• Title/Summary/Keyword: s-PVA

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A Study on the Development of Plat-Ring Restrained Test Method for Evaluating Early Age Shrinkage Crack of Concrete (콘크리트의 초기수축균열 평가를 위한 판상-링형 구속시험방법 개발에 관한 연구)

  • Nam, Jeong-Soo;Park, Yoon-Mi;Kim, Young-Sun;Kim, Young-Duck;Kim, Gyu-Yong;Kim, Moo-Han
    • Proceedings of the Korea Concrete Institute Conference
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    • 2008.04a
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    • pp.821-824
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    • 2008
  • In this study, it is willing to present that fundamental data for proposing quantitatively shrinkage cracking evaluation method such as plat-ring type restrained test method. It is possible to decide that specimen diameter is s 150mm with evaluating restrained shrinkage crack properties of concrete according to change of ring diameter in specimen. Also, effectiveness of test method according to mixing of PVA fiber is evaluated as part of a repeatability verification experiment of plat-ring type restrained test method using ring which diameter is 150mm. As a result, it is possible to measure the crack due to the plastic shrinkage which was occurred within 48hours at early age with plat-ring type restrained test method. Hereafter, it is considered that the study concerning environmental condition and mixing factor in plat-ring type restrained test method is need.

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Fabrication of Polymeric Microcapsules in a Microchannel using Formation of Double Emulsion (마이크로채널 내 이중유화 액적 형성을 통한 마이크로캡슐 제조)

  • Nam, Jin-Oh;Choi, Chang-Hyung;Kim, Jongmin;Kang, Sung-Min;Lee, Chang-Soo
    • Korean Chemical Engineering Research
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    • v.51 no.5
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    • pp.597-601
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    • 2013
  • In this study, we present simple microfluidic approach for the synthesis of monodisperse microcapsules by using droplet-based system. We generate double emulsion through single step in the microfluidic device having single junction while conventional approaches are limited in surface treatment for the generation of double emulsion. First, we have injected disperse fluid containing FC-77 oil and photocurable ethoxylated trimethylolpropane triacrylate (ETPTA) and water containing 3 wt% poly(vinyl alcohol) (PVA) as continuous phase into microfluidic device. Under the condition, we easily generate double emulsion with high monodispersity by using flow focusing. The double emulsion droplets are transformed into microcapsules under the UV irradiation via photopolymerization. In addition, we control thickness of double emulsion's shell by controlling flow rate of ETPTA. We also show that the size of double emulsions can be controlled by manipulation of flow rate of continuous phase. Furthermore, we synthesize microcapsules encapsulating various materials for the application of drug delivery systems.

Characteristics of Immobilized Rhodopseudomonas sp. for Wastewater Treatment (폐수처리를 위한 고정화 Rhodopseudomonas sp.균의 특성)

  • 이범규;김상희;김중균
    • Journal of Life Science
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    • v.9 no.3
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    • pp.268-275
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    • 1999
  • Rhodopseudomonas sp. was immobilized in three supports(agar, k-carrageenan, and PVA) in order to remove nitrate in wastewater coming from fish farm. Among them 3% agar was the most suitable support when denitrification rate and bead durability were tested. Optimum bead size was 4mm-diameter when the substrate transfer into the bead and shear stress for bead were considered, and optimum cell loading was 25mg dry $cells/cm^2$gel gel. Ethanol was the best as a carbon source, and optimum C:N ratio, temperature and pH were 1.5:1, $31^{\circ}C$,, and 6, respectively. Under these conditions the maximum denitrification rate in synthetic wastewater was $$345{\MU}{\ell};N_2/Cm^3 gel{\cdot}hr;and that in modified MYC medium was 450{\MU}{\ell}};N_2/Cm^3 gel{\cdot}hr $$.

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A Broadband High Gain Planar Vivaldi Antenna for Medical Internet of Things (M-IoT) Healthcare Applications

