• Bulletin of the Korean Chemical Society
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• 제33권6호
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• pp.1945-1948
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• 2012

Rhodamine B (RhB) and rhodamine 6G (Rh6G) were employed as catalysts for the synthesis of cyclic carbonate from carbon dioxide and epoxide. It turned out that the catalytic activity of Rh6G was nearly 29 times higher than that of RhB at 1 atm pressure, $90^{\circ}C$. Furthermore, the catalytic efficiency of RhB and Rh6G was greatly enhanced with triethylamine as co-catalyst. Under the optimized conditions, the best isolated yield (93%) of cyclic carbonate was achieved without organic solvent and metal component.

• 한국환경과학회지
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• 제22권10호
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• pp.1273-1278
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• 2013

Novel rhodamine 6G fluorescent chemosensors 1 and 2 for the detection of transition metal cations were synthesized through the condensation of rhodamine 6G ethylenediamine with each of 2-hydroxy-1-naphthaldehyde and 2,6-pyridinedicarbaldehyde, respectively. 1 and 2 were characterized using $^{13}C$ NMR, $^1H$ NMR and mass spectroscopy. Fluorometric and colorimetric measurements involving various metal ions revealed the ring opening of the rhodamine 6G spirocycle framework. In the absence of metal cations, 2 was colorless and non-fluorescent, whereas the addition of metal cations ($Hg^{2+}$ and others) changed the color to pink, accompanied by the appearance of an orange fluorescence. The chemosensors exhibited high selectivity for $Hg^{2+}$ over other divalent first-row transition metals. The complexes of $Hg^{2+}$ with 1 and 2 were successfully isolated. A huge enhancement in the fluorescence for both one- and two-photon excitations makes these compounds suitable candidates to be used for fluorescent labeling of biological systems.

• 한국염색가공학회지
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• 제25권1호
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• pp.7-12
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• 2013

The energy levels are very important to investigate properties of organic dye materials. These values of energy levels can be calculated and compared with absorption spectra, cyclic voltammetric measurement and computer simulative calculation. In this study, absorption and emission changes were observed by complexation between rhodamine 6G based dye and mercury. This is related to spirolactam ring system of rhodamine 6G based dye. According to structural change of this dye, HOMO and LUMO energy levels were investigated and determined by their values with different approaches.

• 대한전기학회:학술대회논문집
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• 대한전기학회 1984년도 하계학술회의논문집
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• pp.306-307
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• 1984

• 대한화학회지
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• 제42권6호
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• pp.672-678
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• 1998

산업폐기물인 꽃게의 껍질로부터 chitin을 탈아세틸화시켜 분자량이 서로 다른 chitosan을 제조하였다. Rhodamine 6G(Rh 6G)-sodium dodecyl sulfate(SDS)계 및 Rh 6G-chitosan계들의 흡수 및 형과 spectra를 조사하였고, chitosan의 분자량 및 pH에 따른 Rh 6G-SDS-chitosan계의 응집효과에 대해 조사하였다. Rh 6G-SDS계의 흡광도나 형광세기는 S/D(SDS 농도/Rh 6G 농도)=32 이하에서 감소하다가 그 이상에서 다시 증가하였다. 부유물질(SS) 제거율이나 투광도로부터 S/D=32에서 chitosan을 첨가한 Rh 6G-SDS-chitosan계의 응집 성능이 Rh 6G-SDS계에 비해 훨씬 우수함을 알 수 있었다. 그리고 chitosan의 농도나 분자량이 크면 클수록, S/D 첨가 범위는 32에서 100까지 확대되는 것을 알 수 있었다. 부유물질의 제거율은 chitosan의 분자량이 클수록 pH 2∼9에서 우수한 성능을 가지는 반면, pH 12 이상에서 부유물질의 제거율은 현저히 저하되는 것을 알 수 있었다.

• 한국광학회지
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• 제4권2호
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• pp.195-199
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• 1993

Rh-6G(Rhodamine 6G)를 주색소로 하고 C-545(Coumarin 545)를 첨가색소로 하는 펄스형 혼합 색소레이저의 출력을 조사하였다. 동축형의 섬광관을 펌핑 광원으로 이용하였으며 Rh-6G 단일 색소로 발진할 경우 전기 입력 에너지가 346 J 일 때 첨두 출력과 에너지는 각각 27kW, 59mJ이었다. Rh-6G의 흡수 스펙트럼과 일치하는 형광 스펙트럼을 갖는 C-545를 에서지 주개로 선택하였다. Rh-6G의 농도를 최적 농도인 $1{\times}10_-4mol/l$로 고정하고 C-545의 농도를 $1{\times}10_7mol/l$부터 변화시키면서 혼합 색소에 대한 레이저의 출력 특성을 조사하였다. C-545의 농도가 Rh-6G 농도의 0.4%일 때 출력 에너지는 약 70% 증가하였다.

• Bulletin of the Korean Chemical Society
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• 제32권2호
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• pp.519-523
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• 2011

We studied the detection of the Hg(II) concentration in an aqueous solution using rhodamine dyes on citrate-reduced Au nanoparticles (NPs). The quenching effect from Au NPs was found to decrease as the Hg(II) concentration increased under our experimental conditions. As the fluorescence signals intensified, the surface-enhanced Raman scattering (SERS) intensities reduced on the contrary due to less rhodamine dyes on Au NPs as the Hg(II) concentration increased. The rhodamine 6G (Rh6G) and rhodamine 123 (Rh123) dyes were examined via fluorescence and SERS measurements depending on Hg(II) concentrations. Fast and easy fluorescence detection of an Hg (II) concentration as low as a few ppm could be achieved by naked eye using citrate-reduced Au NPs.

• 한국염색가공학회지
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• 제25권2호
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• pp.83-88
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• 2013

Rhodamine dyes have been studied in various scientific areas due to their excellent photophysical properties. In particular, these rhodamine dyes are one of the most famous fluorophores as signal unit in chemosensor study. This is related to spirolactam ring system in rhodamine dyes. When the spirolactam ring is closed, there is nonfluorescence and colorless. Whereas, ring-opening of the corresponding spirolactam induces strong fluorescence and color. These absorption and emission changes are related to structural changes as well as electron energy potential levels such as HOMO and LUMO values. In this study, two different structures of rhodamine 6G hydrazide depending on the spirolactam ring system were investigated using absorption measurement, electrochemical measurement and computational calculations.

• Bulletin of the Korean Chemical Society
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• 제10권2호
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• pp.158-161
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• 1989

The hydrophobic interaction occurring between rhodamine 6G and tetraphenylborate anions has been investigated with surfactants by absorption and fluorescence studies. In the order of tetraphenylborate, tetrakis(4-fluorophenyl)borate, and tetrakis[3,5-bis(trifluoromethyl)phenyl]borate the hydrophobicity is found to be increased.

• 한국광학회지
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• 제4권3호
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• pp.338-346
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• 1993

시간 상관 단일 광자 계수법을 사용하여 rhodamine 6G 분자의 회전 재배열 시간을 측정하였다. 알코올 용매에서 유체 역학 모델이 예측하는 것보다 회전 재배열 시간이 느린 현상으로 이해하기 위해 유전 마찰 효과를 고려하였으며, 유전 마찰과 정적 분광학 데이터로부터 바닥 및 여기 상태의 전이 쌍극자 모멘트 크기를 계산하였다.