• Title/Summary/Keyword: sample-spacing

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Quantitative Structure Determination of Ni(111)(2×2)-O/CO: temperature Dependent Study (광전자회절을 이용한 Ni(111)(2×2)-O/CO의 표면 흡착 구조: 시편준비의 온도 의존성)

  • Kang J.H.
    • Journal of the Korean Magnetics Society
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    • v.16 no.1
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    • pp.92-97
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    • 2006
  • A study of the adsorption site of CO in the Ni(111)$(2\times2)$-O/CO coadsorbed phase over different sample preparation temperatures revealed that the atop site is favoured. The Ni-C spacing is given by $1.77\pm0.01\;{\AA}$. A study of the adsorption site of Co in the Ni(111)$(2\times2)$-O/CO coadsorbed phase over different sample preparation temperatures revealed that the atop site is favoured. The Ni-C spacing is given by $1.77\pm0.01\;{\AA}$. The data from the sample prepared at 265 K showed atop sites, which is well consistent with vibrational spectroscopy, whilst the data from the low temperature preparation appears the mixture of atop and hop $(35\%)$. The occupation of hop hollow sites is probably due to an incorrect pre-coverage of atomic oxygen (different from 0.25ml). Similar observation of site mixture also found in recent high resolution XPS measurements using C 1s and O 1s chemical shifts.

Spatial dispersion of aggregate in concrete a computer simulation study

  • Hu, Jing;Chen, Huisu;Stroeven, Piet
    • Computers and Concrete
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    • v.3 no.5
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    • pp.301-312
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    • 2006
  • Experimental research revealed that the spatial dispersion of aggregate grains exerts pronounced influences on the mechanical and durability properties of concrete. Therefore, insight into this phenomenon is of paramount importance. Experimental approaches do not provide direct access to three-dimensional spacing information in concrete, however. Contrarily, simulation approaches are mostly deficient in generating packing systems of aggregate grains with sufficient density. This paper therefore employs a dynamic simulation system (with the acronym SPACE), allowing the generation of dense random packing of grains, representative for concrete aggregates. This paper studies by means of SPACE packing structures of aggregates with a Fuller type of size distribution, generally accepted as a suitable approximation for actual aggregate systems. Mean free spacing $\bar{\lambda}$, mean nearest neighbour distance (NND) between grain centres $\bar{\Delta}_3$, and the probability density function of ${\Delta}_3$ are used to characterize the spatial dispersion of aggregate grains in model concretes. Influences on these spacing parameters are studied of volume fraction and the size range of aggregate grains. The values of these descriptors are estimated by means of stereological tools, whereupon the calculation results are compared with measurements. The simulation results indicate that the size range of aggregate grains has a more pronounced influence on the spacing parameters than exerted by the volume fraction of aggregate. At relatively high volume density of aggregates, as met in the present cases, theoretical and experimental values are found quite similar. The mean free spacing is known to be independent of the actual dispersion characteristics (Underwood 1968); it is a structural parameter governed by material composition. Moreover, scatter of the mean free spacing among the serial sections of the model concrete in the simulation study is relatively small, demonstrating the sample size to be representative for composition homogeneity of aggregate grains. The distribution of ${\Delta}_3$ observed in this study is markedly skew, indicating a concentration of relatively small values of ${\Delta}_3$. The estimate of the size of the representative volume element (RVE) for configuration homogeneity based on NND exceeds by one order of magnitude the estimate for structure-insensitive properties. This is in accordance with predictions of Brown (1965) for composition and configuration homogeneity (corresponding to structure-insensitive and structure-sensitive properties) of conglomerates.

Enhanced Electron Emission of Carbon Nanotube Arrays Grown Using the Resist-Protection-assisted Positioning Technique

  • Ryu, Je-Hwang;Kim, Ki-Seo;Yu, Yi-Yin;Lee, Chang-Seok;Lee, Yi-Sang;Jang, Jin;Park, Kyu-Chang
    • Journal of Information Display
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    • v.9 no.4
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    • pp.30-34
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    • 2008
  • Field emitter arrays (FEAs) were developed using carbon nanotubes (CNTs) as electron emission sources. The CNTs were grown using a selective-positioning technique with a resist-protection layer. The light emission properties were studied through the electron emission of the CNTs on patterned islands, which were modulated with island diameter and spacing. The electron emission of CNT arrays with $5{\mu}m$ diameters and $10{\mu}m$ heights increased with increased spacing (from $10{\mu}m$ to $40{\mu}m$). The electron emission current of the $40-{\mu}m$-island-spacing sample showed a current density of 1.33 mA/$cm^2$ at E = 11 V/${\mu}m$, and a turn-on field of 7 V/${\mu}m$ at $1{\mu}A$ emission current. Uniform electron emission current and light emission were achieved with $40{\mu}m$ island spacing and $5{\mu}m$ island diameter.

