• Applied Chemistry for Engineering
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• v.26 no.4
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• pp.458-462
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• 2015

It is essential to employ a binder to prepare transparent films from conductive polymer such as poly(3,4-ethylenedioxythiophene)-poly(styrene sulfonate) (PEDOT/PSS). In this paper, poly(vinyl alcohol) (PVA), poly(vinyl pyrrolidone) (PVP), and PSS were selected as a binder, and their effects were investigated. The formation of the film was found to be primarily dependent on the surface tension of coating solution including PEDOT/PSS and a binder. When PSS was used as a binder, the film was not formed. In case of using PVP, it was easily peeled off from the substrate. However, when using the PVA or the mixtures of PVA and PSS or PVA and PVP as a binder, films with good transparency and uniform surface resistances were produced. Based on adhesion and long-term stability tests, we concluded that the mixture of PVA and PSS is the best binder for preparing antistatic films of PEDOT/PSS.

• Polymer(Korea)
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• v.32 no.6
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• pp.587-592
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• 2008

High molecular weight poly(vinyl alcohol) (PVA) hydrogel to be expected as a candidate material for the wound-dressing was successfully prepared by electron beam (EB) irradiation. To produce PVA hydrogels with various gel fractions, degrees of swelling in water, gel strengths, and elongations, two different number-average degrees of polymerization [($P_n$)s] of PVA were adapted such as 1700 and 4000, and the PVA solution concentration and irradiation dose of EB were controlled to range of 5 $\sim$ 20% and 30 $\sim$ 100 kGy, respectively. The gel fraction and strength of PV A hydrogel were increased with increasing molecular weight of PVA, solution concentration, and irradiation dose of EB. On the contrary, the degree of swelling and elongation of PVA hydrogel were decreased. The thermal property and crystallinity related to degree of crosslinking of PVA hydrogel were examined by the analyses of differential scanning calorimetry and X-ray diffraction.

• Applied Chemistry for Engineering
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• v.7 no.2
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• pp.379-386
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• 1996

Photosensitive compound, 1-methyl-4-[2-(4-diethylacetylphenyl)ethenyl] pridinium methosulfate(SbQ-A salt), was synthesized from dimethyl sulfate, terephthalaldehyde mono-(diethylacetal) and 4-picoline. SbQ-A salts were reacted with poly(vinyl alcohol)s, (PVA) in aqueous solution with phosphoric acid as catalyst to give photosensitive PVA-SbQ with different SbQ content and molecular weight. Relative photosensitivity of PVA-SbQ was determined by gray scale(GS) method. The rotative sensitivity of PVA-SbQ increased with increasing amount of bound SbQ in the case of high molecular weight(MW=77,000-79,000g/mol) as substrate and decreased with decreasing molecular weight of PVA with about constant(1.3mol%) amount of bound SbQ. The most sensitive polymer was obtained when SbQ group content in PVA-SbQ reached about 2.63mol% in the case of high molecular weight(77,000-79,000g/mol) PVA. This sample showed 90 times greater sensitivity than dichromated PVA as reference photosensitive system. PVA-SbQ photosensitive polymer synthesized was applied to the photolithographic screening process of phosphor on the panel of cathode ray tube(CRT). Phosphor slurry was made with PVA-SbQ, phosphor, a small amount of surfactant and other additives using water as medium. The slurry was coated onto panel, dried by heater, exposed to UV light and then developed by distilled water. When a small amount of cationic surfactant such as cetyltrimethylammonium chloride was used in the slurry formulation, the sharpness of phosphor pattern was equal to or better than that of dichromated PVA photosensitive polymer system used currently.

• Journal of the Korean Applied Science and Technology
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• v.38 no.1
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• pp.178-185
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• 2021

In this study, polyvinyl alcohol (PVA) and polypropylene glycol (PPG)-based polyurethane dispersion resin for wound coating was synthesized. And the physical properties of the sample were coated on the surface of the film sample and the leather (Full-Grain) to study the physical properties change. In the case of tensile strength, PUD-PA1, which reacted with the least amount of PVA, showed the highest resistance at 2.00 kgf/㎟. Likewise, the rate of elongation was measured as high as 554% for PUD-PA1, which reacted with the least amount of PVA. The abrasion resistance measurement result showed that as the PVA response increased, the strength of the surface decreased to 36.77 mg.loss.

• Journal of the Korean Electrochemical Society
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• v.2 no.1
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• pp.5-12
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• 1999

By the PVA-precursor method, polycrystalline powder of $Li_xNi_{1-y}Co_yO_2$, cathode material for lithium battery, was synthesized. Using the powder as the cathode material, lithium ion batteries were fabricated, whose electrochemical properties were measured. The effect of changing synthetic conditions, such as PvA/metal mole ratio, concentration of PVA, degree of polymerization of PVA, pyrolysis condition, and metal stoichiometry, on the battery performance was investigated. Considering the initial performance of the cell, the optimum stoichiometry of the $Li_xNi_{1-y}Co_yO_2$, synthesized by the PVA-precursor method was observed to be x: 1.0 and y=0.26. A minor phase of $Li_2CO_3$, which was generated by the residual carbon in the powder precursor, deteriorated the performance of the cell. In order to eliminate the minor phase, the precursor had to be pyrolyzed under the flow of dry air. Annealing the powder at $500^{\circ}C$ under the flow of dry air also eliminated the minor phase, and the performance of the cell was largely improved by the treatment.

