• Title/Summary/Keyword: salt removal

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Preparation and Characterisation of Titanium Dioxide Produced from Ti-salt Flocculated Sludge in Water Treatment (수처리 티탄염 응집 슬러지에서 생산한 산화티탄의 제조와 특성 조사)

  • Shon, Hokyong;Okour, Yousef;Saliby, Ibrahim El;Park, Jun;Cho, Dong-Lyun;Kim, Jong Beom;Park, Hee Ju;Kim, Jong-Ho
    • Applied Chemistry for Engineering
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    • v.20 no.3
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    • pp.241-250
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    • 2009
  • During the past few years, titanium salts were investigated as alternative coagulants for the removal of organic matter of different molecular sizes in contaminated water. The flocculation efficiency of Ti-salt was comparable to those of $FeCl_3$ and $Al_2(SO_4)_3$ salts, commonly used coagulants. Incinerated sludge-$TiO_2$ showed higher surface area and photocatalytic activity than commercially available $TiO_2$. Metal-doped forms were produced by adding coagulant aids such as iron (Fe-), aluminium (Al-) and (Ca-) calcium salts during Ti-salt flocculation to increase pH. Ca- and Al- doped $TiO_2$ showed very high photocatalytic activity compared to Fe-doped $TiO_2$. When tested in a pilot scale plant for treatment of dye wastewater to check practical feasibility of the novel process, the removal ratio of the chemical oxygen demand was comparable to those of commonly used coagulants but the settling of sludge was faster. The $TiO_2$ generated after sludge incineration showed a high photocatalytic activity for degradation of volatile organic compounds and increased the rate of hydrogen production by water photosplitting. $TiCl_4$ coagulant and $TiO_2$ produced from different water sources with different concentrations had low acute toxicity compared to heavy metals and commercial $TiO_2$ when examined based on D. Magna mortality. This paper presents the production, characterisation and the photoactivity of $TiO_2$ produced from Ti-salt flocculated sludge. Different case studies are discussed to highlighted recent advances in this field.

One-Step Purification of Melittin Derived from Apis mellifera Bee Venom

  • Teoh, Angela Ching Ling;Ryu, Kyoung-Hwa;Lee, Eun Gyo
    • Journal of Microbiology and Biotechnology
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    • v.27 no.1
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    • pp.84-91
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    • 2017
  • The concern over the use of melittin in honey bee venom due to its adverse reaction caused by allergens such as phospholipase A2 ($PLA_2$) and hyaluronidase (HYA) has been an obstacle towards its usage. We developed a novel single-step method for melittin purification and the removal of $PLA_2$ and HYA. This study explores the influence of pH, buffer compositions, salt concentration, and types of cation-exchange chromatography resins on the recovery of melittin and the removal of both HYA and $PLA_2$. Melittin was readily purified with a strong cation-exchange resin at pH 6.0 with sodium phosphate buffer. It resulted in a recovery yield of melittin up to 93% (5.87 mg from a total of 6.32 mg of initial melittin in crude bee venom), which is higher than any previously reported studies on melittin purification. $PLA_2$ (99%) and HYA (96%) were also successfully removed. Our study generates a single-step purification method for melittin with a high removal rate of $PLA_2$ and HYA, enabling melittin to be fully utilized for its therapeutic purposes.

Removal and Decomposition of Organochlorine Compounds in Water Using UV Irradiation (자외선에너지를 이용하여 물속에 함유된 유기염소계 화합물의 분해 및 제거)

  • Kim, Jong Hyang
    • Applied Chemistry for Engineering
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    • v.10 no.1
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    • pp.30-34
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    • 1999
  • Photolysis behavoirs of pesticides(Chlorothalonil and Endosulfan) over UV irradiation UV irradiation with pH 3.0 and irradiation with 3.5% salt were studied. The analyses of pesticides were carried out using gas chromatograph with an electron-capture detector, total organic carbon, and Ion chromatograph, respectively. The reactions were conducted in a alumium annular reactor equipped with a low pressure mercury multilamp ($8W{\times}6$) and initial concentration was 10 ppm. Chlorothalonil was almost photodegraded by UV irradiation, UV irradiation with pH 3.0 and 3.5% salt within 30 min of reaction time. Endosulfan-${\alpha}$,${\beta}$(100%) were photodegraded to 38% of Endosulfan-${\alpha}$ and 25% of Endisulfan-${\beta}$ by UV irradiation. Endosulfan-${\alpha}$(83%) was photodegraded to 66% by UV irradiation, 70% by UV irradiation and pH 3.0 and 75% by UV irradiation and 3.5% salt. Endosulfan-${\beta}$(16%) was photodegraded to 80% by UV irradiation, 98% by UV irradiation and pH 3.0 and 90% by UV irradiation and 3.5% salt.

