• 제목/요약/키워드: salt shrinkage

검색결과 44건 처리시간 0.027초

팽창재를 혼입한 고내구성 해양콘크리트의 염화물 확산특성에 관한 연구 (A Study on the Chloride Migration Properties of High Durable Marine Concrete Using the Expansion Production Admixture)

  • 김경민;류동우;박상준
    • 한국콘크리트학회:학술대회논문집
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    • 한국콘크리트학회 2008년도 추계 학술발표회 제20권2호
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    • pp.697-700
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    • 2008
  • 본 연구에서는 고로슬래그 혼합시멘트와 3성분계 저발열 혼합시멘트를 대상으로 하고, 여기에 CSA계 팽창재를 혼입함으로서 이에 따른 수축보상 효과와 함께 염해저항 특성에 미치는 영향에 대하여 검토하였다. 검토결과, 배합조건이 OPC이고, 팽창재 혼입율이 8%인 경우는 팽창재를 혼입하지 않은 경우에 비해 최대 43.7배까지팽창하는 것으로 평가되었고, 굵은골재 최대치수가 콘크리트의 길이변화특성에 미치는 영향은 적은 것으로 나타났다. 염해저항성은 굵은골재 최대치수가 클수록, 그리고 팽창재 혼입율이 증가할수록 개선되는 것으로 평가되었는데, 본 연구범위에서는 팽창재를 8% 혼입한 콘크리트의 염해저항성이 팽창재를 혼입하지 않은 경우에 비해 약 16% 정도 유리한 것으로 평가되었다.

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소결법에 의한 다공질유리의 제조 (Preparation of Porous Glass by the Sintering)

  • 박용완;이준영
    • 한국세라믹학회지
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    • 제31권9호
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    • pp.957-968
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    • 1994
  • Manufacturing process of porous glass by the filler method was studied. Commercial soda-lime-silicate glass powder was mixed with inorganic salt as the filler such as KCl, K2SO4, Na2SO4. Sintering shrinkages of mixed powders with the variation of sintering temperature were compared, and the effects of the fillers to shrinkages of mixed powder were increased in the order of Na2SO4${\mu}{\textrm}{m}$ of pore diameter were manufactured when the filler sizes 100~200 ${\mu}{\textrm}{m}$. The open pore volume of porous glass is determined by the quantity of filler and porous glasses having open pore volume between 30 and 70 vol% are available. Available sintering temperature range for preparation of porous glass is from the softening temperature of the glass powder to eutectic melting temperature of DTA curve of mixed powder.

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초기입자크기가 $Pb>(Fe_1/2Nb_1/2)O_3$의 소결 및 유전성에 미치는 영향 (Initial Particle Size Effects on Sintering and Dielectric Properties of $Pb>(Fe_1/2Nb_1/2)O_3$)

  • 박경봉;김태희;윤기현
    • 한국세라믹학회지
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    • 제29권9호
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    • pp.711-718
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    • 1992
  • Pb(Fe1/2Nb1/2)O3 was prepared by the molten salt synthesis method using an equimolar mixture of NaCl-KCl. Initial particle size could be controlled by varying the weight ratio of the NaCl-KCl to raw materials from 0.1 to 1.0, and the initial particle size effects on the sintering and dielectric properties of Pb(Fe1/2Nb1/2)O3 were investigated at the sintering temperature range from 90$0^{\circ}C$ to 105$0^{\circ}C$. As the weight ratio of salt increased, the average particle size decreased and the particle size distributions tended to narrow. As the initial particle size decreased, the linear shrinkage and density increased due to the promotion of densification. Dielectric constant increased with decreasing the initial particle size resulting from the increase of density and grain size.

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균열부 콘크리트의 중성화에 대한 실험적 연구 (An Experimental Study on Carbonation in Cracked Concrete)

  • 권성준;송하원;변근주
    • 한국콘크리트학회:학술대회논문집
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    • 한국콘크리트학회 2002년도 가을 학술발표회 논문집
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    • pp.655-660
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    • 2002
  • Major deterioration in concrete structures are salt attack and carbonation. Especially severe problems due to carbonation occur in tile concrete structures of city, tunnel, underground structures. Cracks in concrete during service life including early age due to hydration heat and/or shrinkage accelerate the diffusion of concrete so that the deterioration is also accelerated. In this study, carbonation depths of both non-cracked concrete and cracked concrete are evaluated and weight change test and TGA are carried out. Through the tests, a relation between water-cement ratio and carbonation depth is derived and also carbonation increase rate is derived in the function of crack width.