Anterior Spacing and Crowding in the Primary Dentition in Hwaseong City : A Preliminary Study (화성시 거주 유치열기 어린이의 전치부 치간 공극과 총생에 대한 예비연구)

  • Han, Jiyea;Hwang, Dong hwan;Choi, Hyungjun;Choi, Byung-Jai;Kim, Seong-Oh
    • Journal of the korean academy of Pediatric Dentistry
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    • v.44 no.4
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    • pp.397-402
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    • 2017
  • The aim of this study was to assess the spacing and crowding of the anterior teeth in the primary dentition in Hwaseong city. Photographs of the anterior segment of 237 children satisfied the criteria. The presence of primate spaces and developmental spaces was assessed by the proximal contacts. Physiologic spacing was observed in 47.3% and 38.0% of the cases in the upper and lower arches, respectively. 43.5% showed the presence of two-segment contact or crowded dentition. Physiologic spacing was observed more in boys than in girls. In the maxilla, primate space was more frequent than developmental space; however, in the mandible, the difference was low. In the maxilla, the space between the central incisor and the lateral incisor was more frequent than the space between both central incisors. In contrast, in the mandible, the space between both central incisors was more common than the space between the central and lateral incisors or between the lateral incisors and canine. The present study describes the tendency for anterior spacing and crowding in the primary dentition. Further longitudinal studies with a larger sample are needed. Dentists should consider these concepts of spacing or contact/crowding when performing full coronal restorations of primary anterior teeth.

Asymptotic Properties of Upper Spacings

  • Yun, Seok-Hoon
    • Journal of the Korean Statistical Society
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    • v.26 no.3
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    • pp.289-297
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    • 1997
  • It is well known that the spacings, the differences of two successive order statistics, in a random sample of size n from a distribution function F are independent and exponentially distributed if F is itself the exponential distribution. In this paper we obtain an asymptotically similar result on a fixed number of upper spacings as n .to. .infty. for a general F under the assumption that F is in the domain of attraction of some extreme value distribution. For a heavy or short tailed F, appropriate log transformations of the sample should be proceded to get the result. As a by-product, we also get that each upper spacing diverges in probability to .infty. and converges in probability to 0 as n .to. .infty. for a heavy and short tailed F, respectively, which is fully expected.

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Effect of Strain Rate on the Deformation and Cracking Behaviors of ITO/PET Sheets with 45 ohms/sq. Sheet Resistance (면저항 45 ohms/sq.의 ITO/PET Sheets의 변형률 속도에 따른 균열 형성 거동)

  • Kim, Jin-Yeol;Hong, Sun-Ig
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.22 no.1
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    • pp.67-73
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    • 2009
  • The stress-strain behavior and its effects on the crack initiation and growth of ITO film on PET substrate with a sheet resistance of 45 ohms/sq were investigated. Electrical resistance increased gradually at the strain of 0.7% in the elastic to plastic transition region of the stress strain curves. Numerous cracks were observed after 1% strain and the increase of the resistance can be linked to the cracking of ITO thin films. The onset strain for the increase of resistance increased with increasing strain rate, suggesting the crack initiation is dependent on the strain rate. Upon loading, the initial cracks perpendicular to the tensile axis were observed and propagated the whole sample width with increasing strain. The spacing between horizontal cracks is thought to be determined by the fracture strength and the interfacial strength between ITO and PET. The crack density increased with increasing strain. The spacing between horizontal cracks (perpendicular to the stress axis) increased with decreasing strain rate, The increase of crack density with decreasing strain rate can be attributed to the higher fraction of the plastic strain to the total strain at a given total strain. As the strain increased over 5% strain, cracks parallel to the stress axis were developed and increased in number with strain, accompanied by drastic increases of resistance.

The Fingerprinting of Huangjinju Powder for Injection on Chinese Patent Medicine by XRD Fourier

  • Pan, Yan-Li;Zhang, Gui-Jun;Gong, Ning-Bo;Wu, Yun-Shan;Lu, Yang;Luo, Rong;Choi, Ho-Young
    • Korean Journal of Medicinal Crop Science
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    • v.14 no.2
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    • pp.117-123
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    • 2006
  • The purpose is to study the identification method of Huangjinju powder for injection and the medicinal materials by the fingerprint off-ray Diffraction Fourier (XRDF). We used the same method on both the studying of Huangjinju and the medicinal materials. Then we selected a few components alignment to compare. We analyzed the data by setting up the deviation $d({\AA})$ as ${\pm}0.05$ to calculate the rate of special mark on the sample (Px) and on the patent (P). The special XRDF of Huangjinju$[d({\AA})/(I/I_0)]$ have 5 peaks that have not expressed in medicinal materials. Therefore Px is 22.73%. Flos Trollii Chinensis has 3 special marks and Px is 17.65%. Flos Chrysanthemi Indici has 1 special mark and Px is 3.57%. Its coincided interplanar spacing with the patent is $2.907{\AA}$. Flos Lonicerae Japonicae has 6 special marks and Px is 23.08%. Its special mark in the patent are 4.95/14 and 4.50/15, respectively. The P is 9.09%. Its coincided interplanar spacing with the patent is $2.910{\AA}\;and\;3.05{\AA}$, respectively. The number of special XRDF mark peaks of baicalin is 9 and Px is 18.37%. Its coincided interplanar spacing with the patent is $2.910{\AA}$. It has visible mark and specificity adopting XRDF fingerprint to identify Huangjinju and medicinal materials. Establishing the quality standard is a synthetic index that depends both on special marks in the medicinal materials of the patent and on the coincidence peak data.