  • Permanand, Soothar;Hao, Wang;Zaheer Ahmed, Dayo;Falak, Naz;Badar, Muneer;Muhammad, Aamir
    • International Journal of Computer Science & Network Security
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    • v.22 no.12
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    • pp.245-251
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    • 2022
  • In this paper, a high gain, broadband planar vivaldi antenna (PVA) by utilizing a broadband stripline feed is developed for wireless communication for IoT systems. The suggested antenna is designed by attaching a tapered-slot construction to a typical vivaldi antenna, which improves the antenna's radiation properties. The PVA is constructed on a low-cost FR4 substrate. The dimensions of the patch are 1.886λ0×1.42λ0×0.026λ0, dielectric constant Ɛr=4.4, and loss tangent δ=0.02. The width of the feed line is reduced to improve the impedance bandwidth of the antenna. The computed reflection coefficient findings show that the suggested antenna has a 46.2% wider relative bandwidth calculated at a 10 dB return loss. At the resonance frequencies of 6.5 GHz, the studied results show an optimal gain of 5.82 dBi and 85% optimal radiation efficiency at the operable band. The optometric analysis of the proposed structure shows that the proposed antenna can achieve wide enough bandwidth at the desired frequency and hence make the designed antenna appropriate to work in satellite communication and medical internet of things (M-IoT) healthcare applications.

A Study on the Thermal Stability of Polymer Mixtures using Air Bags (에어백용 고분자 혼합물의 열안정성에 관한 연구)

  • Oh, Yang-Hwan;Park, Keun-Ho
    • Journal of the Korean Applied Science and Technology
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    • v.20 no.4
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    • pp.353-357
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    • 2003
  • Sodium azide (SA) is commonly used as propellant for inflating automatic safety bags and other chemical manufacturing purposes. The investigation of potentially thermal hazard of sodium azide and its mixture with polymers are very important because it can occur an expected traffic accident so we took a experiment s using different scanning calorimeter (DSC) in nitrogen atmosphere. The decomposition temperature were about $350{\sim}450^{\circ}C$. We could find not only exothermic reaction was remarkably decreased in mixture s of acrylonitrile-butadiene-styrene (ABS) and polyvinyl chloride (PVC), but also increasing mixed rate of ABS, polyvinyl alcohol (PVA) and polymethyl methacrylate (PMMA) decreased thermal decomposition heat.

Chromosomal Analysis of Hanwoo Embryos by In Vitro Culture Condition (한우 체외 수정란의 체외 배양 조건에 따른 염색체 분석)

  • Choi, S.H.;Cho, S.R.;Han, M.H.;Kim, H.J.;Choe, C.Y.;Son, D.S.;Chung, Y.G.;Kim, S.K.;Sohn, S.H.
    • Journal of Embryo Transfer
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    • v.22 no.2
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    • pp.137-141
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    • 2007
  • Antioxidants were well known to be essential supplements in the complex media and serve as a reservoir of oxygen. In this study, Hanwoo COCs (cumulus oocytes complexes) were matured and developed in L-cysteine-TCM199 and analyzed metaphase chromosome. Maturation rate of Hanwoo COCs were 73.4%, 94.6% in 0.1% PVA, 0.1 mM L-cysteine, respectively and showed significantly different between the treatments (p<0.05). Blastocyst formation were revealed 20.3%, 10.0% in 5% FBS+TCM199, 0.1 mM L-cysteine+1% BSA, respectively. There were no significant difference among treatment groups. Metaphase chromosome were showed 18.3%, 12.0% in 5% FBS-TCM199, 0.1 mM L-cysteine, respectively and analyzable chromosome were 6.1%, 4.0% and had no differences between the treated groups. In the case of in vitro developmental stages, metaphase chromosome were showed 18.3%, 12.0% in $4{\sim}16$ cells stage, 43.1%, 13.0% in morulae stage and 94.8%, 100.0% in blastocyst stage. These results suggested L-cysteine has beneficial role for in virto maturation and development in Hanwoo COCs.

Preparation and Characterization of PVA/PAM Electrolyte Membranes Containing Silica Compounds for Direct Methanol Fuel Cell Application (실리카 화합물을 함유한 PVA/PAM 전해질 막의 제조 및 특성과 직접메탄올 연료전지로의 응용)

  • Yoon, Seok-Won;Kim, Dae-Hoon;Lee, Byung-Seong;Lee, Bo-Sung;Moon, Go-Young;Byun, Hong-Sik;Rhim, Ji-Won
    • Polymer(Korea)
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    • v.34 no.1
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    • pp.45-51
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    • 2010
  • This study focuses on the investigation of the possibility of the crosslinked poly (vinyl alcohol) membranes with both poly (acrylic acid-co-maleic acid) (PAM) and 3-(trihydroxysilyl)-1-propane-sulfonic acid (THS-PSA) for the direct methanol fuel cell application. In order to characterize the prepared membranes, the water content, the thermal gravimetric analysis, the ion exchange capacity, the ion conductivity and the methanol permeability measurements were carried out and then compared with the existing Nafion 115 membrane. The ion exchange capacity of the resulting membranes showed 1.6~1.8 meq./g membrane which was improved than Nafion 115, 0.91 meq./g membrane. In the case of the proton conductivity, the THS-PSA introduced membranes gave more excellent $0.042{\sim}0.056\;S{\cdot}cm^{-1}$ than Nafion 115, $0.024\;S{\cdot}cm^{-1}$. On the other hand, the methanol permeability was increased more than Nafion 115 for all the range of THA-PSA concentration.