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다이빙용 웨트수트(wetsuit) 소재에 대한 소비자 인식조사와 물성 비교 (Consumer recognition and mechanical property comparison of wetsuit material for diving)

  • 상정선;오경화
    • 한국의상디자인학회지
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    • 제20권4호
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    • pp.163-174
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    • 2018
  • Consumer and property evaluation of wetsuit materials were conducted to obtain useful data for developing competitive products that meet consumer expectations and improving industrial competitiveness. Data were collected through online surveys of 213 domestic consumers who have experienced wearing wetsuit among marine leisure activities. Five types of commercial wet suit materials by brand and four types of commercial wet suit materials with the same quality by thickness were collected. Then, their physical properties, salt water resistance and thermal insulation rate were evaluated and compared. As a result, the most commonly used wetsuit material is 3 to 5 mm thick, and the basic jersey material is bonded on both sides. As a processing for imparting functionality, processing for improving warmth and reducing surface resistance are most frequently used. Consumers often feel uncomfortable when wearing a wetsuit, such as wearing comfort, weight, ease of movement, stretchability, and clothing pressure, which are different from those of casual wear. Also, mechanical strength and warmth were considered to be the most important criteria for selection of wetsuit material for purchase or rental. The mechanical properties of brand A and B were better than those of brand C, D, and E. Resilience and thermal shrinkage were better in brand C, D, and E. On the other hand, there was no significant difference in the physical properties due to the difference in thickness of the material at the same quality. Also, it was found that the thicker the material, the more stable it is in the heat. Brand A and B had superior salt water resistance than brand C, D, and E. In the thermal insulation test, brand A and B showed better insulation characteristics than brand C, D, and E, but the types of bonded fabric and surface finishing of materials were thought to have affected. In comparison of the thickness, the thicker the materials, the better the salt resistance and the thermal insulation.

천연고무의 가황시스템 및 성형공정에 따른 2단 발포 특성 연구 (A Study on the Vulcanization System and Two-Step Foaming Properties for Natural Rubber Foam)

  • 이선희;박예은;쇼더리 딕시타
    • 한국염색가공학회지
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    • 제35권4호
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    • pp.246-255
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    • 2023
  • In this study, we investigated for natural rubber foam to replace petrochemical-based neoprene foam. Experiments were conducted on vulcanization system and 2-step foaming process of natural rubber. The vulcanization system were EV(Efficient Vulcanization Cure), Semi-EV(Semi-Efficient Vulcanization Cure) and CV(Conventional Vulcanization Cure). In the 2-step foaming process, first molding temperature was 140℃, times were 15, 20, 25, and 30minutes, and the second molding temperature was 160℃, the times 5, 10, 15, and 20minutes. The cure and viscosity characterization were evaluated by oscillating disc rheometer (ODR) and mooney viscosmeter. Various mechanical characteristics, including hardness, tensile strength, elongation at the point of rupture, and tear strength, were quantified. Subsequently, an assessment of alterations in these mechanical attributes was conducted post-immersion in a NaCl solution. In addition degree of volume change was measured after immersing the NR foam in NaCl solution and the low-temperature permanent compression set was evaluated at 4℃. And expansion ratio and shrinkage ratio of NR foam were evaluated for 28 days. As a result the EV vulcanization system showed the least change in physical properties before and after salt water immersion, and the lowest shrinkage ratio for 28 days. In addition it was confirmed that the 2-step foaming optimum condition differed depending on the appropriate vulcanization condition.

PET직물의 NaOH/4급암모늄염 혼합액에 의한 물성변화 (The Change of the Physical Properties of PET Fabrics Treated in NaOH/Quarternary Ammonium Salt Compound Solution)

  • 오수민;조승식
    • 한국의류학회지
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    • 제18권3호
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    • pp.287-297
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    • 1994
  • The purpose of this study is to investigate the Improvement of fiber surface, tenacity & elogation, fabric counts, thickness, handle, moisture regain, static voltage, handle, dyeability when polyester fabrics are treated with NaOH solution adding quartemary ammonium salt (Benzyl dimetyl dodecyl ammonium chloride . BDMDAC) The results are as follows. I. In regard to the method of processing VET, when the PET fabrics are alkaline-hydrolyzed adding BDMDAC, the weight loss of PET fabrics increased remarkably to the increse of BDMDAC concentration than when they are treated only in NaOH solution. When PET fabrics are alkaline-hydrolyzed the amount of BDMDAC as the catalyst is proper lg/1 II. The change in physical & chemical properties of alkaline-hydrolyzed PET fabrirs. 1. As the amount of the weight loss on PET fabrics increased, the void space of the PET yale increased but tenacity & elongation and thickness decreased. 2. The fabric counts of PET increased due to shrinkage by alkaline-hydrolydzing. 3. As the amount of of the weight loss on PET fabrics increased. NUMERI, FUKURAMI, increaseed and KOSHI decreased and Total hand value(T.H.V) in all cases increaseed. When the weight Ioss is 30.9% T.H.V. is best. 4. Moisture regain of PET fabrics a little increased by alkaline-hydrolyzing treatment. As the weight loss increased, static voltage is decreased. 5. The last dye absorption is different according to the degree of the Affinity. In regard to the difference of dye color, the dyestuff of low molecular weight dyed for deep color.