• Proceedings of the Korea Concrete Institute Conference
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• 2008.04a
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• pp.913-916
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• 2008

Direct tensile response of strain hardening cement composites(SHCC) depends primarily on the material's tensile response, which is a water cement ratio, direct function of fiber and matrix characteristics, the bond between them, and the fiber volume fraction. This paper discusses effect of aspect ratio of the direct tensile response of SHCC with PET and PVA fibers. The main variables considered include the aspect ratio of PET fibers(Aspect ratio, ${\ell}/d_f$ : 150, 300, 600). For the same mixture proportion, PET1.5+PVA0.5-300 and PET1.5+PVA 0.5-600(Aspect ratio 300, 600) showed better overall behavior(Pseudo strain-hardening, Multiple cracking) than specimens with PET1.5+PVA0.5-150(Aspect ratio 150). Tensile strain of PET1.5+PVA0.5-300 and PET1.5+PVA 0.5-600 at ultimate tensile stress were 0.5, 2.0% respectively.

• Journal of the Korea Safety Management & Science
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• v.22 no.1
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• pp.15-21
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• 2020

Industrial Motors diagnostic equipment is highly dependent on the automation system, so if there are defects in the automation equipment, it can only rely on the operator's intuitive judgment.To help with intuitive judgment, Park's Vactor Approach(PVA) represents the current signal as a pattern of circles, so it can tell if a fault occurs when the circle is distorted. However, the failure to judge the degree of distortion of the circle pattern is the basis of the fault, so it will face difficulties. In this paper, in order to compare the faults of PVA, the period of d-axis current of PVA pulsation was mastered, so that two phase differences occurred in the same signal source. Through experiments, it is confirmed that this is a 90 degree cross formation of PVA, which is convenient for judging from the vision that there is no fault, thus helping the operator to make intuitive judgment.

• Textile Coloration and Finishing
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• v.22 no.3
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• pp.187-193
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• 2010

The effects of molecular weight (MW) and concentration on the rheological properties of poly(vinyl alcohol) (PVA) solutions in dimethyl sulfoxide (DMSO) were investigated at $30^{\circ}C$. Ubbelohde viscometer and rotational rheometer were employed for dilute and concentrated regime, respectively. In the dilute regime, the Mark-Houwink exponent ($\alpha$) of the solutions determined from three different MWs proved 0.73. The critical concentration (C*), in which the entanglement and overlap of polymer molecules began to take place, decreased with increasing the MW of PVA. Huggins constant ($K_H$) values ranged from 0.33 to 0.45 over the MW examined. In the log-log plot of $\eta_{sp}$ versus [$\eta$]C, the PVA with higher degree of polymerization (DP) gave a greater slope exhibiting the inflection point in the vicinity of C*. In the dynamic viscosity ($\eta'$) curve, the PVA solutions of DP 1700 presented Newtonian fluid behavior over most of the frequency range examined. However, the lower Newtonian flow region reduced with increasing the DP. As the PVA concentration increased, $\eta'$ was increased and the onset shear rate for pseudoplasticity was decreased. In the Cole-Cole plot, PVA solutions showed almost a single master curve in a slope of ca. 1.65 regardless of the DP. However, the increase of the concentration from 8 to 12 wt% for PVA solutions of DP 5000 decreased the slope from 1.73 to 1.57. In the tan $\delta$ curve, the onset frequency for sol-gel transition was shifted from 154 to 92 rad/s with increasing the DP from 3300 to 5000 and from 192 to 46 rad/s with increasing the concentration from 8 to 12 wt%. In addition, longer relaxation time ($\lambda$) was observed with increasing the DP and concentration.

• 한국정보디스플레이학회:학술대회논문집
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• 2005.07a
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• pp.15-20
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• 2005

We have achieved 180-degree angle of view performance using Super-PVA (S-PVA) technology first time in TFT-LCD industry. 82" full high definition ($1920{\times}1080$) TFT- LCD panel, the world's largest TFT-LCD, have been developed. In addition to the size breakthrough, this product achieves 600nits brightness, over 1200:1 contrast ratio, viewing angle free, 92% color gamut, and 8ms response time. Several key enabling technologies were developed to achieve these specifications, including two transistor direct driven independently controlled S-PVA subpixels, non even area ratio sub-pixels for optimal offaxis gamma, gate overlap driving for larger driving margin, new CCFL technology for higher color gamut, and advanced fabrication techniques including the use of Samsung's new $7^{th}$ generation line.

• Journal of IKEEE
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• v.26 no.1
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• pp.104-110
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• 2022

In this paper, we propose a new dataset for AI diagnosis and BLDC motor diagnosis in UAV. In the diagnosis of BLDC motor, PVA(Park's Vector Approach) is difficult to apply due to many ripples of frequency components. However, since the components of ripples are the third harmonics, we propose a method to utilize PVA as circle fitting by applying Savitzky-Golay filter which is excellent for the third harmonics. On the other hand, PVA, a technique to convert from three-phase to two-phase, is always based on the origin during the transformation process. This study demonstrates that the error of the origin and the measured center can be detected and diagnosed in the application process of Circle fitting, and that it can be used as a new data set of AI technology.