite, quartz, albite, mixed-layer ohloriteismectite (C/S) and smectite, and anhydrite. Diagenetic changes associated with feldspar are albitization of plagioclase, late calcite and laumontite cementation and grain replacement, plagioclase dissolution, and kaolinite cementation. Plagioclase albitization and late calcite and laumontite cementation in Temblor sandstones occurred at the time of maximum burial with temperatures up to $130^{\circ}C$. Volcanic plagioclases were selectively albitized. Most diagenetic changes are interpreted to have occurred before the maior uplift which occurred within the last one million years ago. Since then to the time of hydrocarbon emplacement plagioclase dissolution and kaolinite cementation occurred. This reaction occurred in relatively closed system due to the occurrence of kaolinite next to the site of plagioclase dissolution. Unaltered part of volcanic plagioclase and plutonic plagioclase which escaped albitization during maximum burial were preferentially dissolved to make plagioclase porosity. Secondary porosity resulting from dissolution of plagioclase and carbonate and anhydrite cements was mainly produced by formation waters containing organic acids released during atagenesis of organic matter.

• Geosciences Journal
• /
• v.22 no.6
• /
• pp.1015-1026
• /
• 2018

This paper aims to investigate the good reservoir quality and hydrocarbon potentiality of the Khatatba Formation, Qasr Field in the Shoushan Basin of the North Western Desert, Egypt by combining results from log-based petrophysical analysis, petrographic description and images from scanning electron microscope (SEM). Promising reservoir units are initially identified and evaluated through well log analysis of three wells in the field of study. Petrophysical results are then compared with petrographic and SEM images from rock samples to identify features that characterize the reservoir quality. Well log results show that Khatatba Formation in the study area has good sandstone reservoir intervals from depths ranging from 12848 ft to 13900 ft, with good effective porosity records of 13-15% and hydrocarbon saturations of greater than 83%. Petrographic analysis of these sandstone reservoir units indicate high concentrations of vacant pore spaces with good permeability that can be easily occupied by hydrocarbon. The availability of these pore spaces are attributed to pore-enhancing diagenetic features, mainly in the form of good primary porosity and dissolution. SEM images and EDX analysis confirmed the presence of hydrocarbon, therefore indicating a good hydrocarbon-storing potential for the Khatatba Formation sandstones.

• Economic and Environmental Geology
• /
• v.35 no.1
• /
• pp.55-66
• /
• 2002

There are several abandoned coal mines around Donghae mine area in the Taebaek coal field. Two major creeks, Soro and Sanae, are contaminated with the colored precipitates formed from the coal mine drainages. Bed rocks of the study area consist of limestone, shale, and sandstone. Limestone consisted mainly of calcite and dolomite, and shale of quartz, pyropyllite and chlorite, and sandstone of quatz and illite. Coal coal spoil dumps composed mainly of pyrite and chlorite. The oxidative dissolution of sulfide minerals leads to acid mine drainage and adds the metal ions in the stream water. The ion concentrations of Fe, Ca, Mg, Al, Si, SO$_{4}$in the stream polluted by AMD are generally higher than those in the unpolluted stream water. High concentrations of Ca and Mg, Al and Si can be resulted from dissolution of carbonate minerals such as calcite, dolomite and aluminosilicates such as chlorite, pyrophyllite. Although the Fe, Al, Si, SO$_{4}$ contents are considerbly high in the acid water released from the mine adits, they become decreased downstream due to dilution of unpolluted water and precipitation of oxide/hydroxide and sulfate minerals on the bottom of stream.

• The Journal of the Petrological Society of Korea
• /
• v.7 no.2
• /
• pp.132-145
• /
• 1998