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사급암모늄염/수산화나트륨용액에서 폴리에스테르 직물의 알칼리처리에 관한 연구 (A Study on Polyester Fabric treated with Quarternary Ammonium Salt and Alkali)

  • 류효선
    • 대한가정학회지
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    • 제25권4호
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    • pp.9-18
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    • 1987
  • This study is conducted to investigate the influence of addition of quarternary ammonium salt(cetyl trimethyl ammonium bromide: CTAB) when polyester(PET) fabric is treated with sodium hydroxide(NaOH), depending on experimental variables such as CTAB concentration, NaOH concentration, time & temperature, and the change in physical & chemical properties of alkaline-hydrolyzed PET fabrics depending on their weight loss. The results are as follows: 1. By adding CTAB in aqueous NaOH, the weight loss of PET fabric is increased remarkably and until the concentration of CTAB is reached at its cmc, and the higher the concentration of CTAB are, the more weight loss on PET fibrics are. 2. The addition of CTAB in aqueous NaOH is most effective at lower NaON concentration(2%) among various NaOH concentration, on increasing the amount of weight loss, while there are almost similar results through various treatment time and temperature. 3. As the amount of weight of weight loss on PET fabric is increased, the increase of void space in the PET yarn, of softness & dyeability of PET fabric and the decrease of tensile strength are found. On the other hand, the moisture regain shows a little increase by alkaline-hydrolysis on PET fabric while vertical absorption test & water retention value are not sufficiently sensitive to distinguish between the hydrophillicity of untreated and treated PET fabric. The shrinkage of PET fabric is induced by swelling in hot aqueous NaOH regardless of NaOH concentration & addition of CTAB.

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규불화염계 복합 조성물을 사용한 콘크리트의 수밀특성에 관한 실험적 연구 (Experimental Study on Watertightness Properties of Concrete Using Fluosilicates Based Composite)

  • 정원섭;박동수;권기주;김정우;김도수
    • 한국콘크리트학회:학술대회논문집
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    • 한국콘크리트학회 2008년도 춘계 학술발표회 제20권1호
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    • pp.429-432
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    • 2008
  • Large area members such as foundation concrete of underground structures in power plants have an effect on structural stability and durability of the structure due to danger of crack occurrence and shrinkage crack that occur owing to the difference of temperature by heat of hydration between inside and outside of the members at initial age. And a construction for waterproofness is performed additionally to protect marine structures from osmosis of seawater because the structures adjoin below the surface of sea. So, if a rise of the heat of hydration, crack, and corrosion of bars are controled effectively using a composite such as fluosilicate salt in concrete production process of a initial construction, expenses are cut down and construction hours are reduced by securing durability through improvement of watertightness. The property tests of adiabatic temperature by hydration are carried out at initial age about standard concrete and test concrete using a fluosilicate salt composite to evaluate an effect on improvement of watertightness for concrete structures in this study. And the experiments such as a permeability test of hardened concrete, a water absorption test, a compression strength test and a elongation test are carried out and the results from these are described.

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규불화염계 수화열 저감제가 첨가된 시멘트 모르타르의 수화열 변화 및 균열저감 특성 (Hydration Heat and Crack-Reducing Properties of Cement Mortar Added Fluosilicate Salt Based Hydration Heat Reducer)

  • 김진용;이효송;이영우;김도수;이병기;길배수;한승구
    • 한국세라믹학회지
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    • 제42권3호
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    • pp.198-204
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    • 2005
  • 본 연구에서는 규불화염, 가용성 실리카, 방향족계 고분자 축합물 그리고 잠열특성을 지닌 질산염계 무기화합물로 구성된 규불화염계 수화열 저감제를 시멘트 모르타르의 수화열 및 건조수축에 미치는 영향을 조사하였다. 규불화염계 수화열 저감제의 첨가로 시멘트 모르타르의 단열상승온도 및 건조수축에 의한 길이변화가 저감되는 특성을 나타내었다. 또한, 규불화염계 수화열 저감제가 첨가된 판상형 시멘트 모르타르 시험체의 균열 패턴을 측정한 결과, 수화열 저감과 건조수축에 의해 길이변화가 저감되는 복합적 효과를 통해 시멘트 모르타르의 균열저감성이 개선되는 것을 확인하였다.