Fracture Characteristics of Ductile Fiber Reinforced Cement based Composites by Collision of Steel Projectile (비상체의 충돌에 의한 고인성 섬유보강 시멘트복합체의 파괴특성)

  • Nam, Jeong-Soo;Kim, Gyu-Yong;Kim, Hong-Seop;Kim, Jung-Hyun;Han, Sang-Hyu
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.19 no.4
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    • pp.92-100
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    • 2015
  • The aim of this study is to evaluate the fracture characteristics of ductile fiber reinforced cement based composites with 1.5 volume ratio of polyvinyl alcohol and steel fiber by high velocity impact of steel projectile. We used gunpowder impact facility to evaluate the fracture characteristics of ductile fiber reinforced cement based composites by collision of steel projectile, and the impact velocity was from about 150 to 1,000m/s. The results of evaluation on the fracture characteristics of ductile fiber reinforced cement based composites were penetration grade, which is the kinetic energy more than three times of no-fiber reinforced specimen (Plain). In addition, ductile fiber reinforced cement based composites did not occurred critical damage other than the debris. In the case of mass loss, Plain specimen was proportional to kinetic energy of steel projectile, while ductile fiber reinforced cement based composites was not significantly affected by kinetic energy of steel projectile. In particular, this tendency had a close relationship with the fracture characteristics of back side of specimens, and the scabbing inhibiting efficiency of PVA specimen was higher than S specimen. In the results of verifying relationship between front and back side calculated by local damage, scabbing occurred at the region close to the back side in the ductile fiber reinforced cement based composites unlike Plain specimen. Thus, in this study, we examined principal fracture behaviors of ductile fiber reinforced cement based composites under collision of steel projectile, and verified that impact resistance performance was improved as compared to Plain specimen.

Preparation and Characterizatino of Nano-sized Liposome Containing Proteins Derived from Coptidis rhizoma (황련유래 단백질이 함유된 나노리포좀의 제조 및 특성)

  • Oh, Seng Ryong;Lee, Sang Bong;Cho, Kye Min;Choi, Moon Jae;Jin, Byung Suk;Han, Yong Moon;Lee, Young Moo;Shim, Jin Kie
    • Applied Chemistry for Engineering
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    • v.17 no.1
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    • pp.52-57
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    • 2006
  • Coptidis Rhizoma, an antimicrobial agent from natural source, is known to have the antiviral effect on the Candida albicans that causes the infectious dermatitis. The valuable protein was extracted from the Coptidis Rhizoma, To prevent denaturalization from external stimulus and improve adsorption onto the skin, the nano-sized liposomes were prepared as a carrier. The CPR-containing liposomes showed an average diameter of 187 nm, surface charge of 3.337 mV and 33% encapsulation efficiency. The release behavior of CRP from the liposome was investigated with various temperature and releasing time. The PVA solution was coated on the surface of liposome to improve the stability. The coated liposome showed slow release behavior in comparison with the non-coated liposome. The CRP in the liposome maintained the effect on the Candida albicans after treating it at 50 and with ultraviolet for 24 h.

Poly(vinyl alcohol) based Solid Polymer Electrolyte with Fast Cationic Transport Process

  • Jo, Yun-Kyung;Lee, Yu-Jin;Jo, Nam-Ju
    • Proceedings of the Polymer Society of Korea Conference
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    • 2006.10a
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    • pp.187-187
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    • 2006
  • A new type solid polymer electrolyte (SPE) composed of poly (vinyl alcohol) (PVA) and lithium trifluoromethanesulfonate ($LiCF_{3}SO_{3}$) was prepared by means of the solution cast technique to observe that Li ion can move by ion hopping decoupled from polymer segmental motion inside of the 'fast cationic transport process'. The highest ion conductivity of the SPEs obtained from ac impedance measurements was $1.42{\times}10^{-3}S/cm$ at room temperature for SPE with 80wt% of salt concentration. Using LSV, we found that the SPEs had good electrochemical stabilities and using FT-IR and AFM, we found the formation of network-like structure.

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