• 한국펄프종이공학회:학술대회논문집
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• 한국펄프종이공학회 2000년도 추계학술발표논문집
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• pp.83-83
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• 2000

Alkylketene dimer was known as a cellulose reactive or alkaline size because it does not require to fix to the fiber as do the traditional rosin sizes. A proposed sizing mechanism of AKD was the formation of P -ketoester bond between AKD and cellulose which provides the permanent attachment and the orientation of the hydrophobic alkylchains outward. However, some questions about the reaction had arisen and thus, the sizing mechanism of AKD has been a subject of controversy for several decades. The major concern of the controversy is that AKD is really reactive with cellulose or not in the papermaking conditions. In this study, reaction between AKD and pulp fiber was investigated, in order to find out whether AKD forms P-ketoester with pulp fiber during aging under no catalyzed neutral condition with obvious spectroscopic evidence. In addition, effect of aging treatment on the sizing development was studied. It has been disclosed that, in absence of water, AKD reacted with cellulose to form P -ketoester linkage under no catalyzed neutral condition, while, in presence of water, most of AKD was hydrolyzed to a dialkyl ketone or P -ketoacid. In addition, during the aging treatment of AKD-sized paper, its typical IR spectra bands gradually were reduced, completely disappeared after 6hr aging, and formed new absorption bands at 1707cm-' and shoulder peak at 1700cm-' which refer to the typical dialkylketone absorption bands. Therefore, the formation of P -ketoester between AKD and pulp fiber is impossible in the practical papermaking process. It could be suggested that the sizing development of AKD-sized paper is obtained by next two mechanism: 1) formation of a thin-layer of AKD on the fiber surface through melting and spreading of AKD emulsion particles by heat and 2) the hydrolysis of AKD to dialkyl ketone which has higher melting point, during drying and storage of AKD sized papers.

• 펄프종이기술
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• 제40권3호
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• pp.36-41
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• 2008

It is known that ethanolamines play a critical role for deacidification of paper sized by alum-rosin. However, amines also are effective as a chelating agent of metal. The present work was focused on whether amines could scavenge metals and prevent from the aging of paper. Metals such as alum, copper(II) and iron(III) was added to paper, and the paper treated with amines was aged in a thermo-hygrostat for 3-6 days. In the case of paper added to alum, the amines efficiency against paper aging was good in the oder of triethanolamine, diethanolamine and monoethanolamine attributable to the intensity of basicity and steric effect. Even in the case of paper treated with copper(II) chloride, iron(III) chloride, and copper(II) chloride, the significant preservation efficiency was shown by ethanolamine during accelerated aging. This outcome pinpoints the fact that ethanolamine can prevent paper aging not only from acid by neutralizing acid contained in paper but also from metals by producing of complexes with metals. These consequences above convince that ethanolamine makes it possible for mass deacidification for paper which contains acid and metals. Future studies should be conducted concerning whether, in reality, the treatment of its gas mode, in a single or multiple applications, has significant effect on lessening paper aging.

• 한국자동차공학회논문집
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• 제16권5호
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• pp.22-28
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• 2008

A closed type crankcase ventilation system has been adopted to engines to prevent emission of blow-by gas to atmosphere. In the early closed type crankcase ventilation system, blow-by gas which contains engine lubricating oil is re-circulated into the intake system. The blow-by gas containing oil mist leads to increased harmful emissions and engine problems. To reduce loss of the engine oil, a highly-efficient oil separation device is required. Principle of a cyclone oil separator is to utilize centrifugal force in the separator and, therefore, oil separator designs depend on rotational flow which causes the centrifugal force. In this paper, flow characteristics and oil separation performances for cyclone type designs are calculated with CFD methodology. In the CFD model, oil particle was injected on a inlet surface with Rosin-Rammler distribution and uniform distribution. The major design parameters considered in the analysis model are inlet area, cone length and outlet depth of the oil separator. As results, reducing inlet area and increasing cone length increase oil separation performance. Changes in outlet depth could avoid interference between rotational flow and outlet flow in the cyclone oil separator.

• 공업화학
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• 제7권4호
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• pp.787-793
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• 1996

본 논문은 옵셋 잉크가 국내 신문고지의 탈묵에 미치는 영향을 조사하기 위해 국내신문 옵셋잉크의 조성분과, 그들 잉크로 옵셋 인쇄된 시료를 10, 30, 90, 180일 동안 열화시킨 후, 이들의 탈묵성을 비교하였다. 인쇄잉크의 조성분을 다르게 하여 인쇄한 시료는 열화기간이 증가될 수록 수율과 백색도가 감소되었다. 특히 아마인유의 첨가량이 많은 시료의 경우, 열화기간에 따라 많은 수율의 감소와 백색도의 저하를가져왔다. 따라서 아마인유의 첨가량은 탈묵에 결정적인 역할을 한다는 결론을 얻었다. 또한 로진변성페놀수지와 길소나이트가 포함된 시료는 열화과정을 통해 상대적으로 백색도의 감소가 있었다. 강도 측면에서 볼 경우, 열화기간에 따라 대체로 인장지수와 파열지수는 감소하였고, 인열지수는 증가했다. 그러나 아마인유만을 비이클 성분으로 사용한 시료의 경우 다른 시료에 비해 모든 강도가 낮았는데, 이것은 잉크와 섬유간의 강한 가교결합이 형성되어 초지 시 해리가 어렵기 때문이다.

