• Safety and Health at Work
• /
• v.5 no.2
• /
• pp.86-90
• /
• 2014

Background: Urinary 1-hydroxypyrene (1-OHP) was selected as a biomarker of polycyclic aromatic hydrocarbons (PAHs) to explore the accumulation level in the bodies of workers at rubber smoke sheet factories in southern Thailand. Methods: Spot urine samples were taken from four groups of workers from June 2006 to November 2007. The nonexposure or control groups included habitual cigarette smokers and nonsmokers. The other two groups were workers exposed to particle-bound PAHs from rubber wood smoke and they were nonsmokers. All spot urine samples were analyzed for 1-OHP and creatinine levels. Results: The mean${\pm}$standard deviation urinary 1-OHP in the control group of habitual smokers and the nonsmokers was $0.24{\pm}0.16{\mu}mol/mol$ creatinine and not-detected to $0.14{\mu}mol/mol$ creatinine, respectively. In the workers, the 1-OHP levels on workdays had no significant difference from the 1-OHP levels on the days off. The yearly average 1-OHP level was $0.76{\pm}0.41{\mu}mol/mol$ creatinine whereas the average 1-OHP level during 10 consecutive workdays was $1.06{\pm}0.29{\mu}mol/mol$ creatinine (p > 0.05). Conclusion: The urinary 1-OHP levels of workers exposed to PAHs were high. The accumulation of 1-OHP in the body was not clear although the workers had long working hours with few days off during their working experience. Therefore, a regular day off schedule and rotation shift work during high productive RSS should be set for RSS workers.

• Journal of the Korean Recycled Construction Resources Institute
• /
• v.8 no.3
• /
• pp.263-268
• /
• 2020

The purpose of this study is to investigate the damping properties of polyurethane composites incorporating waste tire rubber powder and preplaced coarse aggregates. Four types of polyurethane-based composites were manufactured, and longitudinal impact tests were performed. And vibration signals in the time domain and frequency domain were measured and values of damping ratio for each specimen were calculated. Test results showed that the damping ratios of polyurethane composites, in which the amount of polyurethane was reduced by 10.6% and 21.2% through incorporation of rubber particles, were 8.4% and 4.6% lower than that of pure polyurethane. The damping ratio of the polyurethane composite produced in a similar manner to the prepact concrete production method was found to be 22% lower than that of pure polyurethane, however, the amount of polyurethane was reduced by 50% and the stiffness was 25.7 times higher than that of pure polyurethane.

• Journal of the Korean Institute of Gas
• /
• v.2 no.3
• /
• pp.1-11
• /
• 1998

To increase peel strength, low temperature properties and flowability of pressure sensitive adhesives(PSA) used in a heat shrinkable sheet, these properties were evaluated by changing each components in type and content. In this study, Isobutylene-co-Isoprene Rubber (IIR) which has good wetherability was selected as a base polymer. Instead of rosin ester, petroleum resin was selected as a tackifier because of superior peel strength. By decreasing petroleum resin contents, flowability of PSA was decreased. High molecular weight of polybutene was better than low molecular weight for the peel strength of PSA. Large particle size of carbon black showed better properties than small one in peel strength and brittleness temperature. By adding calcium carbonate, the cost of compound was able to be reduced. But it must be used with carbon black.

• Elastomers and Composites
• /
• v.53 no.3
• /
• pp.131-135
• /
• 2018

This study was aimed at improving the white index (WI) to prepare thermally expandable microspheres for wallpaper. In particular, thermally expandable microspheres were prepared for different colloidal silica particle sizes to study thermal properties, foaming ratio, and WI. The spheres obtained from tiny colloidal silica were the best in terms of WI and yellowing. Additionally, thermogravimetric analysis results show that small colloidal silica particles are more likely to be adsorbed physically or chemically to the microsphere surface, thereby improving WI at higher temperatures.

• Elastomers and Composites
• /
• v.58 no.2
• /
• pp.81-86
• /
• 2023

Asphalt pavements are generally composed of fine and coarse aggregates, bitumen, and modifier. Asphalt pavement wear particles (APWPs) are produced by friction between the road surface and the tire tread, and they flow into the environment such as rivers and oceans. Model APWPs were prepared and a single APWP of 212-500 (S-APWP) and 500-1000 ㎛ (L-APWP) was analyzed using thermogravimetric analysis (TGA) to investigate inhomogeneity in the compositions of the APWPs. The reference TGA thermogram was built using thermograms of the raw materials and formulation of the model asphalt pavement. The compositions of the APWPs were different from each other. Ash contents of the APWPs were lower than expected. Inhomogeneity in the total contents of bitumen and modifier was more severe than that in the other components. The inhomogeneity of the S-APWPs was more severe than that of the L-APWPs.