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Effect of gas hydrate process on energy saving for reverse osmosis process in seawater desalination plant (해수담수화플랜트에서 가스 하이드레이트 공정 도입을 통한 역삼투 공정의 에너지 절감 효과)

  • Kim, Suhan;Lim, Jun-Heok
    • Journal of Korean Society of Water and Wastewater
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    • v.27 no.6
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    • pp.771-778
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    • 2013
  • Gas hydrate (GH) process is a new desalination technology, where GH is a non- stoichiometric crystalline inclusion compounds formed by water and a number of gas molecules. Seawater GH is produced in a low temperature and a high pressure condition and they are separated from the concentrated seawater. The drawback of the GH process so far is that salt contents contained in its product does not meet the fresh water quality standard. This means that the GH process is not a standalone process for seawater desalination and it needs the help of other desalting process like reverse osmosis (RO). The objective of this study is to investigate the effect of GH process on energy saving for RO process in seawater desalination. The GH product water quality data, which were obtained from a literature, were used as input data for RO process simulation. The simulation results show that the energy saving effect by the GH process is in a range of 68 % to 81 %, which increases as the salt removal efficiency of the GH process increases. Boron (B) and total dissolved solids (TDS) concentrations of the final product of the hybrid process of GH and RO were also investigated through the RO process simulation to find relavant salt rejection efficiency of the GH process. In conclusion, the salt rejection efficiency of the GH process should exceed at least 78% in order to meet the product water quality standards and to increase the energy saving effect.

A Study on Mixed Noise Removal using Pixel Direction Factors and Weighted Value Mask (화소의 방향요소 및 가중치 마스크를 이용한 복합잡음 제거에 관한 연구)

  • Kwon, Se-Ik;Kim, Nam-Ho
    • Journal of the Korea Institute of Information and Communication Engineering
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    • v.19 no.11
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    • pp.2717-2723
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    • 2015
  • Recently, digital image processing is being applied in various areas of broadcasting, communication, computer graphic and medical science. But, degradation of images occurs in the process of digital image acquisition, processing and transmission. Therefore, in order to remove the mixed noise, this paper suggested the image restoration algorithm to process salt and pepper noise with weighted filters according to 4 direction pixel changes after judging the noise and to process AWGN with weighted filters which have individually different characteristics. Regarding the processed results by applying Boat images which were corrupted by salt and pepper noise(P=40%), suggested algorithm showed the improvement by 1.33[dB], 1.41[dB], 0.51[dB] respectively compared with the existing CWMF, AWMF, MMF.

Noise Removal of Image Signals using Inflection Points on Histogram (히스토그램의 변곡점을 이용한 영상 신호의 잡음 제거)

  • Baek, Ji-Hyeon;Kim, Nam-Ho
    • Journal of the Korea Institute of Information and Communication Engineering
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    • v.24 no.11
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    • pp.1431-1436
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    • 2020
  • In modern society, various video devices such as CCTV and black boxes are used for convenience. However, noise is frequently generated in the process of transmitting and receiving video images and video signals photographed at night. If such noise is not eliminated, the problem that the image is difficult to identify is generated. Accordingly, noise elimination of images in the image information is an indispensable step. Salt and Pepper noises are typical impulse noises among image noises. Previous research has been carried out as a method for eliminating noise, and CWMF, MMF and A-TMF are typical methods. In common, such a filter exhibits excellent performance in a low-density noise area, but a disadvantage is that noise elimination performance in a high-density noise area is somewhat insufficient. Accordingly, the proposed algorithm uses the inflection point of the histogram graph to separate areas and remove singular points, and proposes a weighting filter utilizing histogram distribution. PSNR was used for objective judgment.

NO3-N Removal of A Reed Wetland Cell Constructed for Purifying Effluent from A Night Soil Treatment Plant During Its Initial Operating Stage (분뇨처리장 방류수정화 갈대습지셀의 초기운영단계 질산성질소 제거)

  • Yang, Hongmo
    • Journal of the Korean Society of Environmental Restoration Technology
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    • v.7 no.5
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    • pp.100-106
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    • 2004
  • $NO^3$-N removal was examined from July 2002 to December 2002 of a surface-flow constructed treatment wetland cell, which was a part of a treatment wetland system composed of four wetland cells and one distribution pond. The system was established on rice paddy near the Kohung Estuarine Lake located at the southern part of the Korean Peninsula. The lake and the paddy were formed by a salt marsh reclamation project. Effluent from a secondary-level treatment plant was funneled into the system. The investigated cell was created in June 2002. Its dimensions were 87 m in length and 14 m in width. It had an open water zone at its center, which was equivalent to 10 percent of its total area. Reeds(Phragmites australis) were transplanted from natural wetlands into the cell and their stems were cut at about 40 cm height from their bottom ends. Average 25 $m^3$/day of effluent from the plant was funneled into the cell by gravity flow and average 24.2$m^3$/day of its treated effluent was discharged into the Sinyang Stream flowing into the lake. Its water depth was maintained about 0.2 m and its hydraulic detention time averaged 5.2 days. The average height of the reed stems was 45.2 cm in July 2002 and 80.5 cm in September 2002. The number of stems averaged 40.3 stems/$m^2$ in July 2002 and 74.5 stems/$m^2$ in September 2002. The reeds were established initially well. $NO_3$-N loading rate of influent and effluent averaged 173.7 and $93.5mg/m2{\cdot}day$, respectively. Removal of $NO_3$-N averaged $80.2mg/m2{\cdot}day$ and its removal rate by mass was about 50 %. Considering the initial operation of the cell and the inclusion of the cold months of November and December in the analysis period, the $NO_3$-N removal rate was good.