• 한국응용과학기술학회지
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• 제27권4호
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• pp.427-436
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• 2010

Much oyster shell is breeding by character and conduct of oyster-industry for a long time among them. An experimental study was carried out to investigate the recycling possibility of waste oyster shells, which induce environmental pollutions by piling up out at the open or the temporary reclamation. The purpose of this study is to develope eco-friendly binder using waste oyster shells, and to reinforce soils fur soft soil improvement. In this paper, a series of laboratory tests including compressive pot tests were performed to evaluate characteristics of soils treated by developed waste oyster shells with different water content of soils. Based on test results, eco-friendly Supporter manufactured from waste oyster shells were estimated as good resource materials for soft soil improvements. We got the conclusion by a series of experiment, It is verified that change of pH of soil is improved by mixing with oyster shells. The homogenization method for deducing apparent of oyster shells, which can consider micro-structure of mixed soil, is introduced. The improvement treatment leaded to enlarge fluctuation of soil moisture content. The effect of calcium concentration was good though improvement treatment of physical property. In addition, the crop yield in amelioration plots increased. It means that the increase of crop yield was caused by improvement of soil physical properties rather than improvement of calcium concentration.

• 한국재료학회지
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• 제20권3호
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• pp.167-173
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• 2010

In this study, we used activated carbon (AC) and titanium oxysulfate as a titanium precursor to prepare carbon/titania composites. We then mixed it with bentonite in different ratios to make a carbon/titania/bentonite monolith for use in architecture bricks by using Phenolic rosin (PR) as a bonding agent. The physicochemical properties of the prepared composites were analyzed by BET surface area, scanning electron microscopy (SEM), X-ray diffraction (XRD), energy dispersive X-ray analysis (EDX), self-cleaning effect and bactericidal tests. The BET surface areas increased as the ratio of carbon/titania composites increased. The SEM microscopy showed that the $TiO_2$ and bentonite were coated on the surface of the AC. The XRD patterns showed a mixture structure of anatase and rutile of $TiO_2$ with a clear $SiO_2$ structure. The EDX spectra of the carbon/titania/bentonite monolith confirmed the presence of various elements, namely C, O, Ti and Si, as well as other, impure elements. Moreover, to determine the self-cleaning effect of the carbon/titania/bentonite monolith, we used methylene blue (MB, $C_{16}H_{18}N_3S{\cdot}Cl{\cdot}3H_2O$) in an aqueous solution under the irradiation of visible light. Accordingly, all of the samples had excellent degradation of the MB solution. Furthermore, it was observed that the composites with sunlight irradiation had a greater effect on E. coli than any other experimental conditions.

• 한국가스학회지
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• 제2권3호
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• pp.1-11
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• 1998

열 수축 쉬-트용 점착제의 접착성, 내한성 및 유동성을 향상시키기 위해 점착제를 구성하는 각 성분들의 종류 및 함량에 따른 물성을 평가하였다. 본 연구에서는 베이스 폴리머로서 내후성이 우수한 부틸고무를 선정하여 실험을 진행하였다. 점착부여제는 석유계 수지가 로진보다 우수한 접착력을 나타내었으며, 함량이 감소함에 따라 유동성이 저하됨을 알 수 있었다. 폴리부텐은 저 분자량보다 고 분자량의 물성이 우수하였다. 카본블랙의 경우 입자경이 클수록 물성 향상에 유리하였다. 탄산칼슘을 중량제로서 혼입할 경우 카본블랙과 함께 혼합시키는 경우가 바람직하였다.

• Geomechanics and Engineering
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• 제36권1호
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• pp.51-69
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• 2024

Currently, composite lining mountain tunnels in China are generally classified based on the [BQ] method for the surrounding rock grade. Increasingly, tunnel field construction is replicated indoors for scale down model tests. However, the development of analogous materials for model tests of composite lining tunnels with different surrounding rock grades is still unclear. In this study, typical Class III and V surrounding rock analogous materials and corresponding composite lining support materials were developed. The whole processes of excavation-support dynamics of the mountain tunnels were simulated. Data on the variation of deformations, contact pressures and strains on the surrounding rock were obtained. Finally, a comparative analysis between model tests and numerical simulations was performed to verify the rationality of analogous material development. The following useful conclusions were obtained by analyzing the data from the tests. The main analogous materials of Class III surrounding rock are barite powder, high-strength gypsum and quartz sand with fly ash, quartz sand, anhydrous ethanol and rosin for Class V surrounding rock. Analogous materials for rockbolts, steel arches are replaced by aluminum bar and iron bar respectively with both shotcrete and secondary lining corresponding to gypsum and water. In addition, load release rate of Class V surrounding rock should be less than Class III surrounding rock. The fenestration level had large influence on the load sharing ratio of the secondary lining, with a difference of more than 30%, while the influence of the support time was smaller. The Sharing ratios of secondary lining in Class III surrounding rock do not exceed 12%, while those of Class V surrounding rock exceed 40%. The overall difference between the results of model tests and numerical simulations is small, which verifies the feasibility of similar material development in this study.