Rock Fragmentation Assessment of a Drill Bit by Hopkinson Bar Percussion Test (홉킨스바 타격시험을 통한 드릴비트의 암반파쇄 분석)

  • Kwon, Ki-Beom;Song, Chang-Heon;Park, Jin-Young;Shin, Dae-Young;Cho, Jung-Woo;Cho, Sang-Ho
    • Tunnel and Underground Space
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    • v.23 no.1
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    • pp.42-53
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    • 2013
  • The percussion rate and spacing of the button of drill bit are very important in maximizing the drilling efficiency. Therefore, a series of percussion tests using Hopkinson bar system was carried out to assess the fragmentation performance against the beat rate and spacing of a drill bit. First, single percussion test complemented with numerical simulation was performed to analyze rock fragmentation phenomenon and to describe the fragmentation process. Next, multiple percussion test that repetitively strike the rock sample moving at predetermined rate was carried out to predict drilling efficiency against the button spacing. After the tests, the fragmented volume of the rock was measured by laser scanner and the drilling performance was analyzed using the calculated percussive energy and measured negative volume. Based on the results, the single impact performance of drill bit with 102 mm diameter was predicted.

Studies on the Wood Rays in Coniferous Woods - Mutural Relation on the Indicators of Wood Rays in Coniferous Woods - (침엽수재(針葉樹材)의 방사조직(放射組織)에 관(關)한 연구(硏究) - 방사조직지표치(放射組織指標値)의 상호관련성(相互關聯性)-)

  • Lee, Weon-Yong
    • Journal of the Korean Wood Science and Technology
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    • v.15 no.2
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    • pp.90-98
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    • 1987
  • In the present paper I described the relations of wood ray indicators such as ray height, ray width, number of rays per $0.25mm^2$, ray spacing and fusiform ray height on the stem of Pinus koraiensis and Larix leptolepis grown at the Experiment Forest of Kangweon National University. The results may be summarized as follows. 1. The number of rays and ray spacing were generally decreased with the increase of ray height on the sample woods. 2. According to the tree species the patterns of varition of ray width with the increase of ray height were different, namely the relation between ray width and ray height showed some positive correlation on Pinus koraiensis and negative on Larix leptolepis. 3. It was recognized that the variation of fusiform ray height due to the increase of ray height indicated two patterns(the increasing, md constant regions) in sample woods. This boundary seemed to appear at six cells of ray height on Pinus koraiensis and ninc cells on Larix leptolepis. 4. The relation between fusiform ray height and number of rays had a negative correlation on Pinus koraiensis, but this tendancy was not obvious on Larix leptolepis. And ray spacing and ray width due to the increase of fusiform ray height were generally decreased. 5. On the whole the values of ray spacing and ray width became gradually larger in proportion to the increase of number of rays. 6. According to the increase of ray spacing the values of ray width also increased gradually. But this tendency was more clear on Pinus koraiensis than larix leptolepis.

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Low Resistivity Ohmic Ni/Si/Ni Contacts to N-Type 4H-SiC (낮은 접촉저항을 갖는 Ni/Si/Ni n형 4H-SiC의 오옴성 접합)

  • Kim C. K.;Yang S. J.;Cho N. I.;Yoo H. J.
    • The Transactions of the Korean Institute of Electrical Engineers C
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    • v.53 no.10
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    • pp.495-499
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    • 2004
  • Characteristics of ohmic Ni/Si/Ni contacts to n-type 4H-SiC are investigated systematically. The ohmic contacts were formed by annealing Ni/Si/Ni sputtered sequentially The annealings were performed at 950℃ using RTP in vacuum ambient and N₂ ambient, respectively. The specific contact resistivity(p/sub c/), sheet resistance(R/sub s/), contact resistance (R/sub c/) transfer length(L/sub T/) were calculated from resistance(R/sub T/) versus contact spacing(d) measurements obtained from TLM(transmission line method) structure. While the resulting measurement values of sample annealed at vacuum ambient were p/sub c/ = 3.8×10/sup -5/Ω㎠, R/sub c/ = 4.9 Ω and R/sub T/ = 9.8 Ω, those of sample annealed at N₂ ambient were p/sub c/ = 2.29×10/sup -4/Ω㎠, R/sub c/ = 12.9 Ω and R/sub T/ = 25.8 Ω. The physical properties of contacts were examined using XRD 3nd AES. The results showed that nickel silicide was formed on SiC and Ni was migrated into SiC. This result indicates that Ni/Si/Ni ohmic contact would be useful in high performance electronic devices.