The coal-bearing siliciclastic rocks of the Lower Permian Jangseong Formation, Samcheog coalfield, represent a megacyclothem which shows cyclic repetitions of sandstone, shale, coaly shale, and coals. Petrographic, geochemical, and SEM studies for sandstone samples, and XRD analysis for clay minerals were carried out to understand diagenesis in the sandstones of the Jangseong Formation. The Jangseong sandstones are composed of 60% quartz (mainly monocrystalline quartz) and 36% clay matrix and cement with minor amounts of feldspar, lithic fragments and accessory minerals (less than 4%). Jangseong sandstones are classified mostly as quartzwackes and partly as lithic graywackes according to the scheme of Dott(1964). The textural relationships between authigenic minerals and cements in thin sections and SEM photomicrographs suggest the paragenetic sequence as follows; (1) mechanical compaction, (2) cementation by quartz overgrowth, (3) formation of authigenic clay minerals (illite, kaolinite), (4) dissolution of framework grains and development of secondary porosity, and (5) later-stage pore-filling by pyrophyllite. We propose that these diagenetic processes might be due to organic-inorganic interaction between the dominant framework grains and the formation water. The Al, Si ions and organic acid, derived from dewatering of interbedded organic-rich shale and coals, were transported into the Jangseong sandstones. This caused changes in the chemistry of the formation water of the sandstones, and resulted in overgrowth of quartz and precipitation of authigenic clay minerals of kaolinite and illite. The secondary pores, produced during dissolution of clay and framework grains by organic acid and $CO_2$ gas, were conduit for silica-rich solution into the Jangseong sandstones and the influx of silica-rich solution produced the late-stage pyrophyllite after the expanse of kaolinite. The origin of the solution that formed pyrophyllite is not likely to be the organic-rich formation water based on the observation of fracture-filling pyrophyllite in the Jangseong sandstones, but the process of pyrophyllite pore-filling was indirectly related to organic-inorganic interaction.

• Economic and Environmental Geology
• /
• v.46 no.3
• /
• pp.221-234
• /
• 2013

Laboratory experiments for the reaction with supercritical $CO_2$ under the $CO_2$ sequestration condition were performed to investigate the mineralogical and geochemical weathering process of the sandstones and mudstones in the Pohang basin. To simulate the supercritical $CO_2$-rock-groundwater reaction, rock samples used in the experiment were pulverized and the high pressurized cell (200 ml of capacity) was filled with 100 ml of groundwater and 30 g of powdered rock samples. The void space of the high pressurized cell was saturated with the supercritical $CO_2$ and maintained at 100 bar and $50^{\circ}C$ for 60 days. The changes of mineralogical and geochemical properties of rocks were measured by using XRD (X-Ray Diffractometer) and BET (Brunauer-Emmett-Teller). Concentrations of dissolved cations in groundwater were also measured for 60 days of the supercritical $CO_2$-rock-groundwater reaction. Results of XRD analyses indicated that the proportion of plagioclase and K-feldspar in the sandstone decreased and the proportion of illite, pyrite and smectite increased during the reaction. In the case of mudstone, the proportion of illite and kaolinite and cabonate-fluorapatite increased during the reaction. Concentration of $Ca^{2+}$ and $Na^+$ dissolved in groundwater increased during the reaction, suggesting that calcite and feldspars of the sandstone and mudstone would be significantly dissolved when it contacts with supercritical $CO_2$ and groundwater at $CO_2$ sequestration sites in Pohang basin. The average specific surface area of sandstone and mudstone using BET analysis increased from $27.3m^2/g$ and $19.6m^2/g$ to $28.6m^2/g$ and $26.6m^2/g$, respectively, and the average size of micro scale void spaces for the sandstone and mudstone decreased over 60 days reaction, resulting in the increase of micro pore spaces of rocks by the dissolution. Results suggested that the injection of supercritical $CO_2$ in Pohang basin would affect the physical property change of rocks and also $CO_2$ storage capacity in Pohang basin.

• Nuclear Engineering and Technology
• /
• v.55 no.2
• /
• pp.566-574
• /
• 2023

Investigating the seepage characteristics of the leaching solution in the ore-bearing layer during the in situ leaching process can be useful for designing the process parameters for the uranium mining well. We prepared leaching solutions of four different viscosities and conducted experiments using a self-developed multifunctional uranium ore seepage test device. The effects of different viscosities of leaching solutions on the seepage characteristics of uranium-bearing sandstones were examined using seepage mechanics, physicochemical seepage theory, and dissolution erosion mechanism. Results indicated that while the seepage characteristics of various viscosities of leaching solutions were the same in rock samples with similar internal pore architectures, there were regular differences between the saturated and the unsaturated stages. In addition, the time required for the specimen to reach saturation varied with the viscosity of the leaching solution. The higher the viscosity of the solution, the slower the seepage flow from the unsaturated stage to the saturated stage. Furthermore, during the saturation stage, the seepage pressure of a leaching solution with a high viscosity was greater than that of a leaching solution with a low viscosity. However, the permeability coefficient of the high viscosity leaching solution was less than that of a low viscosity leaching solution.