• Parasites, Hosts and Diseases
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• 제23권1호
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• pp.165-172
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• 1985

Naegleria fowleri의 감염에 의한 생쥐의 원발성 아메바성 뇌수막염의 발생에 prednisolone투여가 어떠한 영향을 주는가를 관찰한 바 다음과 같은 결론을 얻었다. 1. 각 실험군 별로 $1{\times}10^5$의 N. fowleri를 감염시킨 후 생존기간을 관찰하였더니, prednisolone을 투여한 제1군의 평균 생존기간은 10.2일, 제2군은 10.6일, 제3군은은 11.3일로써 prednisolon을 투여한 군이 비투여군에 비하여 유의하게 생존기간이 단축됨을 알 수 있었으며, prednisolon투여군인 제1, 2, 3군 사이에 유의한 차이는 없었으나 전투여군인 제1군에서 생존시간이 단축되는 경향을 나타내었다. 2. 각 실험군 별로 감염 이후 20일까지 체중의 변화를 관찰한 결과, prenisolone 투여군에서는 서로 비슷한 양상을 나타내었는데 투여하는 시기부터 어느 정도 감소하다가 일정한 시간이 지나면서 회복현상을 나타내었다. 또한 prednisolon만 투여한 제 IV군에 비하여 제1, 2, 3군에서 체중이 더욱 심하게 감소하는 현상을 나타내었다. 그리고 대조군은 감염 8일 후부터 감소하기는 하였으나 큰 차이는 없는 것으로 보아 체중감소현상은 주로 prednisolone에 의해 영향을 받는 것으로 보인다. 3. Prednisolone 투여한 감염군은 대조군에 비하여 뇌와 폐조직에서 비교적 심한 병변이 나타났음을 알 수 있었다. 4. 감염된 생쥐의 임상증세는 감염 후 며칠이 지나면 머리를 비비고 고개를 떨구며, 식욕부진이 나타나 먹이를 먹지 않다가 발작이 오고, 빈사상태가 되어 사망하게 된다. 대부분의 생쥐에서 이러한 증세가 나타나는데, prednisolone 투여군에서는 감염 5일 이후부터 증세가 나타나는 경향을 보였고, 대조군은 감염 8일 이후에야 나타나 10일경에 사망하였다. 이상의 결과를 종합항 보면 prednisolone을 투여하여 인위적으로 면역반응을 억제시켜 줄 경우 N. fowleri에 감염된 생쥐의 생존기간은 단축되고 병변도 더욱 심하게 나타나며, 감염전에 투여해 주는 것이 가장 치명적인 영향을 줄 수 있음을 알 수 있었다.

• 보존과학회지
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• 제35권5호
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• pp.453-469
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• 2019

청자 '순화4년'명 항아리는 굽바닥에 명문이 새겨져 용도와 사용처, 제작자를 알 수 있는 등 초기 청자의 제작 정황을 보여주는 중요한 편년자료이다. 청자 항아리는 과거에 여러 번 수리복원 되었으나 시간이 지나면서 다양한 환경변화로 인해 처리 재료가 노화되어 균열부의 이격 및 단차가 발생하는 등 구조적 안정성이 우려되었다. 보존상태를 정밀 진단한 결과, 청자 항아리는 정면의 '입(入)'자형 균열, 좌면의 'V'자형 결실부를 포함한 균열, 후면의 'J'자형 균열이 주요 손상부위로 확인되었다. 균열부는 장뇌, 건성유, 송진 등이 포함된 정제 옻을 접착제로 토분을 첨가하여 접합하고 접합선은 다시 정제 옻을 칠한 후 금분으로 표면 처리한 것을 알 수 있었다. 결실부는 석고로 복원 후 아크릴 물감으로 색맞춤하였다. 이후 수리복원 재료가 노화되어 1981년에 국립중앙박물관에서 응급처리를 실시하였는데, 균열부 보강을 위해 Cemedine C를 쓰거나 Cemedine C에 Microballoon을 첨가하여 사용하였다. 보존처리는 유물의 보존상태 진단 결과를 근거로, 과거 수리복원 재료를 제거하고 물리적으로 취약한 부분을 다시 접합복원을 통해 보강하는데 중점을 두었다. 또한 추후 전시하는데 활용될 수 있도록 복원부를 중심으로 색맞춤을 실시하였다.