• Tribology and Lubricants
• /
• v.25 no.4
• /
• pp.225-230
• /
• 2009

Seals are very useful machine components in protection of leakage of lubricant or working fluid, and incoming of debris from outside. Various elastomer are widely used as sealing materials and the shaft surfaces are generally coated with high hardness material after heat treatment. It is generally known that the foreign debris and wear particles get stuck into sealing surface, the steel shaft surface can be damaged and worn by mainly abrasive wear. In this paper, using MARC, contact analysis are conducted to show the hard coated steel shaft surface can be fatigue failed by very small elastic particle intervened between seal and steel surface. Variations of contact and von-Mises stress distributions and contact half-widths with interference and coating thickness are presented. The maximum von-Mises stress occurs always in the coating layer or between coated layer/substrate interface. Therefore the coated sealing surface can be fatigued and then failed by very small particles. The results can be used in design of sealing surface and further studies are required.

• The Journal of Advanced Prosthodontics
• /
• v.5 no.3
• /
• pp.234-240
• /
• 2013

PURPOSE. This study evaluated the effectiveness of various methods for removing provisional cement from implant abutments, and what effect these methods have on the retention of prosthesis during the definitive cementation. MATERIALS AND METHODS. Forty implant fixture analogues and abutments were embedded in resin blocks. Forty cast crowns were fabricated and divided into 4 groups each containing 10 implants. Group A was cemented directly with the definitive cement (Cem-Implant). The remainder were cemented with provisional cement (Temp-Bond NE), and classified according to the method for cleaning the abutments. Group B used a plastic curette and wet gauze, Group C used a rubber cup and pumice, and Group D used an airborne particle abrasion technique. The abutments were observed using a stereomicroscope after removing the provisional cement. The tensile bond strength was measured after the definitive cementation. Statistical analysis was performed using one-way analysis of variance test (${\alpha}$=.05). RESULTS. Group B clearly showed provisional cement remaining, whereas the other groups showed almost no cement. Groups A and B showed a relatively smooth surface. More roughness was observed in Group C, and apparent roughness was noted in Group D. The tensile bond strength tests revealed Group D to have significantly the highest tensile bond strength followed in order by Groups C, A and B. CONCLUSION. A plastic curette and wet gauze alone cannot effectively remove the residual provisional cement on the abutment. The definitive retention increased when the abutments were treated with rubber cup/pumice or airborne particle abraded to remove the provisional cement.

• Resources Recycling
• /
• v.23 no.3
• /
• pp.44-50
• /
• 2014

In this study, a method of shear crushing and a two-stage disk mill were introduced to grind the waste tire powder. Rubber chips with various size were obtained during the crushing or grinding step. The two-stage disk mill was composed of two drum-type blades rotating at various speed and in opposite directions. Therefore, more roughly surfaced particles of micronized waste tire powder were obtained using shear crushing rather than using conventional cutting crushing. In this study, the shape of shear-crushed waste tire particles was compared with conventional cutting crushing particles by scanning electron microscope. In addition, the particle size analyzer was employed to determine the appropriate particle size of waste ground tire powders obtained in this study.

• Journal of the Korean Geotechnical Society
• /
• v.24 no.2
• /
• pp.87-97
• /
• 2008

Behaviors of cemented engineered soils, composed of rigid sand particle and soft rubber particle, are investigated under $K_o$ condition. The uncemented and cemented specimens are prepared with various sand volume fractions to estimate the effect of the cementation in mixtures. The vertical deformation and elastic wave velocities with vertical stress are measured. The bender elements and PZT sensors are used to measure elastic wave velocities. After cementation, the slope of vertical strain shows bilinear and is similar to that of uncemented specimen after decementation. Normalized vertical strains can be divided into capillary force, cementation, and decementation region. The first deflection of the shear wave in near field matches the first arrival of the primary wave. The elastic wave velocities dramatically increase due to cementation hardening under the fixed vertical stress, and are almost identical with additional stress. After decementation, the elastic wave velocities increase with increase in the vertical stress. The effect of cementation hinders the typical rubber-like, sand-like, and transition behaviors observed in uncemented specimens. Different mechanism can be expected in decementation of the rigid-soft particle mixtures due to the sand fraction. a shape change of individual particles in low sand fraction specimens; a fabric change between particles in high sand fraction specimens. This study suggests that behaviors of cemented engineered soils, composed of rigid-soft particles, are distinguished due to the cementation and decementation from those of uncemented specimens.

• Resources Recycling
• /
• v.24 no.2
• /
• pp.55-61
• /
• 2015

In this study, mechanical properties of waste ground rubber tire powder were investigated to evaluate the influence of pre-treatment process for recycling. The tensile test, fracture test and morphology observation were carried out using various kinds of waste ground tire powders, which were produced by grinding and devulcanization process, respectively. As a results, it was found that the produced rubber powder through grinding process increased its tensile strength and elongation with decreasing particle size because of decreasing surface area. Devulcanized rubber powder also increased its tensile strength and elongation by de-crosslink with sulfur. It could be also suggested that devulcanization treatment after grinding process was more efficient recycling process for both increasing tensile property and fracture elongation of waste ground rubber